File name: Pandora167s1_KenoshaWI_20210214_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T185332.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20210214_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20210214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210214T132244.7Z 7715.557462 52 1 51.38 2 84.95 112.54 103.96 84.81 0.00 1 0.00 1 0 49 5.547e-01 7.321e-02 5.002e-01 6.906e-02 8.728715e-01 4.019643e-02 9.553922e-03 -6.000000e+00 3.197186e-01 224.68 -2.00 3.54 -2.00 321.94 0.00e+00 -2.756181e-02 1.516844e-02 1.367837e-02 -6.000000e+00 1.667703e-02 272.86 -2.00 20.00 -2.00 321.43 0.00e+00 9.773 0.018 302.00 328.00 3 7.6025e-01 1.3262e-01 1.3587e-01 -6.0000e+00 7.9074e-01 1.6725e+00 1.5584e-01 1.2293e-01 -6.0000e+00 8.6275e-01 -1.8965e+00 9.9781e-02 3.5240e-02 -6.0000e+00 5.1142e-01 6.6732e-01 5.4345e-02 1.3853e-02 -6.0000e+00 2.2346e-01 7.9860e-06 7.8026e-03 2.0123e-03 8.0256e-05 -6.0000e+00 1.5723e-02 2.6756e-03 0.0000e+00 12 8 8 10 0 0 86.23 22.80 1.40 0.00268 0.06131 14 3 1 5 0 3669.580 25.68 20.00 22.80 -13.31 26.8 1012.95 900000 153989 900000 900000 -30413 -65654 106480 -54958 900000 -25413 35035 900000 76383 900000 -42668 22224 61344 69281 20969 900000 900000 900000 900000 900000 72052 900000 3237 900000 -30047 900000 -32069 -52092 32925 15809 193059 -65208 124805 -32656 -15093 126155 900000 27545 43863 53848 50731 50415 154174 221313 900000 -11356 900000 -691 164073 194276 -6794 46246 26942 166260 41453 47913 -23304 35479 -2269 -36552 38147 -14192 -2739 9100 5191 7759 18585 48126 59331 25795 41963 -67934 -13340 23909 -37626 14869 49696 74870 44345 11006 20709 3599 225 21829 11680 1754 6843 3671 -13226 -21380 1423 -25289 17186 26341 3909 1175 -11281 -2176 -8229 -18183 -5401 11546 7420 1863 8666 -141 1862 7259 -4223 -7733 4306 -7095 -7802 -3315 5920 407 802 3324 6326 3417 9077 1261 -2431 28 1107 -1211 3199 -7010 -1767 2274 2435 -957 2268 -621 3725 2775 -255 -4910 -3461 900000 10335 900000 900000 -2551 -7344 7146 -7377 900000 -3127 2565 900000 5126 900000 -6682 2034 4117 4650 1791 900000 900000 900000 900000 900000 4836 900000 375 900000 -3300 900000 -3522 -7628 2210 1254 12957 -9946 8376 -4582 -2210 8467 900000 3529 4549 4599 4024 3691 10347 14853 900000 -1524 900000 -101 11011 13038 -1326 5643 4109 11158 4805 4677 -4408 3896 -401 -10036 5120 -3117 -535 1666 1108 1846 4309 8515 9050 5036 6145 -26112 -2767 3501 -11478 3175 8793 11877 10552 3895 7076 1537 103 8124 4703 738 2547 1344 -5729 -10827 660 -17898 9227 14785 2981 918 -9292 -1461 -5372 -13313 -3757 7185 5115 1478 7243 -149 2192 8769 -5875 -10994 5228 -9394 -10567 -4510 7766 579 1106 4259 7604 4128 10079 1470 -2892 35 1608 -2084 5895 -15526 -3989 5341 6180 -2645 6199 -1770 10046 7161 -628 -11802 -8003 SS 20210214T164955.3Z 7715.701334 168 1 50.59 2 57.93 158.15 67.66 120.20 0.00 1 0.00 1 0 17 2.674e-02 1.451e-02 1.552e-02 4.360e-03 2.427714e-01 2.168808e-03 2.973738e-03 -6.000000e+00 1.515743e-02 224.69 -2.00 3.54 -2.00 317.79 0.00e+00 1.542713e-03 3.386253e-04 6.976937e-04 -6.000000e+00 6.488006e-04 272.87 -2.00 20.00 -2.00 317.22 0.00e+00 1.877 0.000 302.00 328.00 3 5.1669e+00 5.7251e-03 2.1978e-02 -6.0000e+00 3.7527e-02 3.9101e-02 6.4586e-03 1.2186e-02 -6.0000e+00 4.0829e-02 2.9432e-03 4.0129e-03 6.2255e-03 -6.0000e+00 2.4246e-02 -1.4840e-02 2.0219e-03 2.0409e-03 -6.0000e+00 1.0327e-02 3.5960e-04 5.9661e-04 1.2757e-04 1.9273e-05 -6.0000e+00 7.1934e-04 7.9877e-04 0.0000e+00 12 8 8 10 0 0 99.98 22.83 0.37 0.00080 0.00528 70 13 1 5 0 722.620 25.68 19.99 22.83 -10.53 26.9 1013.15 -1112 2974 918 -80 -5056 -2659 -14966 5123 -4954 -4279 -8214 -8614 -6307 -2939 3931 1157 2886 2641 1942 1611 2259 79 3380 -413 1163 -298 -2206 -1564 -2631 -414 2606 -1183 2112 -2229 -6602 -5032 -4217 -2528 -1983 -1055 -397 -300 627 216 1037 2812 -282 -151 -1183 186 732 937 2062 1016 865 1375 826 763 -238 -529 -211 1845 2490 3622 2649 650 -700 -2179 -579 147 423 1782 1736 2248 156 -596 -3087 -4981 -4312 -3469 -2841 -1402 -3313 -2209 -1039 -331 1524 1912 2276 1913 340 -7 -2520 -2164 -2070 -1945 -351 471 1285 -127 -304 -1826 -2535 -1385 -1504 -1987 -328 -600 1040 1860 2275 1765 1144 755 -735 -752 -680 -756 130 934 999 1178 1647 621 864 -1123 -2023 -400 -960 -655 -1397 -1296 -1242 -326 -161 711 1110 1253 907 312 38 -1047 -1223 -103 299 98 -8 -505 -240 -1532 475 -565 -517 -1034 -1086 -844 -436 624 211 548 520 400 345 495 18 733 -96 280 -76 -580 -394 -627 -93 585 -298 556 -645 -1922 -1367 -1188 -795 -735 -454 -189 -151 322 114 541 1448 -148 -78 -598 92 373 507 1172 612 540 870 535 496 -154 -339 -137 1245 1808 2788 2109 499 -499 -1502 -404 114 360 1583 1560 1965 132 -463 -2213 -3393 -2944 -2583 -2363 -1265 -3269 -2256 -1109 -376 1794 2333 2798 2313 392 -7 -2520 -2037 -2002 -2038 -400 587 1704 -172 -392 -2222 -2906 -1577 -1843 -2601 -441 -842 1499 2811 3610 2881 1835 1150 -1049 -1005 -888 -1018 184 1402 1554 1824 2489 918 1219 -1545 -2669 -511 -1293 -942 -2122 -2028 -1972 -527 -273 1262 2020 2327 1709 585 69 -1867 -2130 SS 20210214T182903.6Z 7715.770180 236 1 3.14 2 55.52 187.01 53.98 143.22 0.00 1 0.00 1 0 25 2.148e-02 1.537e-02 8.730e-03 4.506e-03 2.317958e-01 2.266431e-03 2.759779e-03 -6.000000e+00 1.217851e-02 224.69 -2.00 3.54 -2.00 315.97 0.00e+00 1.385179e-03 2.330927e-04 1.952474e-04 -6.000000e+00 5.211971e-04 272.87 -2.00 20.00 -2.00 315.47 0.00e+00 1.761 0.000 302.00 328.00 3 3.7495e+00 5.8294e-03 2.0662e-02 -6.0000e+00 3.0152e-02 2.0731e-02 6.5122e-03 1.1538e-02 -6.0000e+00 3.2803e-02 -3.1390e-03 3.7783e-03 5.6882e-03 -6.0000e+00 1.9480e-02 -1.1194e-02 1.7601e-03 1.7878e-03 -6.0000e+00 8.2989e-03 1.7041e-03 4.8715e-04 1.2660e-04 1.8278e-05 -6.0000e+00 5.7786e-04 -3.2405e-04 0.0000e+00 12 9 9 12 1 1 999.00 22.86 0.28 -0.00032 0.00334 2 10 1 5 0 985.650 25.68 20.01 22.86 -9.28 27.1 1013.81 2307 2775 -988 -910 -780 -39 -8573 447 -3194 -3652 -4169 -5582 -1745 -1231 2680 1189 -563 2072 1857 2143 3335 1109 2017 2966 1431 110 2503 -2875 -1516 -3316 -2196 -512 724 283 -5894 -6689 -5053 -4127 -1213 815 606 -363 800 30 983 1914 1822 1440 -2321 -672 940 -196 1044 2704 1301 2298 799 -413 -490 -486 15 2678 2004 3537 1783 -399 -960 -3466 119 1117 634 2596 1546 2248 464 -448 -3876 -3558 -3905 -3828 -2867 -1752 -3440 -2282 -928 -287 533 1582 1876 1950 1544 -9 -1347 -2905 -1666 -1466 -184 1325 885 681 -855 -740 -2085 -1101 -1770 -1310 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