File name: Pandora209s1_Izana_20220915_L2Fit_fout2c5d20220720p1-8.txt File generation date: 20250217T095823.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 209 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora209_OF_v2d20210806.txt Instrument calibration file used: Pandora209s1_CF_v5d20220720.txt Level 1 file used: Pandora209s1_Izana_20220915_L1_smca1c5d20220720p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20220915 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0286 305.1697 305.3107 305.4517 305.5928 305.7338 305.8748 306.0158 306.1567 306.2977 306.4386 306.5796 306.7205 306.8614 307.0023 307.1432 307.2841 307.4250 307.5658 307.7067 307.8475 307.9883 308.1291 308.2699 308.4107 308.5515 308.6923 308.8330 308.9738 309.1145 309.2552 309.3959 309.5366 309.6773 309.8180 309.9586 310.0993 310.2399 310.3806 310.5212 310.6618 310.8024 310.9429 311.0835 311.2241 311.3646 311.5052 311.6457 311.7862 311.9267 312.0672 312.2077 312.3481 312.4886 312.6290 312.7695 312.9099 313.0503 313.1907 313.3311 313.4714 313.6118 313.7522 313.8925 314.0328 314.1731 314.3135 314.4537 314.5940 314.7343 314.8746 315.0148 315.1550 315.2953 315.4355 315.5757 315.7159 315.8560 315.9962 316.1364 316.2765 316.4166 316.5568 316.6969 316.8370 316.9770 317.1171 317.2572 317.3972 317.5373 317.6773 317.8173 317.9573 318.0973 318.2373 318.3772 318.5172 318.6571 318.7971 318.9370 319.0769 319.2168 319.3567 319.4966 319.6364 319.7763 319.9161 320.0560 320.1958 320.3356 320.4754 320.6151 320.7549 320.8947 321.0344 321.1742 321.3139 321.4536 321.5933 321.7330 321.8727 322.0123 322.1520 322.2916 322.4312 322.5709 322.7105 322.8501 322.9896 323.1292 323.2688 323.4083 323.5479 323.6874 323.8269 323.9664 324.1059 324.2454 324.3848 324.5243 324.6637 324.8031 324.9426 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220915T071459.9Z 8293.302082 157 1 54.38 2 85.57 88.98 34.36 262.69 0.00 1 0.00 1 0 25 4.931e-01 2.447e-02 4.137e-01 1.711e-02 9.878039e-01 9.573926e-03 9.678033e-03 -6.000000e+00 2.670319e-01 226.89 -2.00 3.19 -2.00 322.36 0.00e+00 4.283032e-03 5.602927e-03 1.282129e-03 -6.000000e+00 1.257997e-02 280.99 -2.00 20.00 -2.00 321.94 0.00e+00 10.778 0.013 302.00 328.00 3 2.4336e-01 3.8523e-02 9.5383e-02 -6.0000e+00 6.6816e-01 1.4221e+00 5.0391e-02 5.1260e-02 -6.0000e+00 7.3250e-01 -1.7959e+00 4.3803e-02 2.5543e-02 -6.0000e+00 4.3294e-01 6.8977e-01 2.0968e-02 1.0335e-02 -6.0000e+00 1.8602e-01 4.1567e-05 -6.8757e-04 3.8480e-04 1.0276e-04 -6.0000e+00 1.0311e-02 -1.1286e-03 0.0000e+00 12 8 8 10 0 0 2.20 18.67 1.16 -0.00113 -0.00630 96 10 1 8 0 566.090 15.01 18.67 16.21 23.00 23.25 19.4 778.59 75687 68732 -53810 75733 -44080 -164184 -76664 138075 -113618 -72792 -96539 900000 900000 -79786 33604 -39435 -4550 900000 900000 900000 161543 -43125 -33895 217485 38837 -3814 12716 -57924 -37338 53769 900000 900000 182769 -21795 -53693 33869 39472 25122 -9327 7851 15562 84124 92317 900000 73447 132616 15275 3535 31039 19993 1745 47926 45272 24181 12953 38479 18127 59628 30852 120401 7160 -2240 33834 16400 34574 8167 23938 17265 22678 38903 18390 20821 27303 9757 34083 -1429 -649 -2997 11705 468 11520 5340 6130 2053 8171 -45 624 -7686 7037 -7043 -4623 4006 -11293 -8451 -1526 -3463 -2015 -2 -626 -1792 1942 -331 -6690 -3822 -3191 -1203 -2433 -1397 -2003 -2985 210 -1317 -1359 -1329 -492 -1647 408 -2578 724 363 3779 826 1861 3728 2490 3345 2500 -1316 25 72 1954 -1212 849 -328 -303 12 172 1045 919 -876 -723 -394 -2453 1261 1145 -1537 1261 -847 -8836 -1670 2300 -3639 -1586 -2474 900000 900000 -2862 560 -1415 -122 900000 900000 900000 2691 -1616 -1082 3623 647 -95 265 -2171 -1037 896 900000 900000 3044 -1155 -3415 769 897 723 -452 380 778 2166 2237 900000 2002 2209 740 198 1410 1060 124 2467 2537 1831 1157 2680 1592 3341 2313 3409 608 -228 2762 1885 3743 1088 2751 2243 2984 5249 3370 3815 4593 1755 4258 -217 -90 -444 1716 98 2590 1494 1960 701 2804 -18 254 -3495 2743 -3050 -1779 1334 -4308 -3322 -661 -1875 -1279 -1 -542 -1585 1543 -239 -4324 -2311 -2195 -834 -1811 -1122 -1825 -3246 262 -1865 -1989 -1946 -691 -2216 553 -3788 1106 577 5622 1159 2496 4813 3111 4134 2931 -1677 39 133 4069 -2594 1927 -796 -820 34 487 2990 2654 -2400 -1802 -900 -5271 SS 20220915T072658.7Z 8293.310402 160 1 54.26 2 82.93 90.40 36.92 264.53 0.00 1 0.00 1 0 17 6.220e-01 8.306e-03 2.990e-01 2.687e-03 7.886088e-01 1.408720e-03 7.989913e-03 -6.000000e+00 3.312545e-01 226.89 -2.00 3.19 -2.00 321.64 0.00e+00 1.686448e-03 7.588374e-04 2.844341e-03 -6.000000e+00 1.460128e-02 280.99 -2.00 20.00 -2.00 321.16 0.00e+00 7.497 0.004 302.00 328.00 3 2.5792e-01 5.1908e-03 6.9426e-02 -6.0000e+00 8.2385e-01 8.5159e-02 8.3658e-03 4.2673e-02 -6.0000e+00 8.9740e-01 -1.0352e-01 9.7044e-03 2.4462e-02 -6.0000e+00 5.3388e-01 2.8344e-02 4.4294e-03 8.2235e-03 -6.0000e+00 2.3150e-01 6.4540e-04 3.2886e-05 6.1138e-05 8.1309e-05 -6.0000e+00 1.2893e-02 -1.5892e-03 0.0000e+00 11 8 0 10 0 0 -38.61 18.68 0.65 -0.00159 -0.00134 466 49 1 8 0 116.076 15.00 18.68 16.64 23.00 23.25 19.4 780.87 -234567 -5895 -260072 -183272 -263364 -200094 -132781 -117014 -149985 -196021 -214585 -208608 -180764 -33072 4421 -19086 -48243 -33521 -45544 -27677 -39178 -69939 -70932 -39864 -74627 -50108 -54579 -4570 -70489 -45359 -44733 -33801 -23464 2413 -13187 -41287 -20270 -15826 -12199 -2532 -15532 -5977 -277 -1152 -3713 -2510 -5889 -7009 -2285 -742 -2300 4968 5622 -301 -2347 4022 5887 1222 3960 1758 -430 1377 4058 4977 7011 443 3195 107 1092 2978 2990 3003 2694 565 1410 9 -1233 -3635 -2485 -1026 -2065 -844 -2110 -2586 -1024 -398 573 686 1205 1490 539 479 -499 -1881 -321 -180 -279 989 1191 69 235 -1177 -2094 -1350 -192 -1588 -1264 -1398 -768 206 681 871 433 100 79 -797 276 -703 257 81 278 68 795 783 832 935 -1144 -359 -55 96 652 -736 -213 -999 -85 165 -557 727 525 233 713 -554 -910 -757 -15 -1520 -517 -1433 -565 -348 -307 -393 -948 -1298 -1304 -1263 -87 12 -63 -242 -168 -288 -157 -265 -626 -666 -322 -945 -536 -715 -35 -1008 -530 -682 -580 -436 41 -245 -944 -430 -377 -357 -85 -696 -262 -12 -54 -177 -124 -310 -392 -133 -50 -180 426 523 -33 -290 485 744 162 488 214 -54 189 630 905 1406 90 635 23 252 826 932 979 882 175 396 2 -287 -888 -675 -346 -835 -392 -1135 -1437 -606 -252 375 465 815 974 325 272 -275 -1086 -210 -141 -254 956 1304 77 241 -1096 -1856 -1167 -172 -1472 -1235 -1474 -886 271 1022 1420 715 161 121 -1156 405 -1086 423 139 468 107 1200 1150 1157 1287 -1498 -481 -88 177 1230 -1508 -462 -2282 -214 435 -1482 1960 1321 599 1692 -1243 -1918 SS 20220915T073305.9Z 8293.314651 163 1 54.33 2 81.59 91.13 38.23 265.41 0.00 1 0.00 1 0 17 4.935e-01 7.272e-03 1.020e-01 1.541e-03 7.000485e-01 7.902545e-04 7.072722e-03 -6.000000e+00 2.628035e-01 226.89 -2.00 3.19 -2.00 321.18 0.00e+00 9.974016e-04 3.713039e-04 1.475440e-03 -6.000000e+00 1.158394e-02 280.99 -2.00 20.00 -2.00 320.66 0.00e+00 6.447 0.003 302.00 328.00 3 1.9607e-01 2.6058e-03 5.9243e-02 -6.0000e+00 6.5361e-01 4.8665e-02 3.8328e-03 3.4769e-02 -6.0000e+00 7.1195e-01 -5.4638e-02 4.3240e-03 1.9217e-02 -6.0000e+00 4.2355e-01 9.9190e-03 2.0639e-03 6.3515e-03 -6.0000e+00 1.8367e-01 1.5793e-03 3.7677e-05 3.4867e-05 5.0132e-05 -6.0000e+00 1.0230e-02 -1.7623e-03 0.0000e+00 11 8 0 10 0 0 -14.09 18.69 0.66 -0.00176 -0.00148 762 80 1 8 0 70.947 15.00 18.69 17.00 23.00 23.25 19.4 782.81 -169937 -165964 -171506 -170230 -204742 -173379 -147820 -165422 -147895 -71247 -118116 -132417 -78444 -96359 -70275 -34085 -18986 -39582 -30515 -30807 -33177 -38863 -42217 -31528 -29352 2834 -23060 -20763 -25012 -39629 -19642 -8086 -6753 -870 -13510 -21981 -21566 -10759 -5661 -3859 -2020 -456 1201 -3474 -2875 -1763 -635 -1319 -2925 -2968 1725 2198 2122 4384 2561 1412 3219 2410 966 1367 257 1245 1501 3269 3689 599 1185 -633 1646 2501 871 1539 864 1068 275 -488 -719 -2646 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