File name: Pandora121s1_Izana_20240811_L2Fit_fout2c51d20221209p1-8.txt File generation date: 20240812T011701.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c51p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 121 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora121_OF_v2d20210519.txt Instrument calibration file used: Pandora121s1_CF_v51d20221209.txt Level 1 file used: Pandora121s1_Izana_20240811_L1_smca1c51d20221209p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20240811 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Analab+Fld after lab cal First and last pixel inside fitting window: 224 365 Nominal wavelengths inside fitting window [nm]: 305.1019 305.2431 305.3842 305.5254 305.6665 305.8076 305.9487 306.0899 306.2309 306.3720 306.5131 306.6542 306.7952 306.9362 307.0773 307.2183 307.3593 307.5003 307.6412 307.7822 307.9232 308.0641 308.2050 308.3460 308.4869 308.6278 308.7687 308.9095 309.0504 309.1913 309.3321 309.4729 309.6137 309.7546 309.8953 310.0361 310.1769 310.3177 310.4584 310.5992 310.7399 310.8806 311.0213 311.1620 311.3027 311.4433 311.5840 311.7247 311.8653 312.0059 312.1465 312.2871 312.4277 312.5683 312.7089 312.8494 312.9900 313.1305 313.2710 313.4115 313.5520 313.6925 313.8330 313.9734 314.1139 314.2543 314.3948 314.5352 314.6756 314.8160 314.9564 315.0967 315.2371 315.3775 315.5178 315.6581 315.7984 315.9387 316.0790 316.2193 316.3596 316.4998 316.6401 316.7803 316.9205 317.0607 317.2009 317.3411 317.4813 317.6215 317.7616 317.9018 318.0419 318.1820 318.3221 318.4622 318.6023 318.7424 318.8824 319.0225 319.1625 319.3025 319.4425 319.5825 319.7225 319.8625 320.0025 320.1424 320.2824 320.4223 320.5622 320.7021 320.8420 320.9819 321.1218 321.2617 321.4015 321.5413 321.6812 321.8210 321.9608 322.1006 322.2404 322.3801 322.5199 322.6596 322.7994 322.9391 323.0788 323.2185 323.3582 323.4979 323.6375 323.7772 323.9168 324.0565 324.1961 324.3357 324.4753 324.6149 324.7544 324.8940 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Azimuth motor temperature [°C], 999=no temperature signal Column 98: Zenith motor temperature [°C], 999=no temperature signal Column 99: Temperature at electronics board 1 [°C], 999=no temperature signal Column 100: Temperature at electronics board 2 [°C], 999=no temperature signal Column 101: Humidity in head sensor [%], -9=no humidity signal Column 102: Pressure in head sensor [hPa], -9=no pressure signal Columns 103-244: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 245-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240811T070012.8Z 8989.291815 43 1 51.40 2 85.26 75.40 159.27 54.71 0.00 1 0.00 1 0 25 5.673e-01 2.275e-02 4.774e-01 1.873e-02 1.023602e+00 1.177700e-02 1.009021e-02 -6.000000e+00 3.324911e-01 227.69 -2.00 3.19 -2.00 322.54 0.00e+00 8.866846e-03 7.435392e-03 6.950783e-03 -6.000000e+00 1.706656e-02 282.04 -2.00 20.00 -2.00 322.15 0.00e+00 10.264 0.011 302.00 328.00 3 1.0377e+00 5.0518e-02 1.0736e-01 -6.0000e+00 8.2895e-01 1.1425e+00 7.1753e-02 9.3053e-02 -6.0000e+00 9.0256e-01 -1.5314e+00 6.7408e-02 3.5318e-02 -6.0000e+00 5.2910e-01 6.1535e-01 3.0566e-02 1.3437e-02 -6.0000e+00 2.2783e-01 2.6948e-05 -1.9216e-03 5.1915e-04 1.3999e-04 -6.0000e+00 1.6114e-02 5.1772e-04 2.2389e-05 12 8 8 10 0 0 37.43 15.88 0.42 0.00052 -0.01392 49 8 4 8 0 1048.870 15.00 15.88 26.12 56.90 55.60 20.77 20.87 26.2 790.77 -127932 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900000 3832 900000 -4784 132 1374 -3680 -1205 1538 900000 2461 735 953 721 1308 764 1272 1384 1561 3548 1157 1609 2046 2093 2226 3564 2420 2908 3137 1785 2326 1002 2765 779 3198 2533 2290 4326 2631 2201 1595 3720 814 4081 1767 4318 513 1144 1530 -1557 1050 1514 2778 3091 -454 1941 -1025 1802 268 1581 1038 117 -685 -835 -1454 -132 -1308 -4493 -407 -1213 1477 -2597 -921 -1819 -3540 -239 -3229 -1468 -2553 -2560 -1746 -1644 -189 -1638 -1710 -2470 2953 -1269 334 -1190 320 689 652 5672 2043 3545 1685 565 4761 1639 -1636 -830 1825 -295 1980 -53 851 -1156 1877 768 -893 -37 -2788 -3149 SS 20240811T071343.4Z 8989.301197 46 1 52.76 2 82.37 76.93 156.90 60.17 0.00 1 0.00 1 0 17 6.054e-01 7.177e-03 2.317e-01 2.543e-03 7.820888e-01 1.437775e-03 8.089138e-03 -6.000000e+00 3.485447e-01 227.69 -2.00 3.19 -2.00 321.68 0.00e+00 4.379489e-03 7.843380e-04 2.436708e-03 -6.000000e+00 1.540174e-02 282.04 -2.00 20.00 -2.00 321.18 0.00e+00 7.020 0.004 302.00 328.00 3 7.5460e-01 5.3260e-03 6.6304e-02 -6.0000e+00 8.6796e-01 5.0417e-02 8.2557e-03 4.1516e-02 -6.0000e+00 9.4212e-01 -3.8616e-02 9.2345e-03 2.5181e-02 -6.0000e+00 5.5622e-01 7.4463e-04 4.2195e-03 1.0047e-02 -6.0000e+00 2.3827e-01 5.3935e-04 -3.5918e-04 6.9972e-05 1.3030e-04 -6.0000e+00 1.6192e-02 3.4847e-04 -1.3568e-05 11 8 0 10 0 0 -4.62 15.88 0.22 0.00035 -0.00235 303 52 4 8 0 169.070 15.00 15.88 26.77 57.90 57.10 20.77 20.87 26.0 793.48 -223168 -226864 -203069 -111910 -281896 900000 -191407 900000 -228713 -147521 -144455 -156731 900000 -156909 20739 -108931 -22332 -73770 -75658 -62479 -105153 89710 -90554 2937 -44536 17948 -49867 -18644 -37550 -54054 24978 -34806 20054 -21135 2159 -18115 -2779 976 -7838 11024 -9457 1210 -4216 5594 -16 145 -2570 -5847 9293 -620 11063 2105 6230 -332 3360 5616 1634 5290 557 3922 -3094 6103 2644 3385 3691 1031 3402 741 3640 1112 1602 1407 -293 1566 -1241 2196 -2608 612 -1603 -238 -918 -1453 -1044 -1885 43 -651 537 779 577 670 335 389 -1276 -93 -456 402 931 1086 79 -486 -545 -1329 258 -657 -1708 -1975 -1579 -598 -280 602 220 330 -84 -218 -116 143 482 380 435 -166 374 453 795 435 200 -355 82 1170 83 81 -441 -437 -331 -193 -58 -468 704 195 139 42 -86 -332 -855 -1073 -824 -277 -2287 900000 -733 900000 -1701 -532 -553 -848 900000 -1591 51 -1104 -111 -698 -801 -619 -1635 222 -1347 19 -512 129 -652 -176 -448 -901 242 -761 298 -495 38 -408 -62 26 -284 395 -467 58 -226 280 -1 8 -158 -364 586 -44 807 190 601 -37 388 666 206 633 68 460 -417 860 451 647 729 206 680 164 908 327 505 452 -92 445 -325 504 -617 153 -489 -87 -395 -714 -552 -1067 26 -413 351 514 373 409 191 211 -709 -56 -325 335 830 1099 85 -508 -515 -1211 219 -591 -1666 -1873 -1590 -651 -345 834 337 525 -133 -331 -167 202 704 586 706 -271 583 670 1134 601 268 -458 106 1680 139 153 -917 -964 -778 -485 -143 -1203 1816 508 354 107 -204 -750 SS 20240811T071956.9Z 8989.305520 49 1 53.28 2 81.03 77.63 155.76 62.36 0.00 1 0.00 1 0 17 3.892e-01 5.693e-03 1.299e-01 1.464e-03 6.952639e-01 7.968088e-04 7.143146e-03 -6.000000e+00 2.212528e-01 227.69 -2.00 3.19 -2.00 321.30 0.00e+00 2.623722e-03 3.910302e-04 1.423619e-03 -6.000000e+00 9.703283e-03 282.04 -2.00 20.00 -2.00 320.78 0.00e+00 6.092 0.002 302.00 328.00 3 6.3942e-01 2.7375e-03 5.7386e-02 -6.0000e+00 5.5014e-01 1.0213e-02 3.9667e-03 3.5139e-02 -6.0000e+00 5.9649e-01 1.4955e-02 4.2996e-03 2.0084e-02 -6.0000e+00 3.5497e-01 -2.1660e-02 2.0302e-03 7.4669e-03 -6.0000e+00 1.5302e-01 1.2873e-03 -3.2636e-04 4.0340e-05 8.5624e-05 -6.0000e+00 1.0189e-02 1.9195e-04 -1.1872e-05 10 0 0 10 0 0 6.27 15.89 0.15 0.00019 -0.00226 499 85 2 8 0 102.630 15.00 15.89 27.11 58.90 58.60 20.87 20.87 26.0 794.85 -56692 -177319 -77322 -188234 -99053 -165319 -73718 -144317 -99803 -60365 -147680 -70843 -106747 -31562 -61041 -30760 -13967 -18363 -11347 -40845 -15581 -31529 552 -21481 -13767 -4124 -33867 -11863 -33997 -8864 -19333 -465 -8974 -2451 -3569 -7841 2844 -5792 2001 -4176 -189 -2508 1694 2004 461 4536 -1972 1296 -2054 2434 1461 1487 2755 1014 2576 -86 1223 -1923 577 638 1177 1664 2559 2533 -331 459 -1365 1020 1836 1636 1756 1259 1359 346 531 -754 -1410 -1443 -197 -488 -803 -913 -2246 -1381 -711 21 349 712 967 604 688 -379 -341 38 29 197 869 1088 183 -64 -1232 -697 -497 -237 -1697 -1372 -1017 -795 214 236 472 86 218 -251 -50 432 264 373 -71 -91 -19 547 706 370 232 -524 489 589 223 -86 -265 -421 -335 -162 -188 -296 434 294 103 95 -125 -266 -99 -1179 -210 -1401 -301 -974 -204 -921 -483 -214 -1311 -365 -1014 -193 -624 -280 -123 -190 -119 -597 -187 -452 6 -328 -220 -63 -687 -195 -691 -161 -485 -12 -279 -76 -107 -254 95 -254 101 -259 -13 -184 125 151 36 354 -170 114 -200 249 167 191 386 158 417 -15 215 -344 98 108 211 337 592 655 -90 121 -369 288 575 589 680 500 520 124 175 -228 -417 -457 -73 -210 -403 -518 -1390 -899 -480 15 258 530 704 428 453 -238 -212 26 22 174 884 1215 216 -73 -1321 -661 -449 -225 -1755 -1484 -1164 -958 286 355 753 142 352 -387 -74 631 398 595 -117 -151 -31 855 1065 540 327 -711 674 876 371 -160 -536 -876 -736 -372 -459 -748 1105 756 260 225 -283 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