File name: Pandora167s1_KenoshaWI_20201222_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T183856.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Jim Szykman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v3d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20201222_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20201222 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20201222T140636.4Z 7661.587921 61 1 50.72 2 83.64 130.16 133.39 37.04 0.00 1 0.00 1 0 25 5.590e-01 3.148e-02 3.993e-01 1.860e-02 7.619216e-01 1.062312e-02 1.094508e-02 -6.000000e+00 3.208582e-01 222.69 -2.00 3.54 -2.00 322.18 0.00e+00 3.291633e-03 5.563026e-03 1.620911e-02 -6.000000e+00 1.450392e-02 274.33 -2.00 20.00 -2.00 321.74 0.00e+00 8.163 0.010 302.00 328.00 3 7.7954e-01 3.9532e-02 1.2038e-01 -6.0000e+00 7.9499e-01 8.0383e-01 5.1517e-02 1.0944e-01 -6.0000e+00 8.6939e-01 -1.2331e+00 4.5157e-02 5.3632e-02 -6.0000e+00 5.1309e-01 5.0323e-01 2.1704e-02 1.3563e-02 -6.0000e+00 2.1914e-01 4.6362e-05 1.3695e-03 5.6775e-04 3.8889e-04 -6.0000e+00 1.5597e-02 6.0309e-03 0.0000e+00 12 8 8 10 0 0 40.21 22.71 0.62 0.00603 0.01632 45 8 1 5 0 1126.920 25.58 20.00 22.71 7.05 29.0 1001.78 128308 -116878 900000 -75020 900000 -64721 48435 900000 -91148 900000 -99764 -34381 -137023 -3211 900000 75845 33686 15363 900000 41915 240362 63522 -46306 -29959 7223 -32354 16388 -53989 131130 -5522 900000 25609 29366 61634 229627 900000 -14889 138942 -31240 57983 -2609 34943 204093 7740 900000 53328 50456 -8948 69070 177346 12181 156169 38437 62073 58807 43162 59443 15420 85142 22588 738 924 14642 43702 12611 18679 7473 30836 9262 28038 31161 10090 17372 -10374 14843 -752 -20103 9491 -13377 5371 -6860 8864 -1324 2696 4241 -1019 8402 1158 7611 -517 657 -1716 -8840 -2762 -12143 -7938 -2608 -502 1255 -2857 418 -8411 -2057 -5938 -5391 -3294 -2983 1671 -4464 898 1788 1048 1198 -3312 -1129 -4022 -406 -367 1024 3366 954 6095 3339 3305 3195 505 -1409 -582 1964 -907 -814 -517 -64 -641 -1687 333 1451 2148 1925 -320 -1212 -2858 -1043 2324 -6350 900000 -2508 900000 -1563 877 900000 -3026 900000 -3614 -675 -8208 -68 900000 1374 763 441 900000 949 4353 1150 -2236 -1266 218 -1465 445 -2770 2375 -167 900000 773 975 1581 4159 900000 -742 2516 -2452 2188 -201 1951 3696 584 900000 2495 2437 -797 2919 3212 1048 3857 3074 4216 4349 3843 4575 1815 4754 2250 91 123 1923 4881 2074 2875 1263 4235 1719 4951 5925 2482 3933 -2688 2935 -154 -4612 1633 -3230 1289 -2045 2618 -483 1010 1666 -450 3558 545 3372 -241 285 -715 -3830 -1166 -6361 -4700 -1726 -379 1042 -2543 343 -6807 -1407 -4145 -4011 -2570 -2460 1422 -4484 979 2196 1416 1666 -4757 -1525 -5390 -528 -501 1465 4933 1428 8338 4522 4365 4099 647 -1788 -762 2864 -1576 -1586 -1090 -143 -1541 -4415 907 4009 5991 5393 -885 -3164 -7070 -2423 SS 20201222T141637.6Z 7661.594879 64 1 51.12 2 82.25 132.00 132.26 39.94 0.00 1 0.00 1 0 25 5.497e-01 1.650e-02 3.253e-01 6.645e-03 6.854985e-01 3.708146e-03 1.100572e-02 -6.000000e+00 3.118437e-01 222.69 -2.00 3.54 -2.00 321.95 0.00e+00 1.704739e-02 2.005820e-03 1.155081e-02 -6.000000e+00 1.414596e-02 274.33 -2.00 20.00 -2.00 321.51 0.00e+00 6.912 0.006 302.00 328.00 3 6.4144e-01 1.3549e-02 8.6444e-02 -6.0000e+00 7.7059e-01 1.4572e-01 2.0326e-02 5.7427e-02 -6.0000e+00 8.4163e-01 -2.9893e-01 2.2920e-02 4.8043e-02 -6.0000e+00 5.0132e-01 1.2245e-01 1.0614e-02 2.6001e-02 -6.0000e+00 2.1504e-01 1.8855e-04 1.1519e-03 2.0319e-04 4.8326e-04 -6.0000e+00 1.4960e-02 6.0932e-03 0.0000e+00 12 8 8 10 0 0 1.15 22.70 0.46 0.00609 0.01475 108 20 1 5 0 468.880 25.58 20.00 22.70 7.62 29.1 1002.02 -255885 900000 -188688 900000 -157224 -47423 -174492 -170963 -185063 -154764 -173455 -198857 900000 67587 -31184 -103409 -32727 900000 -15018 900000 -46389 -79697 -100559 -107500 75427 77318 -7121 24253 2055 31391 -39987 25242 -21619 99135 11073 -7696 -11261 -14917 37969 -14793 16560 3129 14122 11751 6232 20136 12409 19018 832 20675 18937 5320 20959 9975 15531 5332 4144 6993 -7101 3100 11162 17404 7824 9009 10729 3014 7518 1794 2962 4425 6004 4061 -2923 4399 1665 -2796 -5171 -5723 -7019 -6212 -1706 -3180 -1917 -2973 -2792 1071 2056 3127 2976 2046 1413 -3009 -3542 -5947 -4366 -2609 966 2280 1253 395 -1582 -1351 -2851 -996 -1534 -2186 -1434 -1737 2206 1413 2612 1281 275 -1103 -2223 -2534 -1079 431 968 1590 1673 1713 2910 1835 530 -1336 -2324 -261 -1303 -65 -932 -1345 -974 -534 210 -326 768 1236 1314 512 -150 -1226 -1141 -3589 900000 -2110 900000 -1203 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1.047255e-02 274.33 -2.00 20.00 -2.00 320.98 0.00e+00 5.909 0.004 302.00 328.00 3 4.8870e-01 5.5446e-03 7.6632e-02 -6.0000e+00 5.9901e-01 1.3504e-03 7.8993e-03 5.8280e-02 -6.0000e+00 6.5289e-01 -8.6533e-02 8.7015e-03 4.3696e-02 -6.0000e+00 3.8708e-01 3.0787e-02 4.1412e-03 2.0018e-02 -6.0000e+00 1.6497e-01 6.0250e-04 1.1089e-03 9.0773e-05 3.5167e-04 -6.0000e+00 1.1710e-02 5.7654e-03 0.0000e+00 12 8 8 10 0 0 -1.08 22.72 0.25 0.00577 0.01410 212 40 1 5 0 237.830 25.58 20.01 22.72 8.13 29.1 1001.75 -61603 -149065 -145557 -79366 -208095 201739 -179497 900000 -126099 -90742 -33098 -171843 -47718 -109422 -27694 4441 -18970 -4588 -16135 -12776 -42102 12154 -11475 -23887 -13254 -35167 -11790 -28267 -53 -17849 -25880 -3957 -11418 11756 -12843 1613 -18868 2051 13584 -6492 -2407 -5373 8755 3778 4925 9796 4388 6494 4549 9247 6485 10090 9040 4613 6433 1932 6227 -952 -345 1265 613 2513 3522 8840 4765 2369 2585 -1474 3864 1443 3550 2313 1017 1365 -1722 -1350 -5435 -6881 -4580 -3317 -1525 -1851 -1959 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