File name: Pandora209s1_Izana_20221008_L2Fit_fout2c9d20220720p1-8.txt File generation date: 20250120T091848.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 209 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora209_OF_v3d20210806.txt Instrument calibration file used: Pandora209s1_CF_v9d20220720.txt Level 1 file used: Pandora209s1_Izana_20221008_L1_smca1c9d20220720p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20221008 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0310 305.1721 305.3131 305.4541 305.5951 305.7361 305.8771 306.0180 306.1590 306.2999 306.4409 306.5818 306.7227 306.8636 307.0045 307.1453 307.2862 307.4270 307.5679 307.7087 307.8495 307.9903 308.1311 308.2719 308.4127 308.5534 308.6942 308.8349 308.9756 309.1163 309.2570 309.3977 309.5384 309.6791 309.8197 309.9604 310.1010 310.2416 310.3822 310.5228 310.6634 310.8040 310.9445 311.0851 311.2256 311.3661 311.5067 311.6472 311.7876 311.9281 312.0686 312.2091 312.3495 312.4899 312.6304 312.7708 312.9112 313.0516 313.1919 313.3323 313.4727 313.6130 313.7533 313.8936 314.0340 314.1743 314.3145 314.4548 314.5951 314.7353 314.8756 315.0158 315.1560 315.2962 315.4364 315.5766 315.7167 315.8569 315.9970 316.1372 316.2773 316.4174 316.5575 316.6976 316.8377 316.9777 317.1178 317.2578 317.3979 317.5379 317.6779 317.8179 317.9579 318.0978 318.2378 318.3777 318.5177 318.6576 318.7975 318.9374 319.0773 319.2172 319.3570 319.4969 319.6367 319.7766 319.9164 320.0562 320.1960 320.3358 320.4756 320.6153 320.7551 320.8948 321.0345 321.1743 321.3140 321.4536 321.5933 321.7330 321.8727 322.0123 322.1519 322.2915 322.4312 322.5708 322.7103 322.8499 322.9895 323.1290 323.2686 323.4081 323.5476 323.6871 323.8266 323.9661 324.1056 324.2450 324.3845 324.5239 324.6633 324.8027 324.9421 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221008T074655.2Z 8316.324250 198 1 54.66 2 81.20 101.65 119.73 279.96 0.00 1 0.00 1 0 17 5.802e-01 1.535e-02 3.531e-01 8.171e-03 6.967836e-01 4.186903e-03 7.554271e-03 -6.000000e+00 3.077266e-01 225.94 -2.00 3.19 -2.00 321.17 0.00e+00 3.103316e-03 1.926350e-03 3.733461e-03 -6.000000e+00 1.351219e-02 279.20 -2.00 20.00 -2.00 320.66 0.00e+00 6.199 0.002 302.00 328.00 3 3.3396e+00 1.3679e-02 5.9387e-02 -6.0000e+00 7.6412e-01 2.0814e-01 1.9230e-02 3.8885e-02 -6.0000e+00 8.3329e-01 -2.4092e-01 2.0702e-02 2.1162e-02 -6.0000e+00 4.9559e-01 9.1315e-02 9.9711e-03 6.7478e-03 -6.0000e+00 2.1497e-01 7.7554e-05 -3.1430e-04 1.8544e-04 7.5947e-05 -6.0000e+00 1.1999e-02 1.0611e-03 0.0000e+00 12 8 8 10 0 0 99.92 18.43 0.48 0.00106 -0.00130 63 7 1 8 0 867.283 15.00 18.43 14.94 23.00 23.00 20.1 769.21 -280342 -132986 -145081 -34144 -179184 -178384 -151020 -169017 -41063 80801 -138661 -196330 183994 -173020 74960 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967 448 783 1018 1991 412 56 808 1569 -829 -220 -79 -1847 -1109 1596 -1451 -1880 -1274 -1424 -535 -668 1244 1752 729 -497 -361 -1634 -1566 -364 -825 -1617 1127 676 1758 -1050 -1885 -1189 -1900 -2167 -2213 -1345 -1328 -929 1249 939 2556 -530 -1187 -458 -363 525 -116 -406 1905 1496 -201 1531 2987 1889 2685 -1861 -1039 786 330 1341 -319 -1266 -2253 498 1059 -564 -73 615 805 1377 -2639 -1522 SS 20221008T075917.9Z 8316.332847 204 1 54.29 2 78.54 103.22 122.28 281.72 0.00 1 0.00 1 0 17 2.207e-01 7.056e-03 2.993e-02 8.729e-04 5.755128e-01 4.295655e-04 5.963267e-03 -6.000000e+00 1.170726e-01 225.94 -2.00 3.19 -2.00 320.28 0.00e+00 7.450572e-04 1.545175e-04 6.825476e-04 -6.000000e+00 5.140315e-03 279.19 -2.00 20.00 -2.00 319.71 0.00e+00 4.876 0.001 302.00 328.00 3 7.4715e-01 1.2755e-03 4.5696e-02 -6.0000e+00 2.9071e-01 4.0846e-02 1.6310e-03 2.7222e-02 -6.0000e+00 3.1701e-01 -2.8138e-02 1.6332e-03 1.4185e-02 -6.0000e+00 1.8854e-01 -3.7283e-04 8.3621e-04 4.4228e-03 -6.0000e+00 8.1789e-02 3.1590e-03 -1.5458e-04 1.9982e-05 3.2746e-05 -6.0000e+00 4.5660e-03 3.5267e-04 0.0000e+00 11 8 0 10 0 0 -12.21 18.42 0.57 0.00035 -0.00081 911 96 1 8 0 59.239 15.00 18.42 16.58 22.75 23.25 20.6 778.43 -73669 -72166 -62535 -69954 -89986 -69778 -85667 -73751 -59637 -67156 -61324 -56424 -39138 -29294 -28425 -17722 -20496 -15116 -15185 -12558 -10139 -15592 -12593 -8511 -8101 -5911 -9701 -8595 -9698 -11261 -8832 -4923 -2927 -1943 -7208 -10139 -6481 -4742 -3308 68 -155 757 272 -400 1333 1207 495 685 -443 -1506 523 1181 1172 2178 666 1056 2072 1011 618 -288 -35 712 1580 3215 2503 -139 356 -1538 22 1625 1276 1263 711 886 547 -569 -944 -2845 -2172 -929 -1042 -594 -1560 -2165 -1264 -670 58 211 1046 923 641 891 -335 -403 -113 -81 -136 890 626 560 163 -1037 -1437 -825 -256 -1330 -919 -943 -695 257 551 603 222 178 150 -536 127 -461 140 28 86 73 661 486 939 949 -635 -182 183 28 822 -566 -195 -848 -110 160 -363 503 308 253 444 -586 -718 -538 -614 -532 -650 -868 -530 -839 -743 -605 -838 -727 -664 -494 -467 -557 -389 -506 -393 -430 -366 -305 -480 -386 -286 -295 -225 -405 -335 -361 -430 -400 -278 -187 -143 -508 -680 -478 -398 -344 8 -22 114 44 -67 214 202 84 118 -81 -284 108 277 294 598 198 320 658 325 191 -87 -11 238 592 1354 1155 -60 150 -668 10 879 773 798 454 529 303 -279 -423 -1281 -1049 -543 -707 -416 -1235 -1758 -1101 -627 56 212 1047 897 569 734 -261 -312 -98 -81 -156 1069 842 743 201 -1174 -1559 -887 -289 -1556 -1127 -1234 -974 399 877 1019 371 286 224 -808 193 -732 221 46 142 114 1008 777 1404 1398 -879 -254 274 47 1489 -1093 -364 -1639 -233 355 -814 1074 667 557 918 -1157 -1337 SS 20221008T080509.2Z 8316.336913 207 1 54.29 2 77.29 103.98 123.47 282.58 0.00 1 0.00 1 0 17 1.314e-01 6.787e-03 1.906e-02 6.804e-04 5.283061e-01 3.315871e-04 5.548075e-03 -6.000000e+00 6.968440e-02 225.94 -2.00 3.19 -2.00 319.93 0.00e+00 4.591247e-04 1.063748e-04 4.399779e-04 -6.000000e+00 3.059603e-03 279.19 -2.00 20.00 -2.00 319.35 0.00e+00 4.429 0.001 302.00 328.00 3 6.9632e-01 9.5241e-04 4.1628e-02 -6.0000e+00 1.7303e-01 2.8921e-02 1.1778e-03 2.4797e-02 -6.0000e+00 1.8869e-01 -1.4638e-02 1.1144e-03 1.2666e-02 -6.0000e+00 1.1222e-01 -5.6632e-03 5.8278e-04 3.8242e-03 -6.0000e+00 4.8683e-02 4.8520e-03 -1.2552e-04 1.5532e-05 2.8536e-05 -6.0000e+00 2.7179e-03 2.1744e-04 0.0000e+00 11 8 0 10 0 0 -8.08 18.42 0.55 0.00022 -0.00073 1169 123 1 8 0 46.087 15.00 18.42 17.51 23.00 23.00 20.8 783.31 -44441 -44625 -34747 -40661 -46201 -48629 -58134 -43540 -31642 -34923 -32580 -35685 -25071 -22114 -14075 -9301 -11116 -9072 -6556 -7164 -7712 -5504 -7390 -5483 -3495 -3223 -2814 -5650 -8052 -7611 -5556 -2915 79 -1900 -5754 -7534 -4748 -3983 -1129 -232 -114 -650 311 -160 760 389 -86 126 -849 -1220 203 1399 749 2019 728 871 1241 1365 653 41 -65 795 1299 2470 2153 -251 286 -1589 -148 1528 1306 1436 459 929 384 -339 -566 -2505 -1593 -842 -1179 -911 -1810 -2195 -1211 -742 131 378 993 830 582 933 -173 -314 38 13 -95 907 655 447 122 -798 -1381 -957 -115 -1325 -803 -989 -508 246 563 621 259 129 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