File name: Pandora30s1_Juelich_20250821_L2Fit_fout2c7d20250318p1-8.txt File generation date: 20250821T234122.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c7p1-8 Local principal investigator: Kezia Lange Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 30 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora30_OF_v3d20241219.txt Instrument calibration file used: Pandora30s1_CF_v7d20250318.txt Level 1 file used: Pandora30s1_Juelich_20250821_L1_smca1c7d20250318p1-8.txt Full location name: Juelich JULEY Short location name: Juelich Country of location: Germany Location latitude [deg]: 50.9080 Location longitude [deg]: 6.4130 Location altitude [m]: 94 Local noon date: 20250821 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB after repairs in LabLuftBlick First and last pixel inside fitting window: 221 362 Nominal wavelengths inside fitting window [nm]: 305.0212 305.1630 305.3047 305.4465 305.5882 305.7299 305.8716 306.0133 306.1550 306.2966 306.4383 306.5799 306.7216 306.8632 307.0048 307.1464 307.2880 307.4296 307.5711 307.7127 307.8542 307.9957 308.1373 308.2788 308.4203 308.5617 308.7032 308.8447 308.9861 309.1276 309.2690 309.4104 309.5518 309.6932 309.8346 309.9760 310.1173 310.2587 310.4000 310.5413 310.6826 310.8239 310.9652 311.1065 311.2478 311.3890 311.5303 311.6715 311.8127 311.9539 312.0951 312.2363 312.3775 312.5186 312.6598 312.8009 312.9421 313.0832 313.2243 313.3654 313.5064 313.6475 313.7886 313.9296 314.0706 314.2117 314.3527 314.4937 314.6347 314.7756 314.9166 315.0576 315.1985 315.3394 315.4803 315.6213 315.7621 315.9030 316.0439 316.1848 316.3256 316.4664 316.6073 316.7481 316.8889 317.0297 317.1705 317.3112 317.4520 317.5927 317.7334 317.8742 318.0149 318.1556 318.2963 318.4369 318.5776 318.7182 318.8589 318.9995 319.1401 319.2807 319.4213 319.5619 319.7024 319.8430 319.9835 320.1241 320.2646 320.4051 320.5456 320.6861 320.8266 320.9670 321.1075 321.2479 321.3883 321.5287 321.6691 321.8095 321.9499 322.0903 322.2306 322.3710 322.5113 322.6516 322.7919 322.9322 323.0725 323.2128 323.3530 323.4933 323.6335 323.7737 323.9139 324.0541 324.1943 324.3345 324.4747 324.6148 324.7550 324.8951 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250821T053716.7Z 9364.234221 154 1 32.33 2 80.74 82.31 58.38 92.79 0.00 1 0.00 1 0 25 5.724e-01 2.742e-02 3.127e-01 9.524e-03 7.448737e-01 5.704894e-03 1.148463e-02 -6.000000e+00 3.701814e-01 231.77 -2.00 3.80 -2.00 321.39 0.00e+00 3.042652e-02 2.825360e-03 5.803763e-03 -6.000000e+00 1.640549e-02 282.97 -2.00 20.00 -2.00 320.83 0.00e+00 5.904 0.004 302.00 328.00 3 2.9269e+00 1.9408e-02 7.3233e-02 -6.0000e+00 9.2671e-01 6.7741e-01 2.5494e-02 4.4279e-02 -6.0000e+00 1.0028e+00 -6.0764e-01 2.2905e-02 3.9241e-02 -6.0000e+00 5.9555e-01 2.2145e-01 1.0743e-02 2.8964e-02 -6.0000e+00 2.4131e-01 3.0255e-05 -3.7371e-03 3.0311e-04 4.9828e-04 -6.0000e+00 2.0336e-02 7.3336e-02 0.0000e+00 12 9 9 12 1 1 99.83 21.33 0.43 0.07334 0.04525 16 6 1 5 0 1901.420 26.73 20.01 21.33 19.01 29.1 998.66 10340 18229 -57598 -198335 900000 -154006 -160329 -83334 -191921 -199257 -208220 -50374 -102279 900000 -53816 28201 900000 67084 -78480 13664 166785 -58845 -34085 270849 -72803 -89116 -2604 89508 -50147 -14409 69991 -8031 18927 -5308 58490 -8517 -2852 172380 41118 4383 -12002 5810 10690 36616 16753 74248 32163 -17159 45893 29343 32478 11859 15505 8022 6475 4796 12828 13382 -8526 2201 5800 9655 8593 6822 5463 19801 14980 16987 9121 3203 9683 -2323 -4655 731 2577 7021 4233 3752 2457 3572 -2085 21 -528 2405 -3930 -3695 -474 -878 -669 -2222 -776 3178 -1679 -8 -3039 1400 -306 -1448 -12166 1283 3106 2613 2795 -2389 -4616 -3122 -1978 -868 -292 -22 -1924 -1707 -620 2756 3798 2429 3932 -103 -1325 -622 1705 1856 951 -157 576 2153 2964 620 815 18 -55 1232 575 -476 -914 -376 141 -1922 -735 -122 724 -21 96 169 -559 -7363 900000 -3183 -3247 -773 -4858 -5380 -6588 -468 -1989 900000 -1213 349 900000 741 -3807 284 1548 -2259 -1009 2514 -2864 -4017 -49 831 -1817 -446 1234 -358 728 -270 1551 -444 -150 1840 1744 296 -987 449 841 2363 1399 3708 2601 -2316 3712 3047 3588 1676 2257 1310 1087 813 1970 2004 -1590 384 1072 1947 1983 1753 1479 4694 3811 4500 2871 1115 3313 -895 -1752 252 795 1940 1209 1184 918 1487 -1055 11 -314 1472 -2704 -2545 -340 -609 -472 -1515 -493 1875 -1064 -5 -2381 1227 -313 -1581 -15252 1414 3105 2419 2495 -2295 -4770 -3382 -2289 -1051 -392 -32 -2976 -2694 -955 4127 5489 3571 5887 -161 -2157 -1001 2706 2826 1405 -225 798 2918 4181 990 1402 35 -110 2590 1293 -1103 -2226 -932 351 -4837 -1764 -285 1592 -46 SS 20250821T055513.9Z 9364.246689 166 1 47.62 2 77.93 85.74 55.67 96.33 0.00 1 0.00 1 0 25 2.653e-01 1.545e-02 2.876e-02 1.065e-03 6.072979e-01 6.098800e-04 7.511197e-03 -6.000000e+00 1.702132e-01 231.76 -2.00 3.80 -2.00 320.54 0.00e+00 7.356170e-03 2.430372e-04 1.779361e-03 -6.000000e+00 7.456539e-03 282.97 -2.00 20.00 -2.00 319.90 0.00e+00 4.638 0.002 302.00 328.00 3 1.1036e+00 1.8951e-03 5.9490e-02 -6.0000e+00 4.2592e-01 1.2834e-01 2.3747e-03 4.0423e-02 -6.0000e+00 4.6024e-01 -9.9939e-02 2.0943e-03 1.7645e-02 -6.0000e+00 2.7360e-01 2.8409e-02 1.0259e-03 9.7347e-03 -6.0000e+00 1.1141e-01 8.9184e-04 -2.0085e-03 3.5766e-05 9.8450e-05 -6.0000e+00 9.3603e-03 7.1991e-02 0.0000e+00 12 8 8 10 0 0 95.38 21.33 0.21 0.07199 0.05690 395 93 1 5 0 120.530 26.73 20.00 21.33 19.38 29.2 998.69 -106892 -84111 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1874 586 1029 736 708 815 609 475 -223 -258 -351 306 962 872 766 186 -143 341 1740 1991 2251 1053 -525 -733 -1261 -798 -659 -27 1032 1119 1218 89 -697 -1195 -1681 -1054 -417 -1004 -1281 -1283 -1409 -618 -164 1057 1940 2574 2020 862 696 -535 -2544 -2783 -551 1886 4198 2938 -1641 -2889 -1649 -479 351 -308 -2104 -3028 -1656 89 2736 4713 4715 2550 -376 -3083 -3213 -597 -266 -535 -280 470 3499 5095 1208 -1358 -1313 -377 2103 1817 -72 -1502 -508 -1093 -3708 -2172 -478 1397 3229 SS 20250821T060028.2Z 9364.250326 169 1 48.13 2 77.11 86.75 54.89 97.39 0.00 1 0.00 1 0 25 3.794e-01 2.155e-02 1.625e-01 8.561e-03 5.559464e-01 4.871145e-03 7.041971e-03 -6.000000e+00 2.431733e-01 231.76 -2.00 3.80 -2.00 320.35 0.00e+00 3.740739e-03 1.736843e-03 1.218381e-03 -6.000000e+00 1.066243e-02 282.97 -2.00 20.00 -2.00 319.68 0.00e+00 4.363 0.002 302.00 328.00 3 4.8760e+00 1.4689e-02 5.3984e-02 -6.0000e+00 6.0846e-01 3.3312e-01 1.7777e-02 3.2520e-02 -6.0000e+00 6.5773e-01 -2.4643e-01 1.3884e-02 1.6263e-02 -6.0000e+00 3.9099e-01 9.0302e-02 6.8278e-03 4.8670e-03 -6.0000e+00 1.5900e-01 2.6051e-05 -2.2774e-03 2.9597e-04 8.3580e-05 -6.0000e+00 1.3386e-02 7.9847e-02 0.0000e+00 12 8 8 10 0 0 99.98 21.32 -0.26 0.07985 0.06273 17 4 1 5 0 2830.760 26.73 20.00 21.32 19.68 29.2 998.66 -63664 4458 -33146 -112144 100535 -123758 -116028 -103237 -46165 -57529 -70075 -91876 -51121 53185 -35769 -7224 219088 -18355 -5372 199419 9952 -8167 9614 30644 -32695 -31242 14541 18664 -14237 -14181 -13674 -1067 25763 8899 23733 8606 -2902 74860 6543 2150 2569 -238 6940 12417 -3883 26500 280 5592 10661 6941 -1380 6775 -4800 5642 2291 4746 6573 5715 6621 1511 3630 2743 3957 158 3128 8585 5839 9167 1763 -4049 -57 -2097 -4216 68 1073 6162 -93 -1448 -836 -4721 -3385 -2366 -2136 2521 -2303 29 -4023 830 -1227 -2656 -648 1772 2036 -222 825 780 -1321 -2616 -1085 -330 138 2005 528 49 -4560 -2414 735 16 2114 -1390 -220 -1346 -572 1808 1698 2902 2636 101 -1459 -755 -284 34 1644 -501 1777 2381 4097 -765 642 -1381 1198 972 1249 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