File name: Pandora167s1_KenoshaWI_20200716_L2Fit_fout2c9d20200520p1-8.txt File generation date: 20241119T104257.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v2d20200117.txt Instrument calibration file used: Pandora167s1_CF_v9d20200520.txt Level 1 file used: Pandora167s1_KenoshaWI_20200716_L1_smca1c9d20200520p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20200716 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0344 305.1754 305.3164 305.4574 305.5983 305.7392 305.8802 306.0211 306.1620 306.3029 306.4438 306.5846 306.7255 306.8663 307.0072 307.1480 307.2888 307.4296 307.5704 307.7112 307.8519 307.9927 308.1334 308.2742 308.4149 308.5556 308.6963 308.8370 308.9777 309.1183 309.2590 309.3996 309.5403 309.6809 309.8215 309.9621 310.1027 310.2433 310.3838 310.5244 310.6649 310.8055 310.9460 311.0865 311.2270 311.3675 311.5079 311.6484 311.7888 311.9293 312.0697 312.2101 312.3505 312.4909 312.6313 312.7717 312.9120 313.0524 313.1927 313.3330 313.4734 313.6137 313.7539 313.8942 314.0345 314.1747 314.3150 314.4552 314.5954 314.7356 314.8758 315.0160 315.1562 315.2964 315.4365 315.5767 315.7168 315.8569 315.9970 316.1371 316.2772 316.4173 316.5573 316.6974 316.8374 316.9774 317.1174 317.2575 317.3974 317.5374 317.6774 317.8173 317.9573 318.0972 318.2371 318.3770 318.5169 318.6568 318.7967 318.9366 319.0764 319.2163 319.3561 319.4959 319.6357 319.7755 319.9153 320.0551 320.1948 320.3346 320.4743 320.6140 320.7537 320.8934 321.0331 321.1728 321.3125 321.4521 321.5918 321.7314 321.8710 322.0106 322.1502 322.2898 322.4294 322.5689 322.7085 322.8480 322.9875 323.1270 323.2665 323.4060 323.5455 323.6850 323.8244 323.9639 324.1033 324.2427 324.3821 324.5215 324.6609 324.8003 324.9396 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200716T124527.6Z 7502.531569 879 1 1.11 2 67.19 81.53 31.74 132.23 0.00 1 0.00 1 0 25 2.652e-02 1.491e-02 1.376e-02 3.729e-03 3.187438e-01 1.908395e-03 3.798519e-03 -6.000000e+00 1.542491e-02 232.88 -2.00 3.54 -2.00 317.51 0.00e+00 1.592337e-03 2.927448e-04 8.014784e-04 -6.000000e+00 6.830754e-04 287.72 -2.00 20.00 -2.00 316.68 0.00e+00 2.559 0.000 302.00 328.00 3 1.7099e+00 5.1065e-03 3.0198e-02 -6.0000e+00 3.8742e-02 -2.6724e-02 5.7403e-03 1.6650e-02 -6.0000e+00 4.1867e-02 1.0205e-02 3.4800e-03 8.0481e-03 -6.0000e+00 2.4915e-02 -1.3304e-02 1.7295e-03 2.2568e-03 -6.0000e+00 1.0511e-02 5.3722e-03 8.5639e-04 1.0552e-04 2.1423e-05 -6.0000e+00 7.1573e-04 3.8674e-03 0.0000e+00 12 9 9 12 1 1 94.38 23.02 0.17 0.00387 0.01030 5 60 1 5 0 154.450 25.79 20.00 23.02 27.20 999.00 25.9 995.58 1321 -108 3959 1973 -12386 -1246 -1317 -5261 -3475 -3825 -3864 -12383 -3096 -5021 489 401 -1992 3016 323 3992 398 3498 2628 3221 1753 -2396 549 -4682 -2921 -3591 -1153 413 -892 -4345 -7159 -4955 -5755 -3132 204 -266 -848 338 1412 784 2617 1660 281 1207 -2015 -381 446 1035 2066 1421 2772 1613 1539 45 84 813 677 2177 2958 4211 1030 -404 -389 -2636 970 -242 2027 1774 998 1940 -234 -2037 -3556 -3969 -4154 -3753 -2068 -1983 -3185 -2127 -401 274 822 1981 2406 1367 882 -356 -2424 -2390 -1795 -971 116 1478 1046 -517 -1102 -1784 -2064 -897 -1853 -1330 -511 -28 506 1844 2312 1967 1395 207 -993 -383 -1071 -106 980 1251 977 1442 1919 1032 235 -1309 -1670 -108 -821 -806 -1196 -772 -1024 -61 244 82 971 1232 938 -24 -453 -1100 -792 107 -10 364 178 -1160 -101 -112 -516 -374 -435 -442 -1579 -409 -780 83 75 -404 615 70 876 92 790 609 777 450 -660 149 -1276 -752 -927 -309 119 -280 -1451 -2354 -1568 -1953 -1174 86 -126 -435 179 761 431 1423 914 156 658 -1117 -211 257 626 1299 933 1850 1104 1069 31 58 560 476 1595 2288 3391 854 -324 -299 -2028 762 -208 1821 1645 930 1760 -206 -1702 -2822 -3075 -3333 -3250 -1917 -1957 -3307 -2263 -440 312 965 2357 2864 1605 997 -385 -2529 -2454 -1909 -1093 139 1869 1377 -684 -1411 -2185 -2445 -1072 -2339 -1731 -680 -38 711 2679 3469 2992 2094 302 -1394 -519 -1455 -147 1405 1855 1470 2146 2807 1484 330 -1812 -2254 -145 -1157 -1188 -1823 -1196 -1612 -99 404 140 1675 2148 1645 -42 -774 -1846 -1313 SS 20200716T130612.9Z 7502.545982 980 1 25.74 2 63.40 84.83 29.10 140.21 0.00 1 0.00 1 0 25 3.215e-02 1.578e-02 1.962e-02 4.377e-03 2.792745e-01 2.228566e-03 3.456929e-03 -6.000000e+00 1.870556e-02 232.88 -2.00 3.54 -2.00 318.00 0.00e+00 1.466832e-03 3.883660e-04 1.186841e-03 -6.000000e+00 8.283365e-04 287.72 -2.00 20.00 -2.00 317.15 0.00e+00 2.220 0.000 302.00 328.00 3 5.1223e+00 6.0272e-03 2.6445e-02 -6.0000e+00 4.6982e-02 1.3943e-02 6.8190e-03 1.5157e-02 -6.0000e+00 5.0771e-02 1.8648e-02 4.2545e-03 7.2175e-03 -6.0000e+00 3.0214e-02 -2.2503e-02 2.1511e-03 1.9308e-03 -6.0000e+00 1.2747e-02 2.5344e-04 1.0319e-03 1.2679e-04 1.8025e-05 -6.0000e+00 8.6792e-04 3.5719e-03 0.0000e+00 12 9 9 12 1 1 99.96 23.00 0.27 0.00357 0.01133 6 3 1 5 0 3652.130 25.79 19.99 23.00 27.90 999.00 26.1 995.40 5494 16871 4972 650 338 -8129 -3027 -706 -7462 -2242 -4395 -12206 -2369 -10107 5950 -4467 -186 3561 422 620 857 3906 -489 4815 2238 2351 10 -1347 -1543 -3412 -3436 40 1660 -6059 -6894 -8479 -4180 -3122 -1054 -316 -706 943 20 672 3092 -97 444 1380 -2513 -1680 467 77 1146 1489 680 1812 -1926 84 -313 114 891 3185 4041 4752 1440 722 -1317 -2190 866 1100 2003 1078 2329 2872 -442 -1845 -3677 -4611 -4184 -4538 -2409 -1721 -2910 -1515 -1149 1227 1620 1930 2681 1168 774 -1442 -3157 -2208 -2319 -1773 820 1319 442 -473 -540 -2285 -1559 -1476 -1528 -1324 -613 -310 1261 1454 2521 1953 895 301 -929 -959 -875 -403 915 1102 1646 1150 1701 209 699 -988 -1270 -1211 -1216 -1769 -712 -1570 -1389 -173 390 625 1223 1317 1215 528 -452 -1059 -1191 362 1113 381 50 23 -580 -216 -55 -695 -209 -419 -1288 -256 -1363 792 -730 -31 596 76 116 164 726 -97 948 477 521 2 -297 -322 -715 -762 9 417 -1695 -1850 -2246 -1147 -978 -385 -132 -324 446 10 334 1505 -49 220 667 -1239 -828 237 42 654 887 420 1132 -1263 54 -199 72 575 2146 2914 3611 1133 538 -935 -1531 622 878 1716 968 2070 2471 -369 -1431 -2658 -3223 -3030 -3645 -2105 -1622 -2928 -1569 -1252 1389 1905 2329 3224 1384 870 -1532 -3179 -2147 -2366 -1951 964 1674 592 -633 -690 -2773 -1800 -1743 -1926 -1741 -831 -433 1814 2195 3937 3099 1396 448 -1312 -1298 -1178 -560 1327 1674 2538 1761 2547 307 988 -1365 -1692 -1622 -1714 -2648 -1099 -2492 -2234 -284 666 1108 2203 2409 2234 961 -808 -1851 -2055 SS 20200716T131021.6Z 7502.548861 988 1 47.21 2 62.64 85.49 28.62 141.94 0.00 1 0.00 1 0 25 2.188e-02 1.358e-02 1.461e-03 3.504e-04 2.708372e-01 1.780054e-04 3.306758e-03 -6.000000e+00 1.273029e-02 232.88 -2.00 3.54 -2.00 317.98 0.00e+00 1.614579e-03 3.054056e-05 9.899044e-04 -6.000000e+00 5.637565e-04 287.72 -2.00 20.00 -2.00 317.12 0.00e+00 2.164 0.000 302.00 328.00 3 9.1745e-01 4.8136e-04 2.5679e-02 -6.0000e+00 3.1974e-02 -1.7705e-02 5.4423e-04 1.4456e-02 -6.0000e+00 3.4553e-02 1.4341e-02 3.3616e-04 6.9784e-03 -6.0000e+00 2.0563e-02 -1.8675e-02 1.6886e-04 1.9332e-03 -6.0000e+00 8.6744e-03 1.8479e-02 9.1855e-04 1.0192e-05 1.8335e-05 -6.0000e+00 5.9071e-04 3.9971e-03 0.0000e+00 12 8 8 10 0 0 99.97 23.01 0.21 0.00400 0.01090 1324 248 1 5 0 35.040 25.79 20.01 23.01 27.93 999.00 26.1 995.48 1894 867 1081 -3213 -4444 -4671 -4598 -2534 -3356 -5110 -7172 -6043 -4434 -2500 103 -93 423 1166 1394 2253 658 1300 1994 1383 923 146 -881 -2254 -2459 -2495 -1252 -627 417 -3661 -6260 -6222 -6106 -3238 -1315 -581 -557 177 578 555 1625 1230 541 168 -1071 -284 715 797 1568 1631 1322 1675 911 106 -171 10 1198 2325 3317 3677 1225 4 -1024 -1642 973 972 1457 2139 1532 1695 -89 -1485 -3348 -4723 -3466 -3511 -2757 -2281 -3111 -1723 -538 360 1192 1665 2181 1572 803 -829 -2024 -2070 -1818 -1336 234 1502 585 -188 -1216 -2177 -1978 -1037 -1755 -1414 -630 -341 908 1793 2190 1677 1242 194 -740 -752 -747 -159 901 948 1033 1258 1451 660 642 -1027 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