File name: Pandora167s1_KenoshaWI_20201215_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T183345.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Jim Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v3d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20201215_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20201215 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201215T140319.3Z 7654.585640 69 1 50.54 2 83.52 130.11 93.61 121.77 0.00 1 0.00 1 0 25 5.182e-01 3.473e-02 4.185e-01 2.493e-02 6.662808e-01 1.422918e-02 1.229267e-02 -6.000000e+00 3.063392e-01 222.44 -2.00 3.54 -2.00 321.88 0.00e+00 2.068299e-02 7.357880e-03 1.554480e-02 -6.000000e+00 1.530318e-02 274.76 -2.00 20.00 -2.00 321.43 0.00e+00 8.035 0.010 302.00 328.00 3 1.5090e+00 5.0786e-02 1.0555e-01 -6.0000e+00 7.6374e-01 7.2337e-01 6.7143e-02 7.8399e-02 -6.0000e+00 8.4190e-01 -1.0496e+00 6.0690e-02 5.5000e-02 -6.0000e+00 4.9526e-01 4.4520e-01 2.8781e-02 2.5364e-02 -6.0000e+00 2.0759e-01 2.5465e-05 -1.4235e-04 7.8045e-04 5.4728e-04 -6.0000e+00 1.5179e-02 9.7801e-03 0.0000e+00 12 9 8 11 8 0 95.53 22.80 0.74 0.00978 0.00871 19 4 1 5 0 2659.430 25.58 20.00 22.80 0.56 27.7 1009.48 -115116 900000 900000 -16373 900000 -114146 57527 900000 900000 -161772 -84414 900000 -133390 93978 900000 71052 900000 900000 900000 900000 900000 9006 70829 900000 900000 900000 114214 220988 59519 900000 -53616 95401 119731 108932 900000 66893 105212 1579 96560 900000 12301 29714 57912 76171 51719 63989 110870 124643 80616 47961 92482 13747 43577 71299 1915 31851 15093 42663 23430 49345 66548 -16581 47398 43543 8936 3656 24211 20177 -11881 18526 9575 22964 11427 19027 -13595 -11646 -12318 -9615 -10042 507 12900 -2622 -495 -1966 206 3494 -7636 3286 6132 -2074 274 4418 -5777 -1175 -8207 -11405 -5637 4808 -5006 1068 -241 -5598 -4306 -5408 639 -6488 -723 -3908 3177 2139 2459 3645 -744 -929 -3674 -2185 -264 1941 2018 1255 1734 922 6498 1014 1090 3821 -2527 -1429 1569 -396 -2483 -757 -811 149 -758 257 1951 1016 -257 1849 -1005 -1177 -2203 -5905 900000 900000 -397 900000 -5357 1393 900000 900000 -9551 -2172 900000 -7270 2276 900000 1721 900000 900000 900000 900000 900000 320 1716 900000 900000 900000 2766 5353 1442 900000 -3247 2311 2900 2639 900000 1728 2548 87 2339 900000 854 1823 2805 3198 2840 3203 3581 3623 3775 3253 4331 1457 3941 5181 270 3327 1851 4133 2483 4223 4943 -2912 5358 5471 1718 736 3848 3360 -2914 3814 2392 5249 2906 4234 -3828 -2874 -2816 -2140 -2493 136 3632 -992 -203 -869 94 1656 -4277 1716 3147 -1130 137 1980 -2729 -537 -4485 -7562 -4164 3734 -4812 998 -218 -4830 -3305 -4102 487 -5696 -635 -3816 3179 2448 3161 5011 -1027 -1336 -5178 -2911 -345 2612 2899 1919 2654 1379 8863 1421 1476 4888 -3336 -1918 2306 -682 -4575 -1478 -1670 323 -1776 631 4846 2594 -669 4570 -2408 -2647 -5083 SS 20201215T141339.5Z 7654.592819 72 1 51.07 2 82.08 132.01 92.07 123.42 0.00 1 0.00 1 0 25 4.271e-01 1.682e-02 2.652e-01 6.368e-03 6.060284e-01 3.429369e-03 1.067519e-02 -6.000000e+00 2.413907e-01 222.44 -2.00 3.54 -2.00 321.60 0.00e+00 1.102731e-02 1.703648e-03 1.330422e-02 -6.000000e+00 1.050633e-02 274.76 -2.00 20.00 -2.00 321.13 0.00e+00 6.785 0.006 302.00 328.00 3 8.1018e-01 1.1835e-02 9.2253e-02 -6.0000e+00 5.9410e-01 1.0173e-01 1.6623e-02 7.6683e-02 -6.0000e+00 6.4757e-01 -2.2639e-01 1.7715e-02 4.8512e-02 -6.0000e+00 3.8443e-01 9.1651e-02 8.4033e-03 1.8550e-02 -6.0000e+00 1.6403e-01 1.9826e-04 1.2472e-03 1.9235e-04 3.7233e-04 -6.0000e+00 1.1541e-02 8.9994e-03 0.0000e+00 12 8 8 10 0 0 75.93 22.78 0.41 0.00900 0.01837 94 18 1 5 0 537.510 25.58 20.00 22.78 1.05 27.8 1009.56 -204074 -152597 -162603 -11667 -49184 -131574 900000 -129409 -11252 -131093 -170572 -114325 -104375 -25342 -52392 38363 -16254 -58768 -18315 -36056 136189 -39173 20800 -44665 -66323 -41354 -49435 -23163 -17654 -10130 -20631 -12133 6044 -22268 21423 -10049 573 -14873 2463 25769 -6063 25050 9957 10882 9508 -1809 3750 11633 9697 2574 8769 4192 14989 18043 5547 10189 -2093 5985 -7079 1573 426 6245 13963 9955 11800 2221 4258 180 6704 5927 -1033 3244 1420 3884 1128 -4273 -4130 -5238 -7510 -5458 -3837 -742 -1757 -519 852 1532 473 1340 2192 1728 434 -2949 -5395 -5203 -2953 -2963 -1599 2222 839 372 -1278 -2846 -3017 -1093 -1360 -1716 -676 -803 1638 2125 2666 2134 685 -676 -2343 -1910 -1131 268 1533 1426 2322 1878 2472 1488 477 -928 -3168 -677 -1152 -991 -1308 -729 -565 -922 -116 -168 413 1449 1445 94 -15 -803 -1046 -3456 -1895 -2478 -72 -305 -1262 900000 -1315 -70 -1554 -3081 -1291 -1355 -200 -710 286 -220 -1360 -310 -773 846 -884 258 -1109 -2134 -1074 -1423 -510 -369 -212 -571 -377 184 -993 605 -374 20 -714 120 1178 -431 1414 697 792 724 -147 299 972 865 240 844 473 1667 2110 778 1408 -335 883 -1165 235 67 1018 2413 2040 2558 525 961 43 1623 1665 -348 1106 494 1258 347 -1249 -1113 -1426 -2308 -1954 -1598 -344 -912 -283 490 938 311 907 1487 1150 275 -1802 -3213 -3128 -1922 -2241 -1392 2148 842 384 -1272 -2826 -2729 -960 -1288 -1744 -719 -846 1841 2663 3702 3186 1048 -1017 -3396 -2634 -1548 379 2283 2244 3645 2877 3640 2150 672 -1281 -4318 -1001 -1772 -1727 -2523 -1496 -1215 -2111 -281 -434 1091 3871 3888 250 -37 -1923 -2424 SS 20201215T142520.1Z 7654.600927 75 1 50.11 2 80.51 134.21 90.37 125.30 0.00 1 0.00 1 0 33 3.018e-01 1.474e-02 1.191e-01 3.153e-03 5.421705e-01 1.646486e-03 8.642236e-03 -6.000000e+00 1.694582e-01 222.44 -2.00 3.54 -2.00 321.15 0.00e+00 8.793717e-03 7.307009e-04 8.941973e-03 -6.000000e+00 7.379349e-03 274.76 -2.00 20.00 -2.00 320.67 0.00e+00 5.782 0.004 302.00 328.00 3 7.5144e-01 5.3376e-03 7.2049e-02 -6.0000e+00 4.1720e-01 3.7173e-03 7.1531e-03 5.2612e-02 -6.0000e+00 4.5463e-01 -5.0912e-02 7.4833e-03 3.5728e-02 -6.0000e+00 2.7071e-01 1.1602e-02 3.6584e-03 1.4856e-02 -6.0000e+00 1.1590e-01 5.5996e-04 1.1733e-03 9.4062e-05 2.7026e-04 -6.0000e+00 8.1162e-03 8.7334e-03 0.0000e+00 12 8 8 10 0 0 97.01 22.78 0.26 0.00873 0.01755 169 32 1 5 0 296.470 25.58 20.00 22.78 1.73 27.8 1010.32 -146995 -35124 -39831 -80824 -36573 -81210 -126124 -125566 -99842 -92836 -100695 -73443 -80086 -46660 -51003 -22591 13385 12477 16433 -29603 -2810 -25656 -20295 -1642 -15952 3745 -25040 -16768 -35856 -25961 -11173 -11411 2864 -4765 -8723 -19768 -10299 -5448 -5215 -592 -186 -1952 -3374 4617 10185 3171 7223 1836 4695 1469 6021 5515 7274 6066 2335 6462 -554 -325 -916 1150 1749 2666 7495 5443 3925 2071 1331 747 615 3041 2187 3122 1039 1553 -1070 -4719 -4868 -7906 -4346 -2610 -1475 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