File name: Pandora167s1_KenoshaWI_20201218_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T183538.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Jim Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v3d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20201218_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20201218 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201218T142532.8Z 7657.601074 65 1 51.65 2 80.76 134.03 115.38 94.87 0.00 1 0.00 1 0 25 5.791e-01 2.465e-02 3.317e-01 1.461e-02 6.323815e-01 8.224334e-03 1.003124e-02 -6.000000e+00 3.385730e-01 222.55 -2.00 3.54 -2.00 321.55 0.00e+00 8.372670e-03 4.028261e-03 1.168435e-02 -6.000000e+00 1.683540e-02 274.57 -2.00 20.00 -2.00 321.09 0.00e+00 5.921 0.004 302.00 328.00 3 2.9346e+00 2.8129e-02 8.2916e-02 -6.0000e+00 8.4347e-01 1.4977e-01 3.8887e-02 7.0104e-02 -6.0000e+00 9.2757e-01 -2.9358e-01 4.0375e-02 4.2994e-02 -6.0000e+00 5.5064e-01 1.3109e-01 1.9246e-02 1.5917e-02 -6.0000e+00 2.3226e-01 4.8643e-05 3.5711e-04 4.5626e-04 3.3028e-04 -6.0000e+00 1.6848e-02 8.4405e-03 0.0000e+00 12 8 8 10 0 0 82.57 22.86 0.36 0.00844 0.01112 17 3 1 5 0 3037.290 25.68 20.00 22.86 4.95 28.4 1006.26 -259972 155492 900000 900000 900000 900000 25403 92457 -57548 900000 -90661 -31006 900000 900000 900000 900000 900000 900000 900000 -19421 900000 -111780 7776 -79894 -100081 -68718 -9495 37341 -13516 900000 8438 -72664 472789 -2811 900000 52396 37421 -21174 38485 95999 -32337 41013 13349 29450 7237 17712 15261 -3430 35025 15349 42905 11364 -936 -3519 6563 43715 -5388 12439 18375 2231 7868 17211 11319 19674 19018 8750 -1324 10089 7717 8536 9778 3362 471 2098 525 5410 -4833 -2088 -1105 -3462 -1596 -1210 -4737 922 -4477 3121 1012 1105 469 -3112 -282 -5777 629 -2780 -6804 -6258 -575 2876 2580 -413 -430 -2974 -2969 -238 -711 -4333 -516 744 -227 2372 490 974 -1965 -241 -2004 -2538 328 -1583 3924 1427 3174 1736 2998 1934 88 1634 -2102 1388 -728 -2106 -753 -1488 -854 -1332 887 23 1042 1923 627 174 -79 -1045 -1999 -8599 2209 900000 900000 900000 900000 361 1314 -818 900000 -1288 -441 900000 900000 900000 900000 900000 900000 900000 -392 900000 -5418 125 -3014 -4790 -2556 -208 531 -301 900000 189 -4150 6718 -107 900000 1134 980 -1089 1356 2340 -2935 2025 902 1784 551 1258 1141 -316 2349 1307 3090 1223 -124 -517 928 4501 -905 1767 2410 336 1149 2504 1976 3597 3782 1908 -310 2148 1813 2277 2877 1112 161 674 158 1407 -1280 -536 -308 -1161 -620 -535 -2403 472 -2567 1779 621 705 304 -2040 -170 -3423 335 -1540 -4321 -4558 -461 2560 2550 -431 -427 -2765 -2505 -192 -617 -4148 -503 763 -256 2910 680 1441 -3031 -357 -2867 -3495 437 -2240 5588 2186 4816 2589 4271 2705 121 2146 -2758 1802 -1072 -3548 -1374 -2923 -1747 -2886 2008 56 2552 4748 1576 427 -184 -2328 -4327 SS 20201218T143744.3Z 7657.609540 71 1 50.52 2 79.18 136.37 113.22 96.74 0.00 1 0.00 1 0 25 3.788e-01 1.654e-02 1.814e-01 5.643e-03 5.623786e-01 2.949330e-03 8.449744e-03 -6.000000e+00 2.127635e-01 222.55 -2.00 3.54 -2.00 321.13 0.00e+00 7.017394e-03 1.291185e-03 8.307596e-03 -6.000000e+00 9.253971e-03 274.57 -2.00 20.00 -2.00 320.64 0.00e+00 5.131 0.002 302.00 328.00 3 2.3576e+00 9.4875e-03 6.6693e-02 -6.0000e+00 5.2397e-01 3.7933e-02 1.2558e-02 5.1077e-02 -6.0000e+00 5.7095e-01 -1.1110e-01 1.2785e-02 3.2094e-02 -6.0000e+00 3.3990e-01 3.8192e-02 6.2636e-03 1.2336e-02 -6.0000e+00 1.4548e-01 1.9671e-04 1.0397e-03 1.6669e-04 2.2814e-04 -6.0000e+00 1.0186e-02 8.3535e-03 0.0000e+00 12 8 8 10 0 0 82.32 22.86 0.23 0.00835 0.01617 49 9 1 5 0 1030.760 25.68 20.00 22.86 5.50 28.4 1006.43 -142900 160394 -105840 -19452 -150519 -135395 -116743 -186481 -67360 -81426 -95166 -113076 -30836 -68368 -15886 -7400 -35729 -3220 -14236 -10440 -8125 -24470 -26820 -33820 -10503 -10927 -12873 -17492 -41922 -3259 -3552 1444 5517 -6094 -9503 -7556 23579 9141 3229 12420 6065 9664 4346 3373 4885 9982 10338 8728 1673 8719 9259 3638 7536 6151 8052 4504 -1866 -804 3961 246 942 6890 12500 5421 3407 146 3965 -1646 1943 913 3345 3005 227 243 358 -4084 -4009 -6861 -4070 -5080 -2510 -1935 -1440 -1995 -1300 -49 1317 1207 2031 2093 57 -1045 -2187 -4802 -3680 -3531 -665 1645 1014 640 -857 -2105 -2577 -801 -1736 -1754 -213 -37 1297 1720 2647 1986 471 -576 -1461 -1489 -1088 -231 702 939 1822 1742 3160 1223 632 -2033 -2696 -1261 -1276 -69 -1002 -1470 -945 -674 -77 81 805 1429 1369 386 -213 -1009 -1008 -2064 883 -1435 -119 -2874 -2134 -1594 -5254 -708 -1042 -1428 -2159 -337 -1348 -243 -126 -892 -66 -349 -261 -206 -721 -818 -1155 -307 -336 -414 -581 -1722 -99 -123 57 241 -323 -513 -387 963 489 219 913 534 888 444 362 529 1060 1121 989 210 1074 1238 569 1242 1107 1506 902 -408 -175 805 51 200 1507 2927 1525 1046 45 1154 -508 624 338 1346 1283 100 102 140 -1513 -1367 -2375 -1488 -2186 -1230 -1070 -872 -1287 -887 -35 988 942 1586 1595 42 -721 -1450 -3258 -2697 -2943 -619 1704 1157 747 -965 -2196 -2474 -749 -1756 -1885 -238 -43 1629 2371 3967 3167 764 -916 -2218 -2163 -1566 -343 1095 1534 2986 2785 4843 1855 932 -2973 -3820 -1797 -1997 -119 -1888 -2945 -1959 -1463 -176 194 1976 3547 3422 952 -504 -2294 -2226 SS 20201218T144351.7Z 7657.613793 74 1 49.45 2 78.41 137.57 112.13 97.67 0.00 1 0.00 1 0 41 2.946e-01 1.653e-02 2.947e-01 9.471e-03 5.270616e-01 5.012610e-03 7.735281e-03 -6.000000e+00 1.663612e-01 222.55 -2.00 3.54 -2.00 320.97 0.00e+00 9.438643e-03 2.125850e-03 6.558252e-03 -6.000000e+00 7.490713e-03 274.57 -2.00 20.00 -2.00 320.48 0.00e+00 4.817 0.002 302.00 328.00 3 3.4793e+00 1.5829e-02 5.8634e-02 -6.0000e+00 4.1045e-01 2.2329e-02 2.0854e-02 3.9009e-02 -6.0000e+00 4.4800e-01 -4.9550e-02 2.1553e-02 3.0779e-02 -6.0000e+00 2.6544e-01 1.0682e-02 1.0662e-02 1.5170e-02 -6.0000e+00 1.1544e-01 8.6808e-05 1.1964e-03 2.8628e-04 2.2227e-04 -6.0000e+00 8.2255e-03 8.6918e-03 0.0000e+00 12 8 8 10 0 0 97.48 22.82 0.27 0.00869 0.01768 20 4 1 5 0 2471.930 25.68 20.00 22.82 5.66 28.4 1006.14 900000 900000 57972 30263 900000 -151944 -2468 -120664 900000 25012 60808 -31679 -145214 900000 -10584 35317 -14555 54954 63849 39574 78194 -21664 22875 -2651 1039 83009 -38267 115635 -36888 5269 -27173 2292 28792 14413 2969 -6515 7407 1 -1613 4128 7403 32914 -1870 21608 5637 -6321 1424 2540 19050 -12568 8993 3390 605 5570 -784 3831 -4486 2347 -2537 -2937 2396 1832 6260 4040 10256 3367 2134 -3594 -2153 -1086 4649 3451 84 1704 -2302 -830 -6911 -9978 336 -4075 -2060 -2374 -3696 -1277 -2376 2548 -540 1589 2434 810 -504 -1653 -790 -1794 -3676 -1226 -1151 1662 936 2042 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