File name: Pandora209s1_Izana_20230518_L2Fit_fout2c8d20230220p1-8.txt File generation date: 20250217T121654.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 209 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora209_OF_v3d20210806.txt Instrument calibration file used: Pandora209s1_CF_v8d20230220.txt Level 1 file used: Pandora209s1_Izana_20230518_L1_smca1c8d20230220p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20230518 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0129 305.1539 305.2949 305.4359 305.5769 305.7179 305.8589 305.9999 306.1408 306.2817 306.4227 306.5636 306.7045 306.8454 306.9863 307.1272 307.2680 307.4089 307.5497 307.6905 307.8313 307.9722 308.1129 308.2537 308.3945 308.5353 308.6760 308.8167 308.9575 309.0982 309.2389 309.3796 309.5202 309.6609 309.8016 309.9422 310.0828 310.2235 310.3641 310.5047 310.6453 310.7858 310.9264 311.0670 311.2075 311.3480 311.4885 311.6290 311.7695 311.9100 312.0505 312.1910 312.3314 312.4718 312.6123 312.7527 312.8931 313.0335 313.1739 313.3142 313.4546 313.5949 313.7353 313.8756 314.0159 314.1562 314.2965 314.4368 314.5770 314.7173 314.8575 314.9978 315.1380 315.2782 315.4184 315.5586 315.6987 315.8389 315.9790 316.1192 316.2593 316.3994 316.5395 316.6796 316.8197 316.9598 317.0998 317.2399 317.3799 317.5199 317.6599 317.7999 317.9399 318.0799 318.2199 318.3598 318.4998 318.6397 318.7796 318.9195 319.0594 319.1993 319.3392 319.4790 319.6189 319.7587 319.8985 320.0384 320.1782 320.3179 320.4577 320.5975 320.7372 320.8770 321.0167 321.1564 321.2962 321.4358 321.5755 321.7152 321.8549 321.9945 322.1342 322.2738 322.4134 322.5530 322.6926 322.8322 322.9717 323.1113 323.2509 323.3904 323.5299 323.6694 323.8089 323.9484 324.0879 324.2273 324.3668 324.5062 324.6457 324.7851 324.9245 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230518T073737.6Z 8538.317796 102 1 11.30 2 73.43 76.37 61.30 87.36 0.00 1 0.00 1 0 17 1.530e-01 1.812e-02 1.527e-01 1.510e-02 4.634656e-01 7.317863e-03 4.906020e-03 -6.000000e+00 8.229095e-02 229.21 -2.00 3.19 -2.00 318.72 0.00e+00 1.703633e-03 1.572050e-03 2.124706e-04 -6.000000e+00 3.555458e-03 278.44 -2.00 20.00 -2.00 318.10 0.00e+00 3.453 0.000 302.00 328.00 3 5.5025e+00 1.9956e-02 3.4167e-02 -6.0000e+00 2.0596e-01 1.4425e-01 2.2907e-02 2.1705e-02 -6.0000e+00 2.2390e-01 -1.2834e-01 1.6728e-02 1.0817e-02 -6.0000e+00 1.3276e-01 5.1041e-02 9.0086e-03 3.5109e-03 -6.0000e+00 5.7266e-02 8.2211e-05 -1.0845e-04 3.3718e-04 2.3025e-05 -6.0000e+00 3.1874e-03 5.0575e-03 0.0000e+00 12 9 9 12 1 1 999.00 18.29 0.27 0.00506 0.00424 2 3 1 8 0 2248.506 15.00 18.29 8.25 22.75 23.00 21.1 729.17 -70962 -34106 -44257 -38276 15622 25645 19193 -81381 -23032 -6118 72063 -41480 -35786 -14700 -27000 -19239 8373 -8639 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-603 -826 632 -1454 -4041 -3053 -1280 -2712 -1737 -1547 -3893 -1907 212 -1900 -638 -1592 2172 -2172 2119 2265 -893 731 -914 -1260 1635 2065 884 164 -1615 -155 972 1616 -1085 -707 430 -748 -287 1301 2465 -248 -1487 -114 -249 1261 1676 491 -17 -2214 -879 4254 -120 531 936 -639 498 781 -69 -219 -33 1454 -1573 -1584 -640 -2189 3381 -21 -1981 4906 -825 -3492 SS 20230518T074319.0Z 8538.321748 106 1 54.01 2 72.21 76.96 60.07 87.96 0.00 1 0.00 1 0 17 1.780e-01 9.473e-03 1.513e-01 7.009e-03 4.272431e-01 3.420427e-03 4.492744e-03 -6.000000e+00 9.576198e-02 229.21 -2.00 3.19 -2.00 319.60 0.00e+00 1.079156e-04 9.618197e-04 4.448190e-04 -6.000000e+00 4.207517e-03 278.44 -2.00 20.00 -2.00 319.01 0.00e+00 3.230 0.000 302.00 328.00 3 5.2232e+00 9.6328e-03 3.1868e-02 -6.0000e+00 2.3960e-01 5.2976e-02 1.1521e-02 2.0285e-02 -6.0000e+00 2.6051e-01 -1.7494e-02 9.9665e-03 1.0158e-02 -6.0000e+00 1.5446e-01 8.5917e-04 5.2871e-03 2.9320e-03 -6.0000e+00 6.6726e-02 1.3744e-04 2.6327e-05 1.6473e-04 2.1672e-05 -6.0000e+00 3.7984e-03 6.5434e-03 0.0000e+00 12 8 8 10 0 0 99.97 18.28 0.97 0.00654 0.00674 141 15 1 8 0 382.680 15.00 18.28 8.52 22.75 23.00 21.1 729.78 54569 -54747 152477 -41247 900000 -73564 17475 -14244 -10419 14820 -32890 -20602 -33888 19269 -28966 14235 -1925 8086 -5672 7444 8682 -6069 -12876 9432 -7584 -3588 740 10373 -10882 2285 -4653 8090 -1522 12747 3722 8767 -4218 -8981 5276 -3090 -2584 -915 -1985 -1875 94 -160 -1944 4637 -1563 3196 -336 1101 3868 3545 -2347 -4339 283 1585 1229 114 5193 3014 -558 675 1714 -1688 275 -2565 -915 2021 1809 2242 871 120 1326 -39 -275 -1522 -2085 524 -1029 -690 -615 -3396 -1097 -813 379 456 840 450 489 980 428 -637 -244 19 3 1686 -499 -701 104 -656 -116 -450 -988 -1484 -1341 -721 -902 634 326 388 740 -412 797 -74 675 -721 -279 263 -257 -465 1180 913 498 1484 -508 -538 444 -44 520 -521 651 -1207 432 191 -252 216 153 -115 -217 -22 -709 430 -1496 1042 -1062 900000 -2049 211 -270 -219 273 -1049 -575 -1293 527 -1518 584 -99 401 -346 415 504 -397 -902 591 -605 -290 66 786 -940 168 -416 724 -166 1394 405 817 -506 -1289 813 -637 -602 -219 -503 -489 23 -41 -505 1112 -406 867 -102 372 1340 1337 -993 -1898 124 688 514 47 2047 1320 -282 375 1010 -931 140 -1325 -477 1232 1239 1593 637 84 855 -23 -142 -760 -1080 317 -725 -543 -538 -3094 -1056 -846 408 510 945 495 490 900 362 -522 -215 19 4 2130 -717 -997 136 -794 -123 -478 -1218 -1898 -1789 -1012 -1338 1010 520 646 1198 -638 1235 -106 962 -1081 -448 451 -411 -782 1916 1434 731 2113 -683 -710 660 -72 827 -872 1106 -2132 823 385 -517 450 327 -236 -420 -40 -1247 SS 20230518T075134.8Z 8538.327486 111 1 53.01 2 70.43 77.80 58.28 88.85 0.00 1 0.00 1 0 25 1.322e-01 8.967e-03 1.137e-01 6.015e-03 3.963949e-01 2.941230e-03 4.223797e-03 -6.000000e+00 7.109433e-02 229.21 -2.00 3.19 -2.00 319.23 0.00e+00 5.119799e-04 7.328270e-04 1.810861e-04 -6.000000e+00 3.072008e-03 278.44 -2.00 20.00 -2.00 318.61 0.00e+00 2.954 0.000 302.00 328.00 3 5.3346e+00 8.1491e-03 2.9327e-02 -6.0000e+00 1.7794e-01 6.5027e-02 9.5257e-03 1.8738e-02 -6.0000e+00 1.9345e-01 -2.6616e-02 7.6091e-03 9.4070e-03 -6.0000e+00 1.1470e-01 3.7188e-03 4.0757e-03 2.7908e-03 -6.0000e+00 4.9469e-02 1.5627e-04 -1.4821e-04 1.4113e-04 1.9751e-05 -6.0000e+00 2.7528e-03 6.1956e-03 0.0000e+00 11 8 0 10 0 0 99.99 18.27 0.59 0.00620 0.00508 107 11 1 8 0 495.042 14.98 18.27 8.33 22.75 23.00 20.8 728.10 -15428 -2756 26584 -10109 134541 -34028 13324 -16565 4122 -6557 31376 -19253 -13210 -14797 -14292 4515 -9596 974 8899 -2126 5993 -9719 -2412 -5410 -10288 1918 7694 -9606 -12513 3757 -552 1041 1289 2234 1910 -4132 -1275 1828 -5736 327 519 228 -429 428 -1971 -47 1412 2439 -1082 -1045 -2522 786 -744 2596 592 1823 1990 754 376 -1185 -894 1021 -570 2996 2517 -696 1864 -477 898 2243 285 871 -906 671 1408 -666 941 -728 -744 -236 -592 -295 -2305 -3677 -2122 -1255 503 -168 1495 1168 -540 376 985 1082 -53 278 122 818 253 -86 -110 122 -1406 -556 -88 -903 -1129 -883 -813 -136 81 463 646 347 483 -753 330 102 -744 -130 344 -405 623 533 911 1384 -92 152 -209 218 1181 -753 -248 -723 359 427 -746 516 526 -629 638 -632 -738 -362 -66 504 -278 789 -921 241 -456 115 -228 736 -734 -562 -774 -873 274 -708 69 618 -171 469 -865 -198 -554 -1180 205 812 -1132 -1395 343 -59 124 168 332 259 -533 -180 285 -1187 78 140 64 -127 130 -595 -14 419 704 -327 -344 -906 306 -309 1128 277 850 969 373 179 -561 -424 516 -325 1821 1643 -424 1029 -265 502 1488 217 684 -736 508 995 -423 524 -392 -410 -154 -444 -247 -2189 -3575 -2194 -1396 575 -202 1781 1360 -583 370 880 917 -49 291 143 1081 341 -115 -150 152 -1576 -615 -111 -1196 -1566 -1175 -1135 -204 133 790 1072 545 696 -1002 478 140 -1109 -207 558 -634 947 782 1238 2014 -126 203 -287 325 1872 -1269 -424 -1268 682 855 -1534 1071 1116 -1294 1226 -1184 -1307 SS 20230518T080310.8Z 8538.335541 119 1 30.90 2 67.93 78.98 55.77 90.11 0.00 1 0.00 1 0 17 2.521e-02 6.787e-03 6.373e-03 7.784e-04 3.550891e-01 3.739106e-04 3.801837e-03 -6.000000e+00 1.356144e-02 229.21 -2.00 3.19 -2.00 318.60 0.00e+00 4.811087e-04 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