File name: Pandora121s1_Izana_20250825_L2Fit_fwvt1c51d20221209p1-8.txt
File generation date: 20250826T011717.3Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c51p1-8
Local principal investigator: Alberto Redondas
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 121
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora121_OF_v2d20210519.txt
Instrument calibration file used: Pandora121s1_CF_v51d20221209.txt
Level 1 file used: Pandora121s1_Izana_20250825_L1_smca1c51d20221209p1-8.txt
Full location name: Izana Atmospheric Research Center
Short location name: Izana
Country of location: Spain
Location latitude [deg]: 28.3090
Location longitude [deg]: -16.4994
Location altitude [m]: 2360
Local noon date: 20250825
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Analab+Fld after lab cal
First and last pixel inside fitting window: 1642 1791
Nominal wavelengths inside fitting window [nm]: 492.0941 492.2154 492.3366 492.4578 492.5790 492.7002 492.8214 492.9425 493.0636 493.1847 493.3058 493.4269 493.5480 493.6690 493.7900 493.9110 494.0320 494.1530 494.2740 494.3949 494.5158 494.6367 494.7576 494.8785 494.9994 495.1202 495.2410 495.3619 495.4826 495.6034 495.7242 495.8449 495.9657 496.0864 496.2071 496.3277 496.4484 496.5690 496.6897 496.8103 496.9309 497.0514 497.1720 497.2926 497.4131 497.5336 497.6541 497.7746 497.8950 498.0155 498.1359 498.2563 498.3767 498.4971 498.6174 498.7378 498.8581 498.9784 499.0987 499.2190 499.3392 499.4595 499.5797 499.6999 499.8201 499.9403 500.0604 500.1806 500.3007 500.4208 500.5409 500.6610 500.7811 500.9011 501.0211 501.1411 501.2611 501.3811 501.5011 501.6210 501.7409 501.8608 501.9807 502.1006 502.2205 502.3403 502.4601 502.5799 502.6997 502.8195 502.9392 503.0590 503.1787 503.2984 503.4181 503.5378 503.6574 503.7771 503.8967 504.0163 504.1359 504.2555 504.3750 504.4946 504.6141 504.7336 504.8531 504.9725 505.0920 505.2114 505.3309 505.4503 505.5697 505.6890 505.8084 505.9277 506.0470 506.1663 506.2856 506.4049 506.5241 506.6434 506.7626 506.8818 507.0010 507.1201 507.2393 507.3584 507.4776 507.5967 507.7157 507.8348 507.9539 508.0729 508.1919 508.3109 508.4299 508.5488 508.6678 508.7867 508.9056 509.0245 509.1434 509.2623 509.3811 509.5000 509.6188 509.7376 509.8564 509.9751
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Azimuth motor temperature [°C], 999=no temperature signal
Column 99: Zenith motor temperature [°C], 999=no temperature signal
Column 100: Temperature at electronics board 1 [°C], 999=no temperature signal
Column 101: Temperature at electronics board 2 [°C], 999=no temperature signal
Column 102: Humidity in head sensor [%], -9=no humidity signal
Column 103: Pressure in head sensor [hPa], -9=no pressure signal
Columns 104-253: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 254-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250825T064736.0Z 9368.283055 20 1 18.94 2 89.42 78.22 114.00 75.62 0.00 1 0.00 1 0 29 4.666e-03 4.614e-03 1.546e-04 1.541e-04 1.025593e+04 1.062391e+01 7.021240e+02 -6.000000e+00 2.642778e+02 281.72 -2.00 20.00 -2.00 505.42 0.00e+00 1.575158e-03 4.303866e-06 9.314338e-05 -6.000000e+00 1.317968e-04 281.72 -2.00 20.00 -2.00 501.01 0.00e+00 1.330719e+00 2.999817e-03 7.253000e-02 -6.000000e+00 9.323163e-02 227.40 -2.00 3.19 -2.00 502.52 0.00e+00 19.822 0.080 489.00 513.00 1 1.1661e+00 2.2979e-04 2.4189e-02 -6.0000e+00 7.1599e-03 -3.7627e-02 5.7173e-05 2.1844e-03 -6.0000e+00 1.8359e-03 6.2410e-02 1.5062e-03 1.5635e-05 8.8051e-05 -6.0000e+00 5.0670e-04 7.8613e-03 -2.8366e-05 12 8 8 10 0 0 3.80 15.77 1.45 0.00786 0.01831 609 104 2 2 0 31.040 15.00 15.77 16.17 49.90 47.40 20.67 20.67 28.6 732.08 -957 -621 -274 -127 177 676 749 706 546 345 216 -87 -391 -416 -501 -459 -159 284 196 16 194 300 390 630 636 418 451 151 -548 -653 -519 -451 77 469 12 -200 -5 -10 -219 -114 63 70 270 473 540 538 430 263 -61 -516 -758 -977 -924 -486 -111 -63 -14 113 184 390 574 580 470 432 254 56 -53 -157 -449 -586 -475 -440 -209 91 -187 -581 -635 -490 -547 -651 -579 -604 -432 -148 -175 -303 -228 -117 1 131 402 800 725 491 529 339 8 -306 -808 -1157 -1139 -792 -240 -134 -443 -529 -507 -443 -120 71 34 186 430 583 721 1017 1063 745 397 252 24 191 536 532 284 344 266 136 336 204 -279 -304 -340 -543 -231 59 -181 -53 254 369 294 326 357 329 215 -61 -451 -647 -657 -491 -861 -546 -248 -119 169 658 710 674 520 326 201 -84 -375 -396 -477 -442 -149 273 192 16 193 300 390 634 642 423 453 150 -535 -624 -491 -432 76 474 12 -200 -5 -10 -214 -111 61 69 270 478 550 548 435 263 -60 -498 -746 -948 -896 -478 -107 -63 -14 115 188 398 588 596 485 444 260 57 -53 -154 -440 -570 -461 -430 -206 91 -187 -576 -621 -472 -524 -625 -558 -588 -424 -146 -175 -306 -230 -118 1 132 409 789 717 482 527 329 7 -284 -743 -1062 -1058 -758 -239 -132 -450 -539 -514 -447 -121 72 35 194 451 615 737 1047 1104 779 414 260 25 199 557 556 288 350 272 140 343 208 -283 -316 -351 -564 -234 61 -191 -57 276 390 314 351 386 356 233 -65 -477 -700 -707 -533
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SQ 20250825T064814.6Z 9368.283502 20 3 18.91 2 89.28 78.29 113.87 75.71 0.00 1 0.00 1 0 29 4.450e-03 4.410e-03 1.392e-04 1.388e-04 9.686895e+03 9.459843e+00 6.660514e+02 -6.000000e+00 2.520298e+02 281.72 -2.00 20.00 -2.00 505.43 0.00e+00 1.531147e-03 3.892395e-06 9.078240e-05 -6.000000e+00 1.256890e-04 281.72 -2.00 20.00 -2.00 501.02 0.00e+00 1.327642e+00 2.706070e-03 6.930277e-02 -6.000000e+00 8.890469e-02 227.40 -2.00 3.19 -2.00 502.54 0.00e+00 19.545 0.077 489.00 513.00 1 1.0268e+00 2.0762e-04 2.3715e-02 -6.0000e+00 6.8277e-03 -3.3457e-02 5.1574e-05 2.1037e-03 -6.0000e+00 1.7505e-03 7.4034e-02 1.3268e-03 1.4118e-05 8.2803e-05 -6.0000e+00 4.8315e-04 8.9863e-03 -2.9790e-05 11 8 0 10 0 0 -1.27 15.77 1.38 0.00899 0.01819 609 104 2 2 0 31.040 15.00 15.77 16.23 49.90 47.40 20.67 20.67 28.5 732.17 -902 -596 -232 -91 143 643 719 675 548 352 224 -52 -350 -385 -480 -431 -138 273 189 7 182 297 368 623 615 422 439 117 -513 -631 -473 -452 106 437 -21 -209 -21 -31 -186 -84 33 64 282 435 516 512 409 235 -53 -500 -741 -899 -862 -442 -129 -112 -22 76 173 366 539 550 457 431 266 51 -52 -139 -415 -561 -452 -422 -197 88 -162 -583 -599 -481 -509 -592 -556 -619 -446 -149 -192 -287 -236 -110 10 115 392 745 687 477 494 342 20 -296 -740 -1102 -1045 -767 -220 -138 -479 -523 -480 -421 -107 90 8 168 392 535 679 974 1027 704 387 243 33 220 491 504 269 342 287 110 339 258 -267 -299 -304 -541 -210 52 -173 -87 246 330 244 329 346 301 187 -80 -465 -612 -613 -455 -793 -535 -215 -86 134 615 698 659 534 341 214 -49 -329 -359 -448 -407 -132 267 182 7 178 291 363 615 611 420 433 114 -492 -616 -457 -443 103 433 -22 -213 -21 -31 -185 -84 33 65 288 433 517 513 407 240 -53 -492 -714 -854 -819 -426 -128 -114 -22 76 173 367 542 555 463 435 267 50 -51 -139 -414 -557 -447 -420 -191 86 -159 -567 -595 -472 -497 -579 -546 -613 -429 -145 -189 -284 -233 -109 10 114 391 750 694 478 484 326 19 -281 -694 -1032 -989 -748 -215 -139 -478 -524 -477 -432 -110 90 8 172 405 554 708 1023 1088 750 411 255 34 225 501 517 278 355 299 115 352 268 -276 -305 -307 -550 -216 54 -178 -91 262 355 265 360 381 331 205 -87 -499 -648 -647 -484
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