File name: Pandora209s1_Izana_20221011_L2Fit_fwvt1c5d20220720p1-8.txt File generation date: 20250217T101016.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c5p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 209 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora209_OF_v3d20210806.txt Instrument calibration file used: Pandora209s1_CF_v5d20220720.txt Level 1 file used: Pandora209s1_Izana_20221011_L1_smca1c5d20220720p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20221011 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1618 1768 Nominal wavelengths inside fitting window [nm]: 492.0328 492.1538 492.2748 492.3958 492.5167 492.6377 492.7586 492.8796 493.0005 493.1213 493.2422 493.3631 493.4839 493.6047 493.7255 493.8463 493.9671 494.0878 494.2085 494.3293 494.4500 494.5706 494.6913 494.8119 494.9326 495.0532 495.1738 495.2944 495.4149 495.5355 495.6560 495.7765 495.8970 496.0175 496.1379 496.2583 496.3788 496.4992 496.6196 496.7399 496.8603 496.9806 497.1009 497.2212 497.3415 497.4618 497.5820 497.7023 497.8225 497.9427 498.0629 498.1830 498.3032 498.4233 498.5434 498.6635 498.7836 498.9036 499.0237 499.1437 499.2637 499.3837 499.5037 499.6236 499.7435 499.8635 499.9834 500.1032 500.2231 500.3430 500.4628 500.5826 500.7024 500.8222 500.9419 501.0617 501.1814 501.3011 501.4208 501.5405 501.6601 501.7798 501.8994 502.0190 502.1386 502.2581 502.3777 502.4972 502.6167 502.7362 502.8557 502.9752 503.0946 503.2141 503.3335 503.4528 503.5722 503.6916 503.8109 503.9302 504.0495 504.1688 504.2881 504.4073 504.5266 504.6458 504.7650 504.8841 505.0033 505.1225 505.2416 505.3607 505.4798 505.5988 505.7179 505.8369 505.9559 506.0749 506.1939 506.3129 506.4318 506.5508 506.6697 506.7886 506.9074 507.0263 507.1451 507.2639 507.3827 507.5015 507.6203 507.7390 507.8578 507.9765 508.0952 508.2138 508.3325 508.4511 508.5698 508.6884 508.8069 508.9255 509.0441 509.1626 509.2811 509.3996 509.5181 509.6365 509.7550 509.8734 509.9918 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20221011T070801.3Z 8319.297237 193 1 14.63 2 90.01 98.00 73.51 275.29 0.00 1 0.00 1 0 22 9.844e-03 9.686e-03 2.179e-04 2.173e-04 1.247206e+04 1.398048e+01 8.743266e+02 -6.000000e+00 5.100407e+02 278.96 -2.00 20.00 -2.00 505.40 0.00e+00 1.645079e-03 5.831049e-06 1.077643e-04 -6.000000e+00 2.676892e-04 278.96 -2.00 20.00 -2.00 500.98 0.00e+00 1.101457e+00 4.080346e-03 8.345012e-02 -6.000000e+00 1.888499e-01 225.82 -2.00 3.19 -2.00 502.49 0.00e+00 20.745 0.092 489.00 513.00 1 1.2873e+00 3.1114e-04 2.5811e-02 -6.0000e+00 1.4433e-02 -5.8815e-02 7.9387e-05 2.5022e-03 -6.0000e+00 3.7792e-03 5.0871e-02 4.2802e-04 1.6318e-05 1.1534e-04 -6.0000e+00 7.9744e-04 3.8242e-03 -1.6580e-05 12 8 8 10 0 0 -11.26 18.49 1.97 0.00382 0.00679 525 55 1 2 0 27.505 15.00 18.49 13.58 22.75 23.00 19.8 759.41 -2109 -1688 -432 396 476 1219 1627 1958 1697 1124 797 488 -72 -311 -535 -1079 -593 246 973 909 846 730 585 880 1125 981 805 673 -491 -1363 -2187 -2624 -2182 -425 155 191 165 -20 -384 -505 -220 -132 252 639 990 956 955 739 501 -131 -921 -1603 -2185 -1952 -910 -14 436 631 442 230 514 685 877 925 884 466 -80 -187 -380 -930 -1019 -1211 -975 -254 211 40 -814 -1055 -1489 -1562 -1215 -1125 -1115 -784 -365 -582 -337 -244 -398 -534 -308 278 1246 1354 1304 1068 184 -168 -670 -1774 -2229 -2285 -1363 65 490 388 -211 -1050 -1153 -649 -284 24 659 894 901 1214 1637 1668 1404 1071 370 -23 -26 784 653 701 854 435 465 982 467 -81 -351 -1082 -1316 -342 -187 89 378 583 325 530 659 720 911 812 405 -654 -1113 -1456 -1032 -1842 -1491 -391 374 443 1149 1567 1910 1664 1095 767 467 -69 -291 -499 -1019 -565 239 933 889 828 718 577 870 1123 986 809 676 -488 -1307 -2070 -2512 -2116 -422 154 193 165 -19 -377 -512 -214 -130 250 643 1008 982 978 751 503 -130 -889 -1579 -2133 -1910 -874 -14 445 651 457 238 529 684 883 933 888 463 -82 -189 -382 -928 -1005 -1204 -980 -258 209 40 -796 -1052 -1474 -1537 -1195 -1119 -1077 -761 -359 -583 -338 -243 -395 -531 -308 280 1270 1382 1301 1034 174 -161 -629 -1652 -2073 -2166 -1336 65 489 395 -216 -1066 -1156 -651 -291 25 686 934 945 1274 1677 1743 1480 1118 382 -23 -27 781 660 713 872 448 477 1006 481 -83 -351 -1088 -1327 -348 -196 92 394 618 351 575 696 765 969 862 441 -703 -1178 -1542 -1102 SQ 20221011T070816.1Z 8319.297409 193 2 14.63 2 89.96 98.03 73.57 275.32 0.00 1 0.00 1 0 22 9.541e-03 9.396e-03 2.093e-04 2.087e-04 1.213924e+04 1.339095e+01 8.487638e+02 -6.000000e+00 4.943495e+02 278.96 -2.00 20.00 -2.00 505.40 0.00e+00 1.591342e-03 5.593531e-06 1.043294e-04 -6.000000e+00 2.594560e-04 278.96 -2.00 20.00 -2.00 500.96 0.00e+00 1.109663e+00 3.924573e-03 8.150186e-02 -6.000000e+00 1.830336e-01 225.82 -2.00 3.19 -2.00 502.47 0.00e+00 20.692 0.092 489.00 513.00 1 1.2192e+00 2.9950e-04 2.5675e-02 -6.0000e+00 1.3988e-02 -5.6580e-02 7.6426e-05 2.4527e-03 -6.0000e+00 3.6627e-03 5.4800e-02 2.8802e-04 1.5655e-05 1.1211e-04 -6.0000e+00 7.7290e-04 4.4968e-03 -1.7586e-05 12 8 8 10 0 0 -6.06 18.48 1.91 0.00450 0.00649 525 55 1 2 0 27.505 15.00 18.48 13.58 22.75 23.00 19.8 759.41 -2096 -1661 -482 337 455 1196 1625 1841 1639 1119 739 436 -25 -295 -475 -1022 -587 253 986 989 792 722 527 881 1123 920 782 679 -375 -1296 -2112 -2482 -2072 -313 202 210 166 -1 -320 -487 -251 -134 296 608 942 924 980 708 496 -147 -894 -1544 -2178 -1927 -850 -48 472 581 419 193 441 676 834 892 882 450 -54 -152 -331 -874 -984 -1182 -992 -237 224 53 -735 -984 -1417 -1527 -1203 -1107 -1078 -691 -336 -596 -282 -252 -378 -500 -335 275 1201 1306 1286 1082 200 -134 -648 -1691 -2171 -2271 -1311 -20 477 373 -257 -1013 -1110 -645 -238 65 598 854 825 1205 1585 1681 1331 1089 364 -26 -7 731 593 652 833 382 356 972 456 -61 -313 -1033 -1277 -299 -151 62 333 546 307 526 636 660 842 809 373 -603 -1081 -1412 -1042 -1898 -1454 -434 316 420 1120 1554 1786 1597 1082 707 414 -24 -274 -440 -958 -556 244 980 961 772 706 517 866 1115 920 782 678 -370 -1286 -2069 -2456 -1995 -309 208 211 164 -1 -325 -491 -252 -131 292 609 954 944 998 716 496 -144 -893 -1508 -2109 -1871 -844 -47 477 596 431 198 451 697 867 896 882 462 -55 -153 -330 -865 -964 -1166 -989 -238 228 54 -741 -974 -1392 -1493 -1174 -1093 -1075 -692 -328 -594 -281 -250 -373 -494 -333 275 1218 1327 1278 1043 196 -128 -605 -1565 -2007 -2141 -1278 -19 474 378 -261 -1024 -1107 -645 -242 67 620 889 861 1259 1619 1749 1398 1133 374 -26 -7 752 598 661 848 391 364 992 467 -61 -312 -1034 -1282 -303 -157 64 346 577 330 569 671 701 894 857 405 -646 -1140 -1488 -1108 SQ 20221011T070830.9Z 8319.297580 193 3 14.63 2 89.91 98.06 73.62 275.34 0.00 1 0.00 1 0 22 9.295e-03 9.145e-03 2.009e-04 2.003e-04 1.193778e+04 1.284539e+01 8.354303e+02 -6.000000e+00 4.816063e+02 278.96 -2.00 20.00 -2.00 505.40 0.00e+00 1.580483e-03 5.369168e-06 1.032025e-04 -6.000000e+00 2.527676e-04 278.96 -2.00 20.00 -2.00 500.94 0.00e+00 1.106377e+00 3.770434e-03 8.020756e-02 -6.000000e+00 1.783151e-01 225.82 -2.00 3.19 -2.00 502.46 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