File name: Pandora167s1_KenoshaWI_20201103_L2Fit_fout2c9d20200520p1-8.txt File generation date: 20241119T115215.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c9p1-8 Local principal investigator: Jim Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v3d20200117.txt Instrument calibration file used: Pandora167s1_CF_v9d20200520.txt Level 1 file used: Pandora167s1_KenoshaWI_20201103_L1_smca1c9d20200520p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20201103 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0344 305.1754 305.3164 305.4574 305.5983 305.7392 305.8802 306.0211 306.1620 306.3029 306.4438 306.5846 306.7255 306.8663 307.0072 307.1480 307.2888 307.4296 307.5704 307.7112 307.8519 307.9927 308.1334 308.2742 308.4149 308.5556 308.6963 308.8370 308.9777 309.1183 309.2590 309.3996 309.5403 309.6809 309.8215 309.9621 310.1027 310.2433 310.3838 310.5244 310.6649 310.8055 310.9460 311.0865 311.2270 311.3675 311.5079 311.6484 311.7888 311.9293 312.0697 312.2101 312.3505 312.4909 312.6313 312.7717 312.9120 313.0524 313.1927 313.3330 313.4734 313.6137 313.7539 313.8942 314.0345 314.1747 314.3150 314.4552 314.5954 314.7356 314.8758 315.0160 315.1562 315.2964 315.4365 315.5767 315.7168 315.8569 315.9970 316.1371 316.2772 316.4173 316.5573 316.6974 316.8374 316.9774 317.1174 317.2575 317.3974 317.5374 317.6774 317.8173 317.9573 318.0972 318.2371 318.3770 318.5169 318.6568 318.7967 318.9366 319.0764 319.2163 319.3561 319.4959 319.6357 319.7755 319.9153 320.0551 320.1948 320.3346 320.4743 320.6140 320.7537 320.8934 321.0331 321.1728 321.3125 321.4521 321.5918 321.7314 321.8710 322.0106 322.1502 322.2898 322.4294 322.5689 322.7085 322.8480 322.9875 323.1270 323.2665 323.4060 323.5455 323.6850 323.8244 323.9639 324.1033 324.2427 324.3821 324.5215 324.6609 324.8003 324.9396 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20201103T130500.3Z 7612.545142 230 1 50.55 2 84.59 116.52 68.78 279.90 0.00 1 0.00 1 0 25 9.658e-01 6.038e-02 5.160e-01 4.467e-02 7.739561e-01 2.559207e-02 1.080483e-02 -6.000000e+00 5.532406e-01 223.81 -2.00 3.54 -2.00 322.10 0.00e+00 2.447992e-02 1.192064e-02 6.366143e-03 -6.000000e+00 2.586499e-02 279.59 -2.00 20.00 -2.00 321.60 0.00e+00 9.268 0.015 302.00 328.00 3 8.1602e-01 9.1790e-02 9.9835e-02 -6.0000e+00 1.3697e+00 1.3615e+00 1.1011e-01 4.0746e-02 -6.0000e+00 1.4974e+00 -1.6089e+00 7.6322e-02 2.7845e-02 -6.0000e+00 8.8828e-01 6.0634e-01 3.9312e-02 2.2311e-02 -6.0000e+00 3.8533e-01 1.2156e-05 2.2620e-05 1.3151e-03 4.2953e-04 -6.0000e+00 2.7166e-02 -1.3043e-02 0.0000e+00 12 8 8 10 0 0 98.23 23.06 0.54 -0.01304 -0.01287 21 4 1 5 0 2406.770 25.79 19.99 23.06 11.66 28.5 996.24 900000 900000 151782 16322 -46699 31030 -125213 900000 -74607 -1137 27118 900000 -28034 900000 900000 87874 900000 204857 72151 900000 42791 26783 -43012 -3537 103151 -106534 615840 64534 -64167 900000 900000 900000 37170 -54659 326681 340110 166215 -25563 32571 21075 213505 50908 323627 25552 8700 247990 -41778 140230 28586 26585 32629 900000 96380 1204 17372 17289 231647 59944 95683 -11471 -27765 133144 -208 -20655 5364 53266 85264 80844 118577 28549 61239 38433 -18524 1362 -17727 -16767 55466 53662 -3437 43954 -8929 -4238 1766 -10541 16895 3673 8155 3130 -4356 -2617 8558 -1721 -1003 -23194 -5305 -8445 202 -7203 1656 -3564 3243 -929 -6034 7160 1011 -1338 -6435 -1180 5560 -3646 3599 66 5349 -836 -6950 -4853 2472 -1243 -4454 6118 3442 1267 7414 -63 4705 1166 -2885 2462 2631 -3324 -3022 -1548 -105 3130 -1699 1971 -641 2002 2185 -324 -1273 -3256 -305 900000 900000 6597 774 -3342 1349 -13469 900000 -4164 -49 1179 900000 -1218 900000 900000 3819 900000 8904 3136 900000 1980 1300 -3650 -190 4483 -12944 26767 2805 -4750 900000 900000 900000 1926 -7029 14199 14783 7224 -2257 1846 1463 9280 2926 14066 1975 796 10779 -6394 6095 2424 2396 2988 900000 5601 178 2250 2213 10068 4840 5244 -1673 -4833 5787 -35 -4748 1040 6544 7603 7612 8404 5283 9078 7261 -5816 331 -4650 -3891 6093 6121 -755 7428 -2924 -1514 655 -4630 6030 1569 3489 1449 -2171 -1248 3456 -717 -402 -11834 -2589 -5008 130 -5830 1373 -3190 2581 -695 -4257 4359 696 -1003 -5374 -1011 4965 -4065 4245 88 6903 -1130 -9582 -6368 3058 -1681 -6614 8579 4930 1778 9462 -85 5854 1464 -3671 3128 3825 -5923 -5997 -3289 -235 7215 -4407 5213 -1782 5518 6024 -886 -3295 -8035 -703 SU 20201103T131137.4Z 7612.549739 236 1 50.85 2 83.51 117.69 69.94 280.91 0.00 1 0.00 1 0 25 4.557e-01 2.380e-02 3.559e-01 1.361e-02 7.129383e-01 7.475948e-03 1.161035e-02 -6.000000e+00 2.572161e-01 223.81 -2.00 3.54 -2.00 322.04 0.00e+00 1.624266e-02 4.244124e-03 1.632225e-02 -6.000000e+00 1.152842e-02 279.59 -2.00 20.00 -2.00 321.58 0.00e+00 8.018 0.010 302.00 328.00 3 6.7670e-01 2.8611e-02 1.1264e-01 -6.0000e+00 6.3390e-01 5.8456e-01 3.7630e-02 8.7357e-02 -6.0000e+00 6.9019e-01 -9.2403e-01 3.4674e-02 4.2965e-02 -6.0000e+00 4.1214e-01 3.8163e-01 1.6384e-02 1.4287e-02 -6.0000e+00 1.7912e-01 6.1087e-05 3.2937e-04 3.9905e-04 4.7503e-04 -6.0000e+00 1.2436e-02 -1.4427e-02 0.0000e+00 12 8 8 10 0 0 23.41 23.06 0.42 -0.01443 -0.01195 65 12 1 5 0 781.490 25.79 20.00 23.06 11.71 28.7 997.86 900000 900000 135110 -89152 -62831 -153146 -147112 -117703 -73495 -160767 -108112 -24702 -25755 85022 900000 -19228 -47092 -55381 -24603 -83532 -51749 -25726 900000 107030 -67673 -29875 -61167 49170 39302 218224 86991 -65994 28963 40919 15595 12947 37456 -12884 7790 19425 43288 30048 27778 49196 69536 51509 -6228 13576 21697 22277 24815 41916 22383 4438 22554 34928 52128 21513 8133 14840 37817 11274 22485 16748 23811 21802 4703 11505 12715 14636 11451 21402 6438 5425 -5340 2287 -6836 384 -5562 1375 4475 -3441 -2473 814 -547 6034 4000 -598 2465 -4736 -3710 -4628 -7986 -4635 -9168 -5949 -2584 -493 1601 523 -2523 -2421 -4342 -3325 -2213 -2408 -480 -847 -99 2462 -100 1355 1256 -225 -2915 -1336 -2730 -1749 1299 2452 3109 3203 3542 3109 777 -1182 -2576 477 -611 -202 -238 -1160 -931 444 411 277 -307 1445 1038 -55 -186 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1.753339e-02 3.318704e-03 1.812337e-02 -6.000000e+00 1.281751e-02 279.59 -2.00 20.00 -2.00 321.55 0.00e+00 7.683 0.008 302.00 328.00 3 6.6802e-01 2.2497e-02 1.1673e-01 -6.0000e+00 6.9911e-01 4.2242e-01 3.0920e-02 1.0142e-01 -6.0000e+00 7.6149e-01 -6.9701e-01 2.9702e-02 5.1188e-02 -6.0000e+00 4.5230e-01 2.9002e-01 1.3696e-02 1.6093e-02 -6.0000e+00 1.9319e-01 8.6229e-05 4.0733e-04 3.1395e-04 4.8897e-04 -6.0000e+00 1.3581e-02 -1.3711e-02 0.0000e+00 12 8 8 10 0 0 14.24 23.04 0.37 -0.01371 -0.01065 79 15 1 5 0 640.830 25.79 20.00 23.04 11.79 28.7 998.70 -175370 -192943 -159639 10149 -111992 -100959 4002 -170571 900000 -49743 -86382 -202740 900000 -60252 -60914 65603 -20025 7385 -68867 157127 1292 -52208 108497 47174 78377 -80448 2324 -55827 -36320 -4052 -52962 42963 40121 84791 80804 -23514 16557 -2376 32339 110776 46385 58514 10028 30368 14648 47336 27313 76624 32228 40049 23218 41770 38184 19926 23485 17448 25056 8057 539 19364 1141 41025 12058 19872 18946 2850 14681 7528 19861 12114 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