File name: Pandora167s1_KenoshaWI_20200919_L2Fit_fout2c9d20200520p1-8.txt File generation date: 20241119T112912.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Jim Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v3d20200117.txt Instrument calibration file used: Pandora167s1_CF_v9d20200520.txt Level 1 file used: Pandora167s1_KenoshaWI_20200919_L1_smca1c9d20200520p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20200919 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0344 305.1754 305.3164 305.4574 305.5983 305.7392 305.8802 306.0211 306.1620 306.3029 306.4438 306.5846 306.7255 306.8663 307.0072 307.1480 307.2888 307.4296 307.5704 307.7112 307.8519 307.9927 308.1334 308.2742 308.4149 308.5556 308.6963 308.8370 308.9777 309.1183 309.2590 309.3996 309.5403 309.6809 309.8215 309.9621 310.1027 310.2433 310.3838 310.5244 310.6649 310.8055 310.9460 311.0865 311.2270 311.3675 311.5079 311.6484 311.7888 311.9293 312.0697 312.2101 312.3505 312.4909 312.6313 312.7717 312.9120 313.0524 313.1927 313.3330 313.4734 313.6137 313.7539 313.8942 314.0345 314.1747 314.3150 314.4552 314.5954 314.7356 314.8758 315.0160 315.1562 315.2964 315.4365 315.5767 315.7168 315.8569 315.9970 316.1371 316.2772 316.4173 316.5573 316.6974 316.8374 316.9774 317.1174 317.2575 317.3974 317.5374 317.6774 317.8173 317.9573 318.0972 318.2371 318.3770 318.5169 318.6568 318.7967 318.9366 319.0764 319.2163 319.3561 319.4959 319.6357 319.7755 319.9153 320.0551 320.1948 320.3346 320.4743 320.6140 320.7537 320.8934 321.0331 321.1728 321.3125 321.4521 321.5918 321.7314 321.8710 322.0106 322.1502 322.2898 322.4294 322.5689 322.7085 322.8480 322.9875 323.1270 323.2665 323.4060 323.5455 323.6850 323.8244 323.9639 324.1033 324.2427 324.3821 324.5215 324.6609 324.8003 324.9396 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200919T131704.8Z 7567.553528 534 1 5.66 2 72.40 105.18 99.60 90.71 0.00 1 0.00 1 0 25 5.484e-02 1.511e-02 4.796e-02 4.498e-03 4.090508e-01 2.274899e-03 5.184576e-03 -6.000000e+00 3.143963e-02 228.52 -2.00 3.54 -2.00 318.99 0.00e+00 2.628481e-03 5.464862e-04 2.298431e-03 -6.000000e+00 1.398944e-03 285.21 -2.00 20.00 -2.00 318.24 0.00e+00 3.260 0.001 302.00 328.00 3 2.9510e+00 6.3068e-03 3.9024e-02 -6.0000e+00 7.8198e-02 -3.8612e-02 7.3056e-03 2.3383e-02 -6.0000e+00 8.4771e-02 2.1818e-02 5.3356e-03 1.1793e-02 -6.0000e+00 5.0557e-02 -1.7371e-02 2.8191e-03 3.4545e-03 -6.0000e+00 2.1514e-02 7.1552e-04 1.1485e-03 1.2787e-04 4.0530e-05 -6.0000e+00 1.4783e-03 -7.8307e-03 0.0000e+00 12 9 9 12 1 1 72.79 23.03 0.23 -0.00783 0.00080 6 12 1 5 0 783.710 25.79 20.00 23.03 16.53 30.4 1009.19 -11398 -19388 -31818 -2732 25799 -3647 -14790 -761 -5667 -12037 -23597 -646 -6833 -4614 -612 1864 9595 -1052 -8162 -2130 -6467 -3039 1728 1219 -7440 -4394 -637 -4607 -6770 -599 -262 -1143 3013 -4621 -8896 -7126 -2149 -3199 -3027 258 569 -184 -235 -219 1475 17 -977 285 -732 932 1598 2100 3124 1317 1592 2675 959 349 -1129 659 1087 2339 3806 4513 2601 -928 -1098 -1541 804 1096 1608 2527 1229 1788 -1020 -2018 -2710 -5654 -3322 -4301 -2444 -2451 -2468 -1365 -844 374 1783 2294 2039 2208 483 -1001 -2302 -2175 -1893 -1675 247 1562 1261 -313 -1198 -2456 -2808 -1355 -2082 -1626 -413 -150 1672 2034 2442 1900 1389 146 -589 -635 -1353 -429 844 678 1207 1622 1777 694 256 -712 -1815 -639 -704 -1485 -1415 -1094 -1249 -4 95 -80 818 1752 971 750 -347 -1195 -783 -295 -622 -1220 -79 528 -94 -443 -22 -196 -473 -1054 -25 -322 -256 -39 134 698 -91 -798 -207 -677 -309 173 130 -914 -552 -79 -574 -829 -70 -34 -167 473 -824 -1596 -1227 -380 -659 -740 71 173 -60 -79 -76 508 6 -350 101 -265 341 618 873 1375 621 779 1332 495 182 -585 335 564 1281 2240 2838 1704 -602 -684 -955 517 779 1229 1992 979 1381 -762 -1408 -1772 -3693 -2240 -3237 -2011 -2190 -2337 -1334 -860 398 1947 2560 2287 2425 512 -1013 -2240 -2089 -1911 -1828 290 1964 1670 -420 -1550 -3023 -3302 -1594 -2597 -2103 -548 -205 2362 3025 3798 3031 2197 226 -871 -909 -1938 -629 1279 1066 1914 2534 2724 1048 376 -1027 -2560 -903 -1051 -2360 -2343 -1859 -2164 -7 175 -153 1573 3391 1895 1445 -655 -2207 -1422 SU 20200919T131900.9Z 7567.554872 536 1 21.85 2 72.06 105.54 99.26 91.03 0.00 1 0.00 1 0 25 5.427e-02 1.388e-02 7.332e-03 6.511e-04 4.028439e-01 3.291771e-04 5.116874e-03 -6.000000e+00 3.110110e-02 228.52 -2.00 3.54 -2.00 319.20 0.00e+00 2.252289e-03 8.391767e-05 2.445975e-03 -6.000000e+00 1.383983e-03 285.21 -2.00 20.00 -2.00 318.45 0.00e+00 3.202 0.001 302.00 328.00 3 5.4838e-01 9.2387e-04 3.8651e-02 -6.0000e+00 7.7356e-02 -5.2085e-02 1.0782e-03 2.3951e-02 -6.0000e+00 8.3868e-02 2.7684e-02 8.0397e-04 1.1873e-02 -6.0000e+00 5.0018e-02 -2.3509e-02 4.2253e-04 3.2953e-03 -6.0000e+00 2.1276e-02 8.5078e-03 9.1869e-04 1.8713e-05 4.0691e-05 -6.0000e+00 1.4629e-03 -5.4499e-03 0.0000e+00 12 9 9 12 1 1 63.04 23.02 0.19 -0.00545 0.00145 345 151 1 5 0 62.630 25.79 20.01 23.02 16.62 30.4 1009.70 -16092 -8337 -12535 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-144 411 1317 2177 2643 1211 77 -420 -1038 611 877 1281 1810 1174 1288 -91 -1140 -2427 -3412 -2485 -2609 -2025 -1680 -2614 -1680 -515 588 1459 2058 2494 1880 879 -883 -2169 -2382 -1935 -1710 203 2134 983 -73 -1483 -2853 -2427 -1214 -1995 -1989 -607 -484 1510 2805 3606 2876 2006 324 -1405 -1316 -1171 -188 1276 1469 1671 2058 2598 1113 842 -1667 -2643 -693 -1349 -1381 -1927 -2280 -1867 -591 63 298 1543 2813 1842 749 -206 -1764 -1299 SU 20200919T132100.3Z 7567.556253 538 1 50.52 2 71.70 105.91 98.92 91.36 0.00 1 0.00 1 0 25 5.074e-02 1.334e-02 5.536e-03 4.367e-04 3.949174e-01 2.217464e-04 5.158138e-03 -6.000000e+00 2.907990e-02 228.52 -2.00 3.54 -2.00 319.46 0.00e+00 2.351752e-03 6.076961e-05 2.777684e-03 -6.000000e+00 1.294053e-03 285.21 -2.00 20.00 -2.00 318.72 0.00e+00 3.144 0.001 302.00 328.00 3 3.8513e-01 6.2798e-04 3.8378e-02 -6.0000e+00 7.2328e-02 -5.0846e-02 7.3887e-04 2.4744e-02 -6.0000e+00 7.8418e-02 3.0772e-02 5.6773e-04 1.2027e-02 -6.0000e+00 4.6768e-02 -2.5574e-02 2.9782e-04 3.1960e-03 -6.0000e+00 1.9893e-02 1.0664e-02 8.5005e-04 1.2790e-05 4.2805e-05 -6.0000e+00 1.3679e-03 -5.3016e-03 0.0000e+00 12 8 8 10 0 0 99.03 23.03 0.19 -0.00530 0.00109 994 187 1 5 0 50.660 25.79 20.00 23.03 16.70 30.5 1010.29 -10556 -7425 -7926 -10652 -16371 -15238 -21539 -15513 -14448 -15624 -17249 -17453 -12725 -9856 -3504 -2452 -2012 966 -267 522 -557 -917 86 -970 -1106 -1586 -2977 -5375 -5966 -5747 -3219 -1992 -759 -3983 -7596 -8011 -7737 -4400 -1584 -720 -278 -30 889 794 1868 1557 841 508 -1110 -464 716 1013 1875 1901 1677 1786 788 57 -331 -110 912 2580 3639 4230 1974 398 -626 -1540 1007 1271 1682 2284 1578 1665 -66 -1600 -3625 -5104 -3666 -3445 -2458 -1985 -2844 -1676 -530 454 1369 1877 2428 1770 884 -785 -2246 -2475 -1917 -1477 238 1615 763 -215 -1164 -2321 -2114 -1046 -1665 -1576 -602 -402 967 1905 2282 1698 1118 124 -891 -889 -729 -125 821 878 1018 1350 1642 751 509 -1153 -1917 -560 -841 -905 -1099 -1357 -1036 -362 11 202 792 1388 878 311 -113 -939 -655 -212 -168 -192 -259 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