File name: Pandora209s1_Izana_20221015_L2Fit_fout2c9d20220720p1-8.txt File generation date: 20250120T092102.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 209 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora209_OF_v3d20210806.txt Instrument calibration file used: Pandora209s1_CF_v9d20220720.txt Level 1 file used: Pandora209s1_Izana_20221015_L1_smca1c9d20220720p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20221015 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0310 305.1721 305.3131 305.4541 305.5951 305.7361 305.8771 306.0180 306.1590 306.2999 306.4409 306.5818 306.7227 306.8636 307.0045 307.1453 307.2862 307.4270 307.5679 307.7087 307.8495 307.9903 308.1311 308.2719 308.4127 308.5534 308.6942 308.8349 308.9756 309.1163 309.2570 309.3977 309.5384 309.6791 309.8197 309.9604 310.1010 310.2416 310.3822 310.5228 310.6634 310.8040 310.9445 311.0851 311.2256 311.3661 311.5067 311.6472 311.7876 311.9281 312.0686 312.2091 312.3495 312.4899 312.6304 312.7708 312.9112 313.0516 313.1919 313.3323 313.4727 313.6130 313.7533 313.8936 314.0340 314.1743 314.3145 314.4548 314.5951 314.7353 314.8756 315.0158 315.1560 315.2962 315.4364 315.5766 315.7167 315.8569 315.9970 316.1372 316.2773 316.4174 316.5575 316.6976 316.8377 316.9777 317.1178 317.2578 317.3979 317.5379 317.6779 317.8179 317.9579 318.0978 318.2378 318.3777 318.5177 318.6576 318.7975 318.9374 319.0773 319.2172 319.3570 319.4969 319.6367 319.7766 319.9164 320.0562 320.1960 320.3358 320.4756 320.6153 320.7551 320.8948 321.0345 321.1743 321.3140 321.4536 321.5933 321.7330 321.8727 322.0123 322.1519 322.2915 322.4312 322.5708 322.7103 322.8499 322.9895 323.1290 323.2686 323.4081 323.5476 323.6871 323.8266 323.9661 324.1056 324.2450 324.3845 324.5239 324.6633 324.8027 324.9421 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20221015T073908.2Z 8323.318845 205 1 54.37 2 83.81 103.20 33.11 276.44 0.00 1 0.00 1 0 17 8.252e-01 1.459e-02 2.649e-01 4.649e-03 8.709573e-01 2.482452e-03 8.787669e-03 -6.000000e+00 4.372514e-01 225.65 -2.00 3.19 -2.00 321.94 0.00e+00 5.516400e-03 1.356961e-03 2.357565e-03 -6.000000e+00 1.917464e-02 278.65 -2.00 20.00 -2.00 321.49 0.00e+00 8.368 0.006 302.00 328.00 3 4.3221e-01 9.0818e-03 7.6287e-02 -6.0000e+00 1.0852e+00 3.8675e-01 1.4830e-02 4.4654e-02 -6.0000e+00 1.1837e+00 -5.2246e-01 1.6984e-02 2.6723e-02 -6.0000e+00 7.0396e-01 2.0375e-01 7.6894e-03 1.1053e-02 -6.0000e+00 3.0546e-01 2.5765e-04 -6.5072e-04 1.0327e-04 9.8223e-05 -6.0000e+00 1.7075e-02 -2.3225e-04 0.0000e+00 12 8 8 10 0 0 99.82 18.71 0.66 -0.00023 -0.00512 327 34 1 8 0 165.916 15.00 18.71 10.55 23.00 23.25 19.6 746.68 -291664 -196502 -282404 -237679 -274052 -307462 -259081 -121575 -277526 -288170 -241311 -233274 -94607 -120275 -108234 -53538 -52193 -110467 -10596 -57040 -98207 -70828 -137730 -85440 -94115 -42935 -72080 -68896 -82489 -32675 -45120 -56394 -17959 -39877 -7304 -48456 -12323 -28111 676 23841 3280 25646 9154 4344 17406 -1588 -5446 6585 -1379 10943 14737 19668 18062 18752 17575 9101 15833 17985 8724 5936 8392 6547 4119 20661 17691 7751 8610 1564 5848 11207 6657 6700 8045 1976 4862 688 1307 -3090 -3537 -2274 580 796 1109 -2736 -824 512 425 1555 3195 1357 500 421 -2712 -2127 -426 -2074 -1604 -231 -354 202 -416 -1608 -2946 -2507 -1640 -2220 -2249 -1644 -1503 -8 255 144 325 -44 19 -1252 -533 -323 415 817 923 732 1469 1517 1536 1525 -470 -84 449 238 1458 -317 11 -862 -46 148 -437 267 588 375 353 -883 -1302 -2834 -891 -3644 -1990 -2772 -4075 -2259 -551 -3581 -4623 -2441 -2360 -429 -755 -859 -324 -355 -1544 -60 -539 -1447 -749 -2862 -1194 -1529 -438 -1035 -911 -1216 -337 -707 -1255 -326 -1068 -129 -1178 -234 -718 16 560 110 729 328 170 588 -68 -249 282 -70 523 778 1275 1294 1496 1530 887 1522 1680 843 565 780 692 521 2642 2647 1219 1363 281 1084 2409 1678 1756 2072 495 1071 137 239 -615 -805 -652 193 309 493 -1299 -413 272 235 880 1781 747 253 201 -1300 -1057 -243 -1454 -1320 -223 -391 223 -430 -1502 -2363 -1945 -1445 -2019 -2166 -1703 -1729 -11 355 221 506 -68 29 -1754 -758 -480 657 1340 1474 1081 2082 2098 2016 1988 -585 -107 701 433 2957 -709 27 -2174 -117 395 -1178 728 1615 967 838 -2146 -2952 SS 20221015T074513.1Z 8323.323068 208 1 54.35 2 82.51 103.96 34.41 276.92 0.00 1 0.00 1 0 17 7.158e-01 9.546e-03 1.223e-01 2.220e-03 7.757509e-01 1.144628e-03 7.906625e-03 -6.000000e+00 3.792736e-01 225.65 -2.00 3.19 -2.00 321.50 0.00e+00 8.097041e-04 5.830384e-04 2.525774e-03 -6.000000e+00 1.663206e-02 278.65 -2.00 20.00 -2.00 321.02 0.00e+00 7.133 0.004 302.00 328.00 3 3.6032e-01 4.0232e-03 6.6421e-02 -6.0000e+00 9.4134e-01 1.4032e-01 6.2199e-03 4.0976e-02 -6.0000e+00 1.0268e+00 -1.9065e-01 7.1354e-03 2.2467e-02 -6.0000e+00 6.1061e-01 6.7089e-02 3.3097e-03 7.1063e-03 -6.0000e+00 2.6496e-01 7.6212e-04 -3.1683e-04 5.0263e-05 7.3720e-05 -6.0000e+00 1.4812e-02 -2.8919e-04 0.0000e+00 12 8 8 10 0 0 93.50 18.72 0.62 -0.00029 -0.00267 568 60 1 8 0 95.326 15.00 18.72 10.93 23.00 23.25 19.6 748.78 -271393 -224108 -236209 -206958 -237933 -210778 -274123 -202481 -176026 -227650 -182669 -191927 -117830 -145887 -87388 -97509 -100807 -54978 -61410 -46499 -53391 -67767 -55261 -65081 -43256 -58658 -41593 -28935 -56883 -51880 -37096 -12253 -11833 -16997 -21462 -20425 -23015 -2982 -5305 1658 11218 -2777 4325 -2426 2605 2477 1798 2835 2857 3051 656 5316 5197 8060 5527 7495 6139 3621 2380 202 2409 2505 3357 7061 4232 2096 2614 506 1209 3111 4219 2217 2229 2314 715 -73 -1992 -3583 -1620 -150 -960 -440 -1323 -2372 -1264 -467 214 527 692 961 -4 390 -591 -2080 -1639 -550 -686 771 697 434 -370 -1066 -2086 -1320 -576 -1380 -1081 -980 -791 222 737 536 333 124 -155 -673 92 -443 235 390 398 191 781 658 1286 1155 -1131 -554 117 105 768 -802 -168 -932 -43 194 -323 638 477 222 342 -563 -824 -2215 -1381 -1849 -1241 -1664 -1088 -2967 -1248 -967 -2426 -1278 -1731 -680 -1500 -646 -1038 -1255 -496 -654 -453 -588 -831 -618 -939 -554 -942 -655 -382 -952 -858 -686 -219 -252 -452 -549 -478 -630 -78 -181 66 475 -145 225 -140 140 140 104 170 204 231 58 526 560 949 723 998 883 535 338 28 330 381 586 1399 967 461 574 119 304 939 1413 791 796 765 219 -20 -504 -941 -467 -54 -409 -217 -749 -1395 -794 -313 148 378 497 667 -2 233 -343 -1261 -1137 -451 -595 775 796 495 -396 -1030 -1745 -1185 -536 -1326 -1094 -1067 -943 301 1141 904 566 207 -246 -1000 139 -699 395 685 687 307 1210 993 1825 1625 -1517 -759 192 182 1468 -1669 -369 -2152 -102 475 -800 1604 1213 533 822 -1274 -1748 SS 20221015T075517.2Z 8323.330060 211 1 4.39 2 80.36 105.24 36.56 277.69 0.00 1 0.00 1 0 17 3.630e-01 1.006e-02 9.071e-02 3.600e-03 6.428019e-01 1.756762e-03 6.768326e-03 -6.000000e+00 1.923547e-01 225.65 -2.00 3.19 -2.00 320.00 0.00e+00 2.062955e-03 5.800486e-04 1.145325e-03 -6.000000e+00 8.435045e-03 278.65 -2.00 20.00 -2.00 319.43 0.00e+00 5.711 0.002 302.00 328.00 3 6.4634e-01 5.0815e-03 5.2615e-02 -6.0000e+00 4.7742e-01 5.5032e-02 6.3477e-03 3.0363e-02 -6.0000e+00 5.2074e-01 -6.9872e-02 6.1544e-03 1.6093e-02 -6.0000e+00 3.0968e-01 1.9297e-02 3.1993e-03 5.4183e-03 -6.0000e+00 1.3438e-01 1.8020e-03 -2.0350e-04 7.7891e-05 4.0665e-05 -6.0000e+00 7.5128e-03 -5.4223e-04 0.0000e+00 12 9 9 12 1 1 92.32 18.72 0.60 -0.00054 -0.00207 41 71 1 8 0 79.971 15.00 18.72 11.46 23.25 23.25 19.6 750.62 -161589 -121654 -126628 -108702 -138194 -103526 -103088 -97073 -95036 -71965 -124870 -117592 -74364 -52404 -27228 -21921 -23542 -31143 -20787 -25838 -18386 -41622 -20130 -10403 -25710 -14718 -7154 -11473 -7953 -24618 -7125 -7187 73 -6832 -5704 -4826 -2403 -7284 2309 -585 3058 -1137 92 -696 -672 3598 320 2988 -2166 -603 1187 5625 2006 3368 3864 2843 1334 3939 1079 2584 261 1021 2617 3687 3390 -250 1777 -1374 987 1189 1354 1042 375 1390 -594 -779 -1057 -2169 -2697 -2613 -1540 -825 -1380 -1989 -1334 -687 -50 289 1152 469 48 500 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