File name: Pandora167s1_KenoshaWI_20200815_L2Fit_fout2c9d20200520p1-8.txt File generation date: 20241119T105114.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v2d20200117.txt Instrument calibration file used: Pandora167s1_CF_v9d20200520.txt Level 1 file used: Pandora167s1_KenoshaWI_20200815_L1_smca1c9d20200520p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20200815 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0344 305.1754 305.3164 305.4574 305.5983 305.7392 305.8802 306.0211 306.1620 306.3029 306.4438 306.5846 306.7255 306.8663 307.0072 307.1480 307.2888 307.4296 307.5704 307.7112 307.8519 307.9927 308.1334 308.2742 308.4149 308.5556 308.6963 308.8370 308.9777 309.1183 309.2590 309.3996 309.5403 309.6809 309.8215 309.9621 310.1027 310.2433 310.3838 310.5244 310.6649 310.8055 310.9460 311.0865 311.2270 311.3675 311.5079 311.6484 311.7888 311.9293 312.0697 312.2101 312.3505 312.4909 312.6313 312.7717 312.9120 313.0524 313.1927 313.3330 313.4734 313.6137 313.7539 313.8942 314.0345 314.1747 314.3150 314.4552 314.5954 314.7356 314.8758 315.0160 315.1562 315.2964 315.4365 315.5767 315.7168 315.8569 315.9970 316.1371 316.2772 316.4173 316.5573 316.6974 316.8374 316.9774 317.1174 317.2575 317.3974 317.5374 317.6774 317.8173 317.9573 318.0972 318.2371 318.3770 318.5169 318.6568 318.7967 318.9366 319.0764 319.2163 319.3561 319.4959 319.6357 319.7755 319.9153 320.0551 320.1948 320.3346 320.4743 320.6140 320.7537 320.8934 321.0331 321.1728 321.3125 321.4521 321.5918 321.7314 321.8710 322.0106 322.1502 322.2898 322.4294 322.5689 322.7085 322.8480 322.9875 323.1270 323.2665 323.4060 323.5455 323.6850 323.8244 323.9639 324.1033 324.2427 324.3821 324.5215 324.6609 324.8003 324.9396 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200815T114304.7Z 7532.488248 244 1 51.32 2 82.99 77.67 41.85 101.98 0.00 1 0.00 1 0 25 6.280e-01 6.622e-02 5.146e-01 5.610e-02 7.507925e-01 3.162344e-02 9.427910e-03 -6.000000e+00 3.702287e-01 231.75 -2.00 3.54 -2.00 321.83 0.00e+00 7.576099e-04 1.392097e-02 1.325807e-02 -6.000000e+00 1.839222e-02 288.28 -2.00 20.00 -2.00 321.19 0.00e+00 7.513 0.008 302.00 328.00 3 2.6886e+00 1.1170e-01 1.1280e-01 -6.0000e+00 9.2702e-01 1.1867e+00 1.3598e-01 1.0836e-01 -6.0000e+00 1.0059e+00 -1.4973e+00 8.2380e-02 3.4263e-02 -6.0000e+00 5.9767e-01 5.6534e-01 4.1971e-02 8.3631e-03 -6.0000e+00 2.5690e-01 1.0235e-05 1.6630e-03 1.6251e-03 9.7738e-05 -6.0000e+00 1.7624e-02 8.2094e-04 0.0000e+00 12 8 8 10 0 0 95.18 23.02 1.02 0.00082 0.01332 13 2 1 5 0 3947.200 25.79 20.01 23.02 26.86 999.00 29.1 993.60 900000 121371 900000 140611 -20757 62956 -79839 22152 -45899 -50876 900000 64203 -63459 -82086 -22591 -5910 196134 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6566 7117 900000 8876 -6468 4843 -2852 9823 4329 6805 6807 7413 6307 8394 2537 -5320 8407 4837 4780 8775 3295 -3866 8666 5971 9029 10936 7213 4410 -1247 -13903 4583 -109 1954 -8749 7205 -9363 -14320 2528 141 -2139 6019 363 10534 15101 5470 4480 14217 -5453 -1752 4436 -9467 -3125 6463 -10471 5821 -6825 -8849 -11042 -2319 -11001 1991 -2679 3025 5218 -5508 -98 1825 7400 6415 -10091 7299 1139 -6601 7343 2281 -130 3162 1798 12905 6911 -11860 -5612 -720 2020 2392 -628 8384 -2502 -5720 -2271 -4344 -2282 -373 6416 8864 6084 -704 -8539 -5783 SS 20200815T114628.1Z 7532.490603 248 1 50.16 2 82.38 78.22 41.25 102.68 0.00 1 0.00 1 0 25 5.320e-01 4.142e-02 4.798e-01 3.063e-02 6.981953e-01 1.707628e-02 1.026533e-02 -6.000000e+00 3.101314e-01 231.75 -2.00 3.54 -2.00 321.95 0.00e+00 1.888125e-04 8.898411e-03 1.963819e-02 -6.000000e+00 1.489129e-02 288.28 -2.00 20.00 -2.00 321.36 0.00e+00 7.001 0.006 302.00 328.00 3 2.7811e+00 6.5718e-02 1.4064e-01 -6.0000e+00 7.7582e-01 6.5888e-01 8.4412e-02 1.6459e-01 -6.0000e+00 8.4045e-01 -1.1358e+00 6.0464e-02 5.0448e-02 -6.0000e+00 5.0086e-01 4.6851e-01 2.8481e-02 1.1442e-02 -6.0000e+00 2.1267e-01 1.9609e-05 2.4793e-03 9.2535e-04 1.5905e-04 -6.0000e+00 1.4625e-02 -9.1605e-04 0.0000e+00 12 8 8 10 0 0 97.55 23.02 0.90 -0.00092 0.01771 20 4 1 5 0 2507.700 25.79 20.00 23.02 26.96 999.00 29.2 993.37 -94779 900000 1098 -9710 -55228 44880 -45687 81538 36483 60419 197594 -74261 -80586 900000 59036 1640 -50034 -57165 99112 900000 900000 39382 900000 17774 58775 900000 -102092 900000 -27728 154180 -22 -63828 123671 49615 229400 74181 493 10308 124861 64864 -6275 28636 8074 73754 11177 71001 129291 152676 114808 50783 19342 6896 95791 113257 89165 96510 56175 38468 24442 -11303 26732 -7759 13753 10740 47359 34996 29472 14950 55863 29188 8704 32042 7652 16754 12646 -13154 14022 -34383 -6293 -14923 -5012 2765 -3382 18485 -2710 -3802 -1995 9331 13917 2371 -204 -17247 1739 1067 -4536 -5439 -6604 -1643 -6487 2268 -9265 -8645 -2716 -5432 -680 -908 -2895 -1601 499 5526 754 7255 2827 2490 -159 -5369 -3285 -3149 4369 531 2611 3749 2552 3391 -604 -791 -4763 2667 522 -296 17 -673 -84 -1582 372 -483 1492 1675 837 -968 486 -1138 -2179 -5184 900000 33 -290 -1798 1339 -1363 2433 1088 1803 5895 -3223 -4372 900000 1761 62 -3393 -4341 2957 900000 900000 1175 900000 627 1754 900000 -12184 900000 -1354 4600 -1 -6059 3690 1749 6844 2213 27 587 3725 2991 -647 2175 767 3601 1000 3466 3857 4555 3737 3306 1889 842 5196 5529 5804 6021 5333 4278 2983 -1901 3118 -1389 2238 2010 6423 5221 4556 2757 7576 5938 2385 7213 2159 4044 2881 -3461 2624 -10632 -1656 -5100 -1821 1065 -1523 7119 -1382 -2093 -1042 4885 6946 1280 -106 -9964 807 521 -2658 -3762 -4942 -1348 -6113 1968 -8478 -7093 -2114 -4420 -572 -815 -2819 -1525 516 6168 988 9506 3915 3368 -210 -7262 -4427 -4479 6159 812 3882 5322 3553 4553 -892 -1133 -6925 3813 798 -519 33 -1403 -183 -3773 936 -1291 4010 4572 2297 -2596 1205 -2692 -5071 SS 20200815T114847.1Z 7532.492211 250 1 50.13 2 81.97 78.60 40.84 103.16 0.00 1 0.00 1 0 25 8.177e-01 6.243e-02 4.867e-01 4.545e-02 6.440831e-01 2.592682e-02 9.084921e-03 -6.000000e+00 4.926231e-01 231.75 -2.00 3.54 -2.00 321.71 0.00e+00 7.675622e-03 1.198932e-02 1.294366e-02 -6.000000e+00 2.394446e-02 288.28 -2.00 20.00 -2.00 321.09 0.00e+00 6.686 0.006 302.00 328.00 3 3.4204e+00 9.3347e-02 1.0095e-01 -6.0000e+00 1.2346e+00 8.3541e-01 1.1002e-01 8.9040e-02 -6.0000e+00 1.3417e+00 -1.2807e+00 6.3311e-02 2.2313e-02 -6.0000e+00 7.9450e-01 5.1438e-01 3.2724e-02 9.3329e-03 -6.0000e+00 3.3834e-01 1.3296e-05 1.1597e-03 1.4283e-03 1.3460e-04 -6.0000e+00 2.3283e-02 3.2837e-04 0.0000e+00 12 9 8 11 8 0 93.25 23.03 0.69 0.00033 0.00904 18 3 1 5 0 2784.430 25.79 19.99 23.03 27.01 999.00 29.2 993.29 900000 -78420 900000 90680 -32041 -88396 -66490 900000 -74206 -17741 -2022 900000 53496 73733 -36402 59949 900000 219081 151839 449126 900000 155714 900000 352699 127110 900000 151946 11395 65921 -48294 69503 88347 219543 50509 900000 164822 900000 133829 208157 143152 900000 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