File name: Pandora167s1_KenoshaWI_20200825_L2Fit_fout2c9d20200520p1-8.txt File generation date: 20241119T110855.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v2d20200117.txt Instrument calibration file used: Pandora167s1_CF_v9d20200520.txt Level 1 file used: Pandora167s1_KenoshaWI_20200825_L1_smca1c9d20200520p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20200825 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0344 305.1754 305.3164 305.4574 305.5983 305.7392 305.8802 306.0211 306.1620 306.3029 306.4438 306.5846 306.7255 306.8663 307.0072 307.1480 307.2888 307.4296 307.5704 307.7112 307.8519 307.9927 308.1334 308.2742 308.4149 308.5556 308.6963 308.8370 308.9777 309.1183 309.2590 309.3996 309.5403 309.6809 309.8215 309.9621 310.1027 310.2433 310.3838 310.5244 310.6649 310.8055 310.9460 311.0865 311.2270 311.3675 311.5079 311.6484 311.7888 311.9293 312.0697 312.2101 312.3505 312.4909 312.6313 312.7717 312.9120 313.0524 313.1927 313.3330 313.4734 313.6137 313.7539 313.8942 314.0345 314.1747 314.3150 314.4552 314.5954 314.7356 314.8758 315.0160 315.1562 315.2964 315.4365 315.5767 315.7168 315.8569 315.9970 316.1371 316.2772 316.4173 316.5573 316.6974 316.8374 316.9774 317.1174 317.2575 317.3974 317.5374 317.6774 317.8173 317.9573 318.0972 318.2371 318.3770 318.5169 318.6568 318.7967 318.9366 319.0764 319.2163 319.3561 319.4959 319.6357 319.7755 319.9153 320.0551 320.1948 320.3346 320.4743 320.6140 320.7537 320.8934 321.0331 321.1728 321.3125 321.4521 321.5918 321.7314 321.8710 322.0106 322.1502 322.2898 322.4294 322.5689 322.7085 322.8480 322.9875 323.1270 323.2665 323.4060 323.5455 323.6850 323.8244 323.9639 324.1033 324.2427 324.3821 324.5215 324.6609 324.8003 324.9396 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20200825T195831.1Z 7542.832305 5 1 50.28 2 42.18 229.65 81.35 127.18 0.00 1 0.00 1 0 17 1.737e-02 1.345e-02 1.662e-03 8.021e-04 1.688279e-01 4.090620e-04 2.087404e-03 -6.000000e+00 1.003837e-02 230.84 -2.00 3.54 -2.00 316.42 0.00e+00 1.072721e-03 4.711780e-05 3.771114e-04 -6.000000e+00 4.470989e-04 287.44 -2.00 20.00 -2.00 315.61 0.00e+00 1.348 0.000 302.00 328.00 3 3.0244e+00 1.0706e-03 1.5810e-02 -6.0000e+00 2.5089e-02 1.1770e-02 1.1948e-03 8.6100e-03 -6.0000e+00 2.7145e-02 4.2274e-03 6.8958e-04 4.1635e-03 -6.0000e+00 1.6180e-02 -1.6220e-02 3.1834e-04 1.1661e-03 -6.0000e+00 6.8623e-03 5.8687e-03 6.9251e-04 2.3260e-05 1.3850e-05 -6.0000e+00 4.6853e-04 -3.8323e-03 0.0000e+00 12 8 8 10 0 0 99.98 22.93 0.17 -0.00383 0.00137 934 175 1 5 0 52.370 25.68 20.00 22.93 33.81 999.00 28.8 996.86 2325 1098 1300 -1928 -2458 -2184 -1620 -329 -204 -2526 -4413 -3858 -2392 -954 496 187 144 1136 1097 2270 1381 1168 2300 1793 1418 1071 81 -605 -1377 -843 -264 -201 518 -2905 -5461 -5407 -5458 -3270 -1358 -740 -604 173 300 462 1223 858 222 76 -1020 -397 738 468 1112 1380 967 1354 782 268 -124 -74 1010 1904 2857 3198 1207 -62 -943 -1822 591 743 1233 2000 1518 1587 236 -1159 -2678 -4231 -3131 -3443 -2727 -2445 -3240 -1843 -649 86 856 1400 1969 1438 867 -689 -1759 -1789 -1673 -1369 39 1379 620 -227 -1034 -2238 -2155 -1187 -1762 -1581 -672 -478 675 1636 2057 1772 1328 417 -599 -764 -847 -306 718 870 839 1088 1293 478 784 -705 -1429 -340 -640 -632 -914 -1231 -830 -165 138 282 780 1198 740 286 -279 -1117 -1103 450 235 283 -409 -462 -379 -287 -64 -44 -583 -1018 -875 -577 -255 147 60 48 382 380 801 502 420 821 667 554 433 33 -234 -495 -288 -92 -74 201 -1203 -2177 -2059 -2216 -1498 -728 -459 -379 113 200 311 812 569 145 51 -672 -256 485 328 812 1049 757 1070 586 217 -99 -59 813 1503 2408 2838 1088 -52 -778 -1442 476 672 1133 1913 1467 1489 211 -1020 -2140 -3188 -2371 -2897 -2546 -2320 -3299 -1933 -718 101 1062 1791 2520 1794 1009 -738 -1849 -1780 -1721 -1421 44 1691 814 -297 -1283 -2593 -2366 -1331 -2162 -2057 -905 -669 973 2463 3224 2805 2025 594 -784 -934 -1023 -383 957 1248 1247 1610 1863 667 1033 -896 -1862 -434 -801 -842 -1274 -1757 -1192 -243 215 462 1313 2058 1291 493 -470 -1835 -1774 SS 20200825T200305.8Z 7542.835484 8 1 1.63 2 42.83 231.01 80.71 128.02 0.00 1 0.00 1 0 17 1.775e-02 1.502e-02 2.632e-03 1.873e-03 1.720627e-01 9.697637e-04 2.095917e-03 -6.000000e+00 1.026156e-02 230.84 -2.00 3.54 -2.00 314.76 0.00e+00 1.037568e-03 8.039566e-05 1.691233e-04 -6.000000e+00 4.569985e-04 287.44 -2.00 20.00 -2.00 314.11 0.00e+00 1.362 0.000 302.00 328.00 3 2.3130e+00 2.4950e-03 1.6022e-02 -6.0000e+00 2.5647e-02 9.1881e-03 2.7638e-03 8.8318e-03 -6.0000e+00 2.7746e-02 -2.6322e-03 1.5831e-03 4.2198e-03 -6.0000e+00 1.6539e-02 -1.0651e-02 6.9151e-04 1.1754e-03 -6.0000e+00 7.0164e-03 1.1738e-02 9.0152e-04 5.2489e-05 1.5866e-05 -6.0000e+00 4.7883e-04 -5.4496e-03 0.0000e+00 12 9 9 12 1 1 76.21 22.95 0.18 -0.00545 0.00132 9 64 1 5 0 145.970 25.68 20.01 22.95 33.96 999.00 28.4 997.07 2711 1738 1030 257 -2971 -2577 -2470 -679 -303 -2621 -3286 -3082 -2355 -161 723 741 155 2069 895 1990 1392 1358 2397 1775 2449 704 557 -7 -1040 -873 -934 404 68 -3061 -5746 -5707 -4708 -3179 -894 -902 -262 131 735 799 1448 897 193 49 -977 -242 699 368 1269 1511 1208 1339 1056 545 24 -43 840 1949 2593 3402 1426 -207 -1031 -1604 917 1049 1125 2209 1270 2069 -128 -1226 -2928 -4528 -3335 -3693 -2914 -2563 -3333 -2148 -547 90 813 1746 1637 1471 700 -630 -1686 -2067 -1822 -1538 327 1476 551 109 -718 -1905 -1982 -972 -1488 -1476 -391 -600 907 1936 2468 1765 1745 477 -505 -336 -841 -173 1039 1144 1093 1291 1463 471 907 -621 -1503 -318 -727 -701 -1049 -1141 -841 -135 231 333 826 1075 759 -94 -195 -969 -1291 905 639 389 92 -1029 -823 -808 -242 -113 -1046 -1295 -1199 -982 -70 332 370 77 1022 461 1043 749 722 1265 978 1401 404 319 -4 -552 -464 -484 219 39 -1797 -3250 -3232 -2685 -1970 -619 -671 -211 106 605 664 1191 738 156 40 -772 -187 552 298 1070 1280 1052 1181 948 490 21 -38 755 1783 2457 3380 1439 -195 -952 -1417 823 1022 1126 2295 1340 2104 -129 -1167 -2625 -3973 -2941 -3492 -2853 -2656 -3593 -2390 -619 106 977 2153 2034 1774 812 -693 -1799 -2165 -1907 -1697 378 1755 684 134 -863 -2199 -2237 -1119 -1819 -1863 -495 -773 1199 2602 3449 2440 2374 625 -643 -410 -1020 -211 1308 1507 1493 1755 1938 622 1161 -768 -1824 -378 -913 -910 -1388 -1501 -1114 -183 323 478 1216 1577 1130 -139 -287 -1390 -1866 SS 20200825T200835.7Z 7542.839302 11 1 15.31 2 43.63 232.60 79.96 129.04 0.00 1 0.00 1 0 17 1.810e-02 1.484e-02 4.472e-03 2.474e-03 1.776782e-01 1.264928e-03 2.171468e-03 -6.000000e+00 1.046082e-02 230.84 -2.00 3.54 -2.00 315.84 0.00e+00 1.002467e-03 1.302042e-04 3.110099e-04 -6.000000e+00 4.659228e-04 287.44 -2.00 20.00 -2.00 315.09 0.00e+00 1.380 0.000 302.00 328.00 3 4.7879e+00 3.2916e-03 1.6314e-02 -6.0000e+00 2.6144e-02 2.8664e-02 3.6673e-03 9.0343e-03 -6.0000e+00 2.8288e-02 -3.2099e-03 2.1026e-03 4.3592e-03 -6.0000e+00 1.6861e-02 -1.2310e-02 9.5405e-04 1.2045e-03 -6.0000e+00 7.1507e-03 9.5370e-04 6.7167e-04 7.0363e-05 1.5182e-05 -6.0000e+00 4.8827e-04 -3.4644e-03 0.0000e+00 12 9 9 12 9 1 99.99 22.96 0.13 -0.00346 0.00158 18 12 1 5 0 796.160 25.68 19.99 22.96 34.01 999.00 28.1 996.60 914 1705 2114 -1827 -2611 -2198 -3389 -1432 -887 -3616 -2696 -2835 -1594 -1841 1249 584 6 2074 1172 3352 1438 1140 1771 1987 1318 1122 186 -733 -1446 -1849 -429 -232 931 -2933 -4720 -5197 -5611 -2579 -1540 -573 -521 -72 912 435 1047 464 530 16 -1798 -31 382 395 1338 1542 1282 1517 668 326 105 133 1019 2184 2824 2868 1209 -166 -1098 -1995 1063 663 1335 1817 1537 1993 85 -870 -2636 -4872 -3581 -3697 -3319 -2683 -3004 -1787 -704 346 1146 1533 2237 1727 680 -958 -2561 -2051 -1800 -1272 360 1612 556 121 -785 -2107 -2353 -1182 -1960 -1538 -583 -599 905 1706 2089 2048 1550 622 -800 -952 -1051 -179 916 972 954 1356 1829 754 559 -505 -1472 -398 -674 -353 -1042 -959 -878 -351 328 151 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