File name: Pandora121s1_Izana_20250123_L2Fit_fwvt1c51d20221209p1-8.txt File generation date: 20250124T013320.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c51p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 121 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora121_OF_v2d20210519.txt Instrument calibration file used: Pandora121s1_CF_v51d20221209.txt Level 1 file used: Pandora121s1_Izana_20250123_L1_smca1c51d20221209p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20250123 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Analab+Fld after lab cal First and last pixel inside fitting window: 1642 1791 Nominal wavelengths inside fitting window [nm]: 492.0941 492.2154 492.3366 492.4578 492.5790 492.7002 492.8214 492.9425 493.0636 493.1847 493.3058 493.4269 493.5480 493.6690 493.7900 493.9110 494.0320 494.1530 494.2740 494.3949 494.5158 494.6367 494.7576 494.8785 494.9994 495.1202 495.2410 495.3619 495.4826 495.6034 495.7242 495.8449 495.9657 496.0864 496.2071 496.3277 496.4484 496.5690 496.6897 496.8103 496.9309 497.0514 497.1720 497.2926 497.4131 497.5336 497.6541 497.7746 497.8950 498.0155 498.1359 498.2563 498.3767 498.4971 498.6174 498.7378 498.8581 498.9784 499.0987 499.2190 499.3392 499.4595 499.5797 499.6999 499.8201 499.9403 500.0604 500.1806 500.3007 500.4208 500.5409 500.6610 500.7811 500.9011 501.0211 501.1411 501.2611 501.3811 501.5011 501.6210 501.7409 501.8608 501.9807 502.1006 502.2205 502.3403 502.4601 502.5799 502.6997 502.8195 502.9392 503.0590 503.1787 503.2984 503.4181 503.5378 503.6574 503.7771 503.8967 504.0163 504.1359 504.2555 504.3750 504.4946 504.6141 504.7336 504.8531 504.9725 505.0920 505.2114 505.3309 505.4503 505.5697 505.6890 505.8084 505.9277 506.0470 506.1663 506.2856 506.4049 506.5241 506.6434 506.7626 506.8818 507.0010 507.1201 507.2393 507.3584 507.4776 507.5967 507.7157 507.8348 507.9539 508.0729 508.1919 508.3109 508.4299 508.5488 508.6678 508.7867 508.9056 509.0245 509.1434 509.2623 509.3811 509.5000 509.6188 509.7376 509.8564 509.9751 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Zenith motor temperature [°C], 999=no temperature signal Column 100: Temperature at electronics board 1 [°C], 999=no temperature signal Column 101: Temperature at electronics board 2 [°C], 999=no temperature signal Column 102: Humidity in head sensor [%], -9=no humidity signal Column 103: Pressure in head sensor [hPa], -9=no pressure signal Columns 104-253: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 254-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250123T081825.2Z 9154.346125 184 1 44.34 2 86.57 114.16 50.70 185.84 0.00 1 0.00 1 0 15 3.395e-03 3.400e-03 1.752e-03 1.748e-03 4.763977e+03 1.092789e+02 3.385998e+02 -6.000000e+00 1.854535e+02 272.60 -2.00 20.00 -2.00 505.30 0.00e+00 7.697940e-04 4.726973e-05 4.828675e-05 -6.000000e+00 9.382172e-05 272.60 -2.00 20.00 -2.00 500.62 0.00e+00 1.226352e+00 3.449961e-02 3.902455e-02 -6.000000e+00 6.788942e-02 223.27 -2.00 3.19 -2.00 502.18 0.00e+00 12.759 0.021 489.00 513.00 1 7.0402e+00 2.6346e-03 1.4419e-02 -6.0000e+00 5.1986e-03 5.6550e-03 6.6808e-04 1.2022e-03 -6.0000e+00 1.3357e-03 3.9012e-04 1.0905e-03 1.8165e-04 4.7498e-05 -6.0000e+00 3.6850e-04 1.1718e-02 -6.0267e-05 10 0 0 10 0 0 99.93 15.95 0.88 0.01172 0.01928 38 8 1 2 0 1166.440 15.00 15.95 5.65 41.10 38.10 20.87 20.87 24.1 713.90 -546 -307 -317 33 -201 589 288 478 104 421 -80 137 -259 -367 -215 -323 -11 149 94 -267 255 50 188 331 487 656 293 232 -634 -377 -180 -432 503 363 274 -499 -89 100 -42 -280 -250 470 -34 366 -42 554 300 451 206 -294 -84 -586 -745 -274 152 -1213 -638 185 -38 464 303 479 82 405 75 108 150 -239 -242 -524 -49 -355 -103 235 -193 -152 -296 37 -384 -267 -461 -218 77 -120 25 -297 -123 -436 129 -276 -22 359 376 354 202 70 -324 -161 -217 -724 -440 -317 195 -42 -209 -415 -271 -449 87 215 34 96 117 230 219 502 529 533 519 347 245 -380 228 335 255 395 157 335 179 339 -454 44 -128 -248 -24 51 140 -198 314 -167 -49 294 420 34 -47 47 -461 -454 -527 -213 -508 -292 -310 33 -208 618 289 482 104 418 -79 141 -265 -372 -217 -330 -10 149 96 -276 263 52 195 344 508 680 303 235 -634 -367 -173 -422 501 372 286 -527 -93 103 -42 -287 -256 482 -36 384 -44 584 314 464 209 -291 -81 -557 -708 -264 150 -1243 -661 191 -39 479 314 497 86 419 77 109 149 -236 -236 -509 -47 -345 -101 232 -192 -150 -287 35 -364 -253 -440 -209 75 -118 24 -295 -123 -435 128 -277 -22 366 386 361 203 69 -311 -151 -200 -663 -406 -299 191 -42 -214 -426 -275 -454 88 217 33 95 117 230 221 507 537 540 521 343 240 -371 221 325 249 386 153 327 175 329 -440 42 -120 -233 -23 49 138 -199 318 -172 -50 305 437 36 -49 48 -468 -452 -521 -211 SQ 20250123T082342.5Z 9154.349797 187 1 29.92 2 85.52 114.82 50.85 187.39 0.00 1 0.00 1 0 15 3.259e-03 3.232e-03 1.258e-03 1.255e-03 3.680709e+03 7.671590e+01 2.721452e+02 -6.000000e+00 1.780070e+02 272.60 -2.00 20.00 -2.00 505.31 0.00e+00 6.813735e-04 3.405487e-05 4.042333e-05 -6.000000e+00 9.005456e-05 272.60 -2.00 20.00 -2.00 500.62 0.00e+00 1.017323e+00 2.480266e-02 2.933439e-02 -6.000000e+00 6.517198e-02 223.27 -2.00 3.19 -2.00 502.19 0.00e+00 10.715 0.013 489.00 513.00 1 6.6895e+00 1.8963e-03 1.1971e-02 -6.0000e+00 4.9904e-03 2.0434e-03 4.8054e-04 9.5511e-04 -6.0000e+00 1.2824e-03 7.0342e-04 1.0314e-03 1.3165e-04 3.9987e-05 -6.0000e+00 3.5383e-04 2.4631e-03 -1.3794e-05 12 1 1 12 1 1 99.99 15.95 0.92 0.00246 0.00962 20 6 1 2 0 1424.390 15.00 15.95 6.01 40.10 37.10 20.87 20.96 23.7 714.65 -397 -255 -304 -270 33 329 494 264 290 208 165 134 -219 -198 -340 -92 -322 22 75 -22 226 429 464 253 543 210 318 -22 -333 -688 -191 -334 254 228 -186 -47 -193 -45 192 24 81 -69 291 262 308 267 226 441 -140 -330 -610 -601 -527 -564 -252 254 -481 -309 -74 98 661 388 438 306 169 348 -164 -88 -410 -325 -374 -169 16 287 62 -695 -305 -356 -42 -453 -353 -384 -441 -68 95 -186 -311 25 -161 33 212 394 419 116 340 34 287 -431 -248 -515 -720 -441 -280 -105 -564 -376 -77 -253 18 163 23 -117 371 135 409 696 518 409 319 298 375 -257 316 361 243 407 -6 268 580 -10 90 -76 -351 -492 -184 199 -61 36 75 152 75 27 379 92 202 -189 -380 -674 -85 -356 -365 -239 -295 -269 34 342 520 267 293 218 170 137 -221 -198 -340 -93 -331 22 76 -23 233 442 479 263 565 218 327 -23 -332 -672 -193 -325 252 234 -195 -49 -201 -47 195 25 83 -71 301 274 324 281 236 453 -142 -325 -588 -569 -497 -542 -248 255 -494 -320 -76 100 679 401 453 316 173 349 -163 -87 -399 -313 -359 -163 16 283 61 -682 -294 -339 -39 -429 -336 -368 -427 -66 94 -185 -309 24 -160 33 213 401 429 118 341 33 276 -407 -230 -473 -668 -419 -276 -107 -554 -368 -78 -254 18 165 23 -116 372 136 415 708 530 418 323 298 369 -253 309 354 239 401 -5 264 568 -10 88 -73 -333 -466 -176 193 -60 36 77 156 78 28 396 96 210 -195 -385 -673 -83 -353 SQ 20250123T083831.2Z 9154.360083 190 1 11.50 2 82.58 116.72 51.41 191.66 0.00 1 0.00 1 0 15 2.824e-03 2.814e-03 1.407e-03 1.405e-03 2.339689e+03 8.278717e+01 1.808654e+02 -6.000000e+00 1.542519e+02 272.60 -2.00 20.00 -2.00 505.29 0.00e+00 5.494699e-04 3.810583e-05 3.021540e-05 -6.000000e+00 7.804807e-05 272.60 -2.00 20.00 -2.00 500.52 0.00e+00 6.895911e-01 2.788900e-02 1.787803e-02 -6.000000e+00 5.652436e-02 223.28 -2.00 3.19 -2.00 502.11 0.00e+00 7.199 0.004 489.00 513.00 1 6.5907e+00 2.1350e-03 7.9779e-03 -6.0000e+00 4.3276e-03 8.3078e-03 5.4431e-04 6.1341e-04 -6.0000e+00 1.1132e-03 1.1662e-03 2.2261e-03 1.4790e-04 2.7009e-05 -6.0000e+00 3.0691e-04 5.6020e-03 -9.3106e-05 12 1 1 12 1 1 99.98 15.96 1.00 0.00560 0.02104 6 6 1 2 0 1641.570 15.00 15.96 6.79 39.80 38.80 20.87 20.96 23.7 717.83 -226 -336 64 -224 -179 390 496 61 356 236 165 74 -340 -259 -355 -344 -110 94 238 -176 256 99 346 486 476 451 171 371 -465 -302 -82 -322 333 536 -109 -391 33 -63 -177 -205 -11 -50 -110 -37 174 217 309 89 134 -185 -316 -447 -471 -404 102 -7 -299 -183 -11 47 246 260 49 226 143 299 -16 29 -294 -474 46 -198 85 295 -17 -270 -162 -224 -315 -121 -436 -434 -362 -56 -62 -104 -88 -114 -4 -257 164 357 220 241 224 320 8 6 -435 -546 -676 -565 130 119 -439 -604 -207 -52 28 208 -10 154 35 49 91 357 458 150 100 390 833 106 359 153 135 243 225 -96 285 234 -25 44 -143 -341 150 131 90 -108 183 61 281 114 161 226 175 -86 -515 -492 -420 -374 -217 -330 62 -226 -185 397 511 63 368 241 167 76 -347 -261 -358 -349 -110 96 248 -186 270 105 365 514 505 476 179 383 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