File name: Pandora209s1_Izana_20241206_L2Fit_fout2c4d20221111p1-8.txt File generation date: 20241207T010242.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 209 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora209_OF_v3d20210806.txt Instrument calibration file used: Pandora209s1_CF_v4d20221111.txt Level 1 file used: Pandora209s1_Izana_20241206_L1_smca1c4d20221111p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20241206 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0169 305.1580 305.2990 305.4401 305.5811 305.7221 305.8631 306.0041 306.1451 306.2861 306.4270 306.5680 306.7089 306.8499 306.9908 307.1317 307.2726 307.4135 307.5543 307.6952 307.8360 307.9769 308.1177 308.2585 308.3993 308.5401 308.6809 308.8216 308.9624 309.1031 309.2439 309.3846 309.5253 309.6660 309.8067 309.9474 310.0880 310.2287 310.3693 310.5099 310.6506 310.7912 310.9318 311.0723 311.2129 311.3535 311.4940 311.6346 311.7751 311.9156 312.0561 312.1966 312.3371 312.4775 312.6180 312.7584 312.8989 313.0393 313.1797 313.3201 313.4605 313.6008 313.7412 313.8816 314.0219 314.1622 314.3025 314.4428 314.5831 314.7234 314.8637 315.0039 315.1442 315.2844 315.4246 315.5649 315.7051 315.8452 315.9854 316.1256 316.2657 316.4059 316.5460 316.6861 316.8262 316.9663 317.1064 317.2465 317.3865 317.5266 317.6666 317.8066 317.9466 318.0866 318.2266 318.3666 318.5066 318.6465 318.7865 318.9264 319.0663 319.2062 319.3461 319.4860 319.6259 319.7657 319.9056 320.0454 320.1852 320.3251 320.4649 320.6046 320.7444 320.8842 321.0239 321.1637 321.3034 321.4431 321.5828 321.7225 321.8622 322.0019 322.1416 322.2812 322.4208 322.5605 322.7001 322.8397 322.9793 323.1188 323.2584 323.3980 323.5375 323.6770 323.8165 323.9561 324.0955 324.2350 324.3745 324.5140 324.6534 324.7928 324.9323 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241206T091648.5Z 9106.386673 67 1 53.09 2 73.55 127.84 127.00 94.36 0.00 1 0.00 1 0 17 2.391e-01 1.423e-02 1.675e-01 8.806e-03 4.015678e-01 4.230752e-03 4.366816e-03 -6.000000e+00 1.259610e-01 223.34 -2.00 3.19 -2.00 319.39 0.00e+00 1.516850e-03 1.107640e-03 5.287964e-04 -6.000000e+00 5.468944e-03 274.47 -2.00 20.00 -2.00 318.84 0.00e+00 3.478 0.000 302.00 328.00 3 5.9405e+00 1.1726e-02 3.2142e-02 -6.0000e+00 3.1147e-01 3.5429e-02 1.3820e-02 1.8648e-02 -6.0000e+00 3.4020e-01 3.2674e-03 1.1546e-02 9.7558e-03 -6.0000e+00 2.0217e-01 -1.2077e-02 6.1902e-03 3.3439e-03 -6.0000e+00 8.8081e-02 5.9539e-05 1.5370e-04 2.0829e-04 2.4911e-05 -6.0000e+00 4.9903e-03 -7.6919e-03 0.0000e+00 12 8 8 10 0 0 99.73 18.81 0.90 -0.00769 -0.00654 14 1 1 8 0 3791.190 15.00 18.81 15.90 23.25 23.25 23.4 759.85 -47002 -38444 -10023 -22038 -12117 -55263 161555 139497 -93764 -27578 -45014 -11819 80030 10181 -8279 40052 16314 6055 -30542 -19726 -8260 -14996 -1263 18653 14358 6146 12245 -8700 32 -16150 8594 21839 -5020 19031 -8106 -13973 7062 5505 -4026 4201 -1568 2481 2455 -2659 -4008 -610 10605 10374 -410 -19 1264 -231 6015 1707 4540 -1455 101 326 3534 1908 -4166 -2154 -1596 2282 2484 -3403 347 827 -1075 518 481 1424 2220 -1664 2215 -1090 260 -1889 -7010 1415 -697 -1901 1073 42 -2278 -623 -1219 370 2046 2338 671 -602 -1829 -2046 768 -627 -684 1752 1093 -735 -870 -905 -1842 -1642 -1302 -412 -291 -577 174 124 941 285 -41 -284 1933 -1063 252 -31 -1028 1049 837 -384 733 -407 1176 1840 3 -1210 808 1117 32 -82 490 -1464 -511 62 -1073 739 1230 139 -189 -394 -875 -1180 -1041 -218 -553 -232 -1497 1387 1198 -5569 -947 -1836 -338 1088 342 -397 1433 794 347 -2710 -1638 -644 -1223 -97 1296 1110 542 1071 -890 3 -1589 745 1892 -627 2169 -1114 -1811 833 748 -739 872 -393 624 648 -766 -1142 -173 2951 2851 -127 -6 411 -86 2216 709 1941 -667 48 154 1557 836 -1950 -1073 -880 1345 1574 -2081 190 445 -597 340 356 1088 1716 -1263 1526 -685 143 -1017 -4051 899 -519 -1602 982 39 -2346 -685 -1284 401 2200 2450 718 -600 -1693 -1799 706 -668 -819 2108 1481 -1005 -1106 -1059 -2112 -1859 -1541 -501 -370 -777 245 190 1569 500 -70 -462 2834 -1466 344 -44 -1583 1699 1397 -619 1149 -624 1653 2514 3 -1543 1143 1727 54 -143 875 -2718 -1029 120 -2139 1476 2508 276 -387 -778 -1642 SS 20241206T111411.7Z 9106.468191 148 1 53.35 2 56.63 151.28 102.48 105.66 0.00 1 0.00 1 0 17 2.790e-02 1.245e-02 1.998e-02 6.196e-03 2.286919e-01 2.939772e-03 2.546924e-03 -6.000000e+00 1.469871e-02 223.34 -2.00 3.19 -2.00 317.21 0.00e+00 6.878632e-04 4.078770e-04 1.388335e-04 -6.000000e+00 6.380399e-04 274.46 -2.00 20.00 -2.00 316.65 0.00e+00 1.812 0.000 302.00 328.00 3 6.9063e+00 7.6817e-03 1.7253e-02 -6.0000e+00 3.6347e-02 4.9033e-02 8.6655e-03 1.0475e-02 -6.0000e+00 3.9697e-02 1.1557e-02 5.3366e-03 5.2668e-03 -6.0000e+00 2.3590e-02 -1.3483e-02 2.7228e-03 1.5958e-03 -6.0000e+00 1.0279e-02 9.9884e-05 -2.1093e-04 1.4432e-04 1.2549e-05 -6.0000e+00 5.8248e-04 -9.0103e-03 0.0000e+00 12 9 8 11 8 0 99.97 18.85 0.57 -0.00901 -0.01060 21 2 1 8 0 2539.884 15.00 18.85 15.82 23.25 23.25 23.6 760.17 1933 -6043 -6048 3542 -3334 -3771 -12148 3010 -11100 978 7431 -5766 934 -10367 2838 5919 1515 2936 -15 2343 4237 1083 -6275 2618 -2799 3553 730 -2106 -187 -6063 -1272 -2634 2228 4404 -2931 -5899 -4032 -1803 1177 1155 -603 -2635 1827 1806 -1782 1736 -88 1206 1785 -1058 -849 63 1395 1647 192 231 398 -1901 1310 1887 -1474 1847 635 1458 3757 -892 449 -5123 -254 605 797 970 1399 120 1176 764 -1755 -2627 -2493 -601 -1083 -1645 -1895 -1279 -1354 -978 -505 1283 895 1460 498 892 80 -469 -1401 308 277 1644 660 -70 -93 -1234 -2549 -2046 87 -1200 -1333 -990 -492 151 710 1893 912 923 -53 -1053 -684 -2562 571 -147 1038 879 1440 667 -582 1200 -377 -1239 -362 840 434 -19 -12 -954 103 589 -171 789 730 103 -610 -668 -1380 186 -716 -801 426 -356 -363 -1327 312 -1515 131 909 -752 127 -1832 494 1157 319 619 -4 583 1082 279 -1689 698 -824 1019 224 -625 -49 -1575 -333 -757 644 1410 -918 -1666 -1245 -610 467 557 -332 -1521 1044 1061 -1052 1009 -51 662 1053 -616 -513 41 940 1067 145 158 309 -1378 976 1374 -1117 1455 552 1234 3269 -797 356 -4117 -191 537 723 913 1343 111 1135 658 -1361 -1905 -1765 -486 -992 -1665 -2123 -1427 -1479 -1160 -625 1633 1159 1842 580 1036 84 -454 -1430 345 311 2029 911 -95 -118 -1476 -3045 -2424 106 -1545 -1786 -1390 -713 230 1154 3125 1460 1373 -72 -1310 -841 -3323 773 -217 1594 1311 2109 950 -775 1528 -453 -1434 -457 1122 611 -28 -17 -1427 166 997 -298 1391 1328 182 -1039 -1110 -2198 SS 20241206T112233.8Z 9106.474002 154 1 19.59 2 55.77 153.36 100.77 106.50 0.00 1 0.00 1 0 17 1.890e-02 1.046e-02 1.069e-02 4.982e-03 2.229570e-01 2.364768e-03 2.475701e-03 -6.000000e+00 9.960643e-03 223.34 -2.00 3.19 -2.00 316.18 0.00e+00 4.184848e-04 2.591412e-04 5.436511e-05 -6.000000e+00 4.323421e-04 274.46 -2.00 20.00 -2.00 315.66 0.00e+00 1.773 0.000 302.00 328.00 3 6.1800e+00 6.0898e-03 1.6810e-02 -6.0000e+00 2.4630e-02 3.6576e-02 6.8454e-03 1.0144e-02 -6.0000e+00 2.6900e-02 -5.3517e-03 4.0264e-03 5.0792e-03 -6.0000e+00 1.5985e-02 -5.4011e-03 1.9599e-03 1.4930e-03 -6.0000e+00 6.9661e-03 2.1774e-04 -1.3634e-04 1.1303e-04 1.2678e-05 -6.0000e+00 3.9474e-04 -9.4243e-03 0.0000e+00 12 9 9 12 1 1 98.97 18.85 0.54 -0.00942 -0.01045 4 1 1 8 0 3916.759 15.00 18.85 16.19 23.25 23.25 23.6 761.94 128 344 2394 -4800 -276 -4842 -11118 -1432 -4828 -1491 -1886 -2842 413 190 -4153 2220 -1346 -1183 2420 4043 5394 -2087 2910 -89 1529 2307 -804 -446 1110 -929 3037 1894 2006 1167 -2782 -4356 -3510 -1474 -818 1940 306 -2156 -360 -677 -147 320 -263 -882 -988 -1219 725 776 39 1040 -51 287 1599 275 1829 354 1516 1367 1213 1193 2805 -266 -67 -1061 -546 1652 1013 57 2 803 7 -201 -858 -2029 -3190 -1841 -654 -1926 -2151 -2190 -1223 -1538 -817 574 1552 1105 735 520 -43 -1045 -420 -258 863 739 1788 489 -138 -459 -1545 -1584 22 -1291 -888 -736 -847 -128 875 988 13 535 393 -816 -63 -22 -491 178 92 -8 1687 838 1034 809 -181 -138 853 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