File name: Pandora167s1_KenoshaWI_20210218_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T185432.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20210218_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20210218 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210218T142537.5Z 7719.601128 89 1 50.93 2 73.62 123.32 106.62 52.07 0.00 1 0.00 1 0 25 1.355e-01 1.369e-02 3.078e-02 1.338e-03 4.943405e-01 6.916533e-04 6.610215e-03 -6.000000e+00 7.688289e-02 224.85 -2.00 3.54 -2.00 320.28 0.00e+00 6.415322e-03 2.355093e-04 4.200169e-03 -6.000000e+00 3.297921e-03 273.14 -2.00 20.00 -2.00 319.79 0.00e+00 3.489 0.001 302.00 328.00 3 1.7687e+00 2.0241e-03 4.4606e-02 -6.0000e+00 1.9041e-01 -4.3529e-02 2.4892e-03 3.0325e-02 -6.0000e+00 2.0720e-01 5.0114e-03 2.3639e-03 2.1573e-02 -6.0000e+00 1.2297e-01 -1.2768e-02 1.2191e-03 1.0291e-02 -6.0000e+00 5.2755e-02 1.7189e-03 8.6958e-04 3.8838e-05 1.3701e-04 -6.0000e+00 3.6727e-03 -2.9986e-03 0.0000e+00 12 9 8 11 8 0 99.43 22.67 0.23 -0.00300 0.00354 196 37 1 5 0 257.160 25.47 19.99 22.67 2.72 29.5 1008.75 900000 -31884 -52667 -33380 -49509 -52470 -37476 -58567 -25647 -49483 -34236 -53738 -22266 -20597 -16225 -515 -10840 -1695 -5254 933 3661 -6594 3188 -9660 -805 -9610 -8417 -10170 -11411 -8531 -11900 -865 191 -1084 -5023 -8968 -5086 -6765 -908 -2924 -863 -644 -1174 1700 201 2645 2251 2393 735 798 2060 1083 3548 3211 2392 2080 328 -292 -2329 -348 -172 2442 3593 4581 3300 277 398 -1634 905 1595 1784 3088 1106 1591 -422 -1953 -4254 -6185 -4580 -4244 -2322 -1721 -2424 -2103 -864 469 928 1885 2357 2027 1114 -304 -2496 -3251 -2669 -1991 10 1794 1270 552 -772 -1913 -2375 -1166 -1158 -1754 -502 -490 782 1777 2194 1772 935 168 -1280 -1152 -978 -308 738 1003 1153 1299 1907 987 420 -986 -2507 -700 -1016 -877 -1045 -1495 -1136 -758 -48 -41 500 1489 1234 430 94 -694 -865 900000 -374 -768 -408 -658 -672 -465 -896 -348 -839 -516 -1045 -380 -442 -422 -14 -369 -58 -203 36 143 -287 127 -461 -37 -512 -456 -555 -616 -461 -752 -58 15 -92 -440 -783 -450 -644 -98 -388 -128 -103 -200 293 36 474 414 447 143 161 443 260 907 888 705 635 105 -94 -754 -109 -55 823 1345 1901 1479 125 172 -711 406 811 1015 1842 679 936 -236 -1000 -2029 -2904 -2244 -2396 -1499 -1159 -1809 -1658 -715 411 857 1796 2258 1904 992 -254 -1985 -2550 -2231 -1874 11 2119 1543 691 -931 -2288 -2599 -1241 -1320 -2149 -638 -613 1034 2554 3438 2950 1572 273 -1976 -1672 -1396 -453 1141 1640 1917 2114 2981 1507 618 -1411 -3483 -956 -1518 -1460 -1896 -2886 -2115 -1474 -99 -89 1116 3360 2819 969 202 -1429 -1716 SS 20210218T143824.1Z 7719.610001 98 1 36.24 2 71.68 125.89 104.76 54.50 0.00 1 0.00 1 0 25 8.608e-02 1.369e-02 2.851e-02 1.643e-03 4.528075e-01 8.334791e-04 5.755411e-03 -6.000000e+00 4.885117e-02 224.85 -2.00 3.54 -2.00 319.85 0.00e+00 4.632308e-03 2.504885e-04 2.949868e-03 -6.000000e+00 2.095547e-03 273.14 -2.00 20.00 -2.00 319.35 0.00e+00 3.141 0.001 302.00 328.00 3 2.3573e+00 2.3641e-03 3.9390e-02 -6.0000e+00 1.2099e-01 -4.5184e-02 2.8247e-03 2.5460e-02 -6.0000e+00 1.3166e-01 1.5369e-02 2.4952e-03 1.6481e-02 -6.0000e+00 7.8132e-02 -1.8297e-02 1.3139e-03 7.4177e-03 -6.0000e+00 3.3520e-02 1.3864e-03 7.8526e-04 4.7347e-05 8.9367e-05 -6.0000e+00 2.3337e-03 -2.8348e-03 0.0000e+00 12 9 9 12 9 1 99.79 22.70 0.16 -0.00283 0.00307 98 26 1 5 0 360.580 25.58 19.99 22.70 3.50 29.4 1007.60 900000 200 -23378 -17206 -34363 -23182 -28146 -35448 -9150 -40843 -24448 -35260 -23272 -10148 -13011 4789 -8964 5760 -1684 2407 4166 -1978 3558 -5741 -816 -6063 -5651 -3682 -10274 -4922 -7468 -1451 -1358 -2405 -2691 -9599 -5894 -6050 -1205 -2063 -496 313 -953 2086 466 1581 0 1391 -561 -138 2625 468 2796 2539 1918 1793 -27 -215 -2089 -683 61 2206 3900 4154 2865 394 498 -1786 512 1345 1463 2631 1379 1829 -40 -2232 -3463 -5615 -3988 -4262 -2464 -2021 -2622 -2049 -768 408 1010 2081 2218 2238 1332 -544 -2269 -3071 -2501 -1972 -165 1798 1268 439 -728 -1922 -2152 -922 -1302 -1824 -618 -524 842 1655 2028 1744 944 247 -1055 -1090 -856 -360 817 889 1204 1162 2024 849 540 -779 -2430 -775 -876 -977 -1010 -1484 -1186 -606 97 43 622 1463 1184 479 6 -666 -903 900000 3 -421 -294 -642 -362 -473 -710 -159 -1058 -555 -937 -646 -309 -505 186 -415 271 -85 124 220 -111 208 -358 -52 -427 -407 -256 -737 -340 -586 -124 -133 -261 -288 -1053 -656 -778 -178 -369 -100 67 -218 481 111 380 0 343 -143 -36 717 144 913 893 665 642 -10 -81 -790 -251 23 866 1680 1984 1468 202 241 -869 256 759 925 1745 936 1193 -25 -1278 -1821 -2891 -2121 -2606 -1715 -1587 -2122 -1746 -686 387 1009 2140 2302 2270 1279 -491 -1933 -2566 -2209 -1952 -182 2210 1615 575 -917 -2385 -2447 -1023 -1554 -2194 -771 -690 1166 2483 3106 2821 1534 388 -1658 -1609 -1239 -538 1281 1395 1922 1825 3243 1331 813 -1139 -3444 -1078 -1321 -1633 -1725 -2683 -2210 -1174 187 87 1307 3112 2553 1019 12 -1300 -1804 SS 20210218T150328.3Z 7719.627411 111 1 50.65 2 68.06 131.18 100.97 59.09 0.00 1 0.00 1 0 25 1.736e-01 1.923e-02 1.530e-01 1.245e-02 3.905095e-01 6.314662e-03 5.197662e-03 -6.000000e+00 9.855882e-02 224.85 -2.00 3.54 -2.00 319.63 0.00e+00 7.621305e-03 1.703215e-03 2.666842e-03 -6.000000e+00 4.225277e-03 273.14 -2.00 20.00 -2.00 319.11 0.00e+00 2.653 0.000 302.00 328.00 3 5.6744e+00 1.7594e-02 3.3180e-02 -6.0000e+00 2.4410e-01 5.2239e-02 2.0552e-02 2.0509e-02 -6.0000e+00 2.6558e-01 -6.8875e-03 1.6357e-02 1.5279e-02 -6.0000e+00 1.5761e-01 -1.0624e-02 8.6500e-03 8.9484e-03 -6.0000e+00 6.7664e-02 8.0381e-05 8.5081e-04 3.6811e-04 9.7415e-05 -6.0000e+00 4.7053e-03 -7.1864e-03 0.0000e+00 12 8 8 10 0 0 99.99 22.67 0.27 -0.00719 -0.00079 27 5 1 5 0 1875.460 25.58 19.99 22.67 4.01 29.3 1007.22 900000 117160 -21172 -41544 23676 -73001 -31838 -46883 5728 14493 -95769 2686 -23999 12059 13810 40678 19725 1141 -4755 -6626 10924 11446 4011 17475 -12749 8824 -16239 15366 584 -17512 3135 -2693 -9048 -7373 2350 -17349 13081 -7515 -6287 -4672 -9035 5980 7327 951 2471 9576 1547 548 9411 1462 1236 5741 3503 3601 -3591 2265 -2118 4320 1603 123 1883 -88 3822 7702 3920 -2097 463 -388 -2235 2262 1410 4224 2508 3245 -391 -1576 -1401 -6360 -1385 -3496 -4373 -968 -4548 -2852 429 -427 101 1028 504 1388 502 -551 -1942 -2990 -1634 -2125 -856 1344 -713 1582 -171 -1667 -3518 -2349 -1850 -3626 967 -496 649 2875 1930 2268 211 -89 711 -1735 -1116 -1539 1345 447 1371 2372 3499 426 -230 -56 -2833 148 -926 -783 -724 -1825 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