File name: Pandora209s1_Izana_20250108_L2Fit_fout2c8d20221111p1-8.txt File generation date: 20250122T182524.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c8p1-8 Local principal investigator: Alberto Redondas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 209 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora209_OF_v3d20210806.txt Instrument calibration file used: Pandora209s1_CF_v8d20221111.txt Level 1 file used: Pandora209s1_Izana_20250108_L1_smca1c8d20221111p1-8.txt Full location name: Izana Atmospheric Research Center Short location name: Izana Country of location: Spain Location latitude [deg]: 28.3090 Location longitude [deg]: -16.4994 Location altitude [m]: 2360 Local noon date: 20250108 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are blind pixel subtraction, dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 198 340 Nominal wavelengths inside fitting window [nm]: 305.0129 305.1539 305.2949 305.4359 305.5769 305.7179 305.8589 305.9999 306.1408 306.2817 306.4227 306.5636 306.7045 306.8454 306.9863 307.1272 307.2680 307.4089 307.5497 307.6905 307.8313 307.9722 308.1129 308.2537 308.3945 308.5353 308.6760 308.8167 308.9575 309.0982 309.2389 309.3796 309.5202 309.6609 309.8016 309.9422 310.0828 310.2235 310.3641 310.5047 310.6453 310.7858 310.9264 311.0670 311.2075 311.3480 311.4885 311.6290 311.7695 311.9100 312.0505 312.1910 312.3314 312.4718 312.6123 312.7527 312.8931 313.0335 313.1739 313.3142 313.4546 313.5949 313.7353 313.8756 314.0159 314.1562 314.2965 314.4368 314.5770 314.7173 314.8575 314.9978 315.1380 315.2782 315.4184 315.5586 315.6987 315.8389 315.9790 316.1192 316.2593 316.3994 316.5395 316.6796 316.8197 316.9598 317.0998 317.2399 317.3799 317.5199 317.6599 317.7999 317.9399 318.0799 318.2199 318.3598 318.4998 318.6397 318.7796 318.9195 319.0594 319.1993 319.3392 319.4790 319.6189 319.7587 319.8985 320.0384 320.1782 320.3179 320.4577 320.5975 320.7372 320.8770 321.0167 321.1564 321.2962 321.4358 321.5755 321.7152 321.8549 321.9945 322.1342 322.2738 322.4134 322.5530 322.6926 322.8322 322.9717 323.1113 323.2509 323.3904 323.5299 323.6694 323.8089 323.9484 324.0879 324.2273 324.3668 324.5062 324.6457 324.7851 324.9245 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250108T090544.1Z 9139.378983 197 1 53.88 2 78.07 123.51 133.64 19.87 0.00 1 0.00 1 0 17 2.691e-01 7.844e-03 1.980e-01 3.670e-03 5.932429e-01 1.820775e-03 6.169087e-03 -6.000000e+00 1.423540e-01 223.09 -2.00 3.19 -2.00 320.50 0.00e+00 1.706413e-03 6.620851e-04 5.894908e-04 -6.000000e+00 6.148807e-03 272.92 -2.00 20.00 -2.00 320.04 0.00e+00 4.699 0.001 302.00 328.00 3 3.5643e+00 5.3142e-03 4.4763e-02 -6.0000e+00 3.5190e-01 3.9511e-02 6.9863e-03 2.7780e-02 -6.0000e+00 3.8461e-01 -3.9495e-02 7.5526e-03 1.5271e-02 -6.0000e+00 2.2775e-01 4.8196e-03 3.8605e-03 5.4298e-03 -6.0000e+00 9.8917e-02 2.1268e-04 -3.7610e-04 8.3426e-05 3.9569e-05 -6.0000e+00 5.6256e-03 8.7875e-06 0.0000e+00 11 8 0 10 0 0 99.01 18.85 0.69 0.00001 -0.00282 77 8 1 8 0 699.285 14.99 18.85 14.82 23.25 23.25 24.3 764.61 -114554 -133278 116514 -62441 -65055 -67358 900000 148594 -3817 9484 -44017 -61334 -28760 -55839 -26017 -43571 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-834 -534 -259 -1477 -861 -534 -1294 -892 -1188 -442 283 1284 298 836 1081 -404 -387 -152 -421 -498 806 1335 405 -47 -455 -1332 -837 94 -2847 -1215 -1278 -306 -3 1079 1079 727 445 -103 -1147 -102 -434 -264 77 -164 -321 1554 1008 957 2107 -279 -851 37 -5 1412 -537 197 -2203 285 533 -823 680 1362 107 -202 -1072 -906 SS 20250108T091007.3Z 9139.382029 199 1 54.01 2 77.27 124.15 133.31 21.17 0.00 1 0.00 1 0 17 1.597e-01 6.602e-03 4.783e-02 1.269e-03 5.657688e-01 6.176812e-04 5.945896e-03 -6.000000e+00 8.400786e-02 223.09 -2.00 3.19 -2.00 320.11 0.00e+00 5.819412e-04 2.056434e-04 3.957858e-04 -6.000000e+00 3.628291e-03 272.92 -2.00 20.00 -2.00 319.65 0.00e+00 4.423 0.001 302.00 328.00 3 1.9956e+00 1.7685e-03 4.2328e-02 -6.0000e+00 2.0773e-01 8.5714e-03 2.2346e-03 2.6316e-02 -6.0000e+00 2.2698e-01 -7.2162e-03 2.2875e-03 1.3874e-02 -6.0000e+00 1.3479e-01 -7.7878e-03 1.1932e-03 4.4168e-03 -6.0000e+00 5.8702e-02 1.2959e-03 -2.3231e-04 2.8533e-05 3.3679e-05 -6.0000e+00 3.3297e-03 -1.2387e-04 0.0000e+00 11 8 0 10 0 0 98.22 18.86 0.59 -0.00012 -0.00187 309 32 1 8 0 174.439 15.00 18.86 14.86 23.25 23.25 24.3 764.79 -46766 -65993 -41217 -57053 -49959 -71021 -63403 -38095 -30275 -30517 -31220 -47697 -39388 -25055 -24467 -14654 -21996 -4066 -9174 -10562 -12701 -7301 -15159 -9404 -12261 -7011 -3205 -8657 -10056 -12553 -7695 -5410 -2037 -2827 -2606 -6425 -7572 -3921 -1583 783 -452 -1116 -905 87 -141 -517 -484 350 -200 -796 266 1007 1848 1662 1654 1325 1693 1220 74 -86 -1104 620 1357 2308 2682 -44 952 -1126 -294 1074 1125 1218 813 1044 667 -331 -739 -1598 -1982 -732 -1115 -1216 -1406 -2678 -1149 -482 -195 214 923 988 354 937 -3 -324 105 160 179 797 679 510 -102 -300 -1143 -1217 91 -1412 -931 -1033 -605 -123 435 529 187 229 107 -432 59 -161 -12 -188 390 -201 695 468 788 982 -393 -74 191 244 703 -346 -153 -1049 -21 101 -415 586 328 -6 135 -150 -583 -280 -578 -310 -523 -366 -600 -543 -291 -250 -289 -306 -612 -580 -411 -493 -336 -604 -102 -267 -329 -429 -229 -515 -345 -506 -293 -138 -376 -415 -578 -401 -330 -137 -227 -195 -449 -603 -346 -170 103 -70 -184 -158 16 -25 -95 -90 65 -39 -160 58 251 491 486 520 429 576 421 25 -28 -362 218 537 1029 1319 -21 423 -520 -139 606 653 738 503 604 398 -175 -352 -754 -986 -439 -713 -884 -1163 -2286 -1039 -469 -198 225 971 1015 335 814 -2 -261 93 164 192 975 943 709 -133 -357 -1191 -1349 105 -1713 -1174 -1389 -868 -180 710 920 325 381 166 -621 84 -240 -19 -320 667 -326 1089 714 1122 1371 -564 -104 287 409 1190 -630 -288 -2054 -41 210 -888 1259 724 -13 265 -302 -1106 SS 20250108T091559.4Z 9139.386104 202 1 53.55 2 76.21 125.01 132.82 22.88 0.00 1 0.00 1 0 17 1.319e-01 6.740e-03 2.341e-02 8.336e-04 5.289493e-01 4.019038e-04 5.590121e-03 -6.000000e+00 6.937434e-02 223.09 -2.00 3.19 -2.00 319.87 0.00e+00 5.428393e-04 1.239622e-04 4.151411e-04 -6.000000e+00 2.996314e-03 272.92 -2.00 20.00 -2.00 319.39 0.00e+00 4.104 0.001 302.00 328.00 3 1.4531e+00 1.1362e-03 3.9376e-02 -6.0000e+00 1.7154e-01 4.0314e-03 1.3964e-03 2.4512e-02 -6.0000e+00 1.8744e-01 -6.5920e-04 1.3613e-03 1.2781e-02 -6.0000e+00 1.1131e-01 -1.0737e-02 7.2129e-04 3.9917e-03 -6.0000e+00 4.8476e-02 2.9268e-03 -2.3928e-04 1.8804e-05 2.9280e-05 -6.0000e+00 2.7497e-03 -2.3733e-05 0.0000e+00 11 8 0 10 0 0 91.81 18.86 0.63 -0.00002 -0.00182 674 71 1 8 0 79.100 14.99 18.86 14.98 23.25 23.50 24.4 766.01 -45907 -40735 -51077 -37430 -48798 -43267 -47346 -38291 -37389 -39527 -33782 -33846 -30641 -17536 -18995 -10214 -11909 -5739 -7042 -4119 -6406 -5027 -10269 -6340 -5360 -3104 -3399 -4898 -7653 -9122 -5136 -3395 -1065 -287 -5778 -8674 -5503 -3882 -2900 -1327 -1246 -767 -664 158 78 526 673 -206 -653 -850 267 1397 636 1473 1248 1202 2245 1429 299 101 -149 389 1566 2149 2863 53 440 -917 -740 1425 1283 1061 537 858 626 -141 -719 -1890 -2018 -633 -955 -1058 -1303 -2422 -1154 -600 -318 74 884 898 631 979 -146 -290 -181 34 94 763 767 431 24 -542 -1118 -1153 157 -1378 -945 -1058 -462 -26 466 568 164 342 194 -337 36 -297 71 -112 195 -111 554 533 737 1076 -429 -128 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