File name: Pandora167s1_KenoshaWI_20210304_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T185910.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20210304_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20210304 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210304T131358.5Z 7733.551371 259 1 50.99 2 81.35 106.75 71.34 221.45 0.00 1 0.00 1 0 25 5.843e-01 2.047e-02 3.245e-01 8.249e-03 8.083916e-01 4.676685e-03 1.287548e-02 -6.000000e+00 3.343273e-01 225.44 -2.00 3.54 -2.00 322.11 0.00e+00 1.847726e-02 2.573132e-03 1.430400e-02 -6.000000e+00 1.453679e-02 274.10 -2.00 20.00 -2.00 321.68 0.00e+00 6.279 0.005 302.00 328.00 3 1.2484e+00 1.7385e-02 9.1908e-02 -6.0000e+00 8.3043e-01 3.4283e-01 2.6191e-02 7.2122e-02 -6.0000e+00 9.0357e-01 -6.5923e-01 2.8525e-02 5.4347e-02 -6.0000e+00 5.3530e-01 2.8368e-01 1.3068e-02 2.7583e-02 -6.0000e+00 2.2869e-01 1.5499e-04 6.9321e-04 2.3667e-04 5.7617e-04 -6.0000e+00 1.5964e-02 2.0234e-03 0.0000e+00 12 8 8 10 0 0 99.98 22.88 0.33 0.00202 0.00723 122 23 1 5 0 414.480 25.68 19.99 22.88 6.27 30.2 1007.47 -244362 900000 -231547 -92399 -131462 -142234 -59562 -192893 900000 -220817 -189006 -63787 -192706 900000 -166463 900000 -8943 -26718 -36222 -57951 63525 -34088 900000 -85035 -76684 -41855 -110682 -106687 -61574 -27573 -60414 74568 80395 -7344 37274 -53083 682 -10690 16682 37274 -15368 47387 32149 32441 17643 16733 30267 5444 39101 6331 49465 21089 28608 25100 11220 38288 22215 11028 17105 21913 8234 17787 21369 17864 27386 6276 10691 12769 11539 12443 6435 14473 3880 8137 2854 -3289 -1763 -5291 357 -4434 -812 1556 -2211 -7 -479 3542 1520 486 2779 792 2992 -4443 -3228 -8821 -5714 -3819 -1706 2289 -364 -252 -2373 -2956 -5180 -3725 -482 -3631 -1184 -1698 299 2014 2103 1769 82 -1190 -3034 -1529 -786 -157 1388 945 2863 2283 3841 2182 949 -199 -2728 -332 -1021 -151 -112 -830 -288 -843 309 -344 548 1226 1077 811 -466 -799 -1924 -4068 900000 -4786 -743 -1057 -1143 -479 -2266 900000 -3550 -2220 -513 -3455 900000 -4528 900000 -84 -314 -515 -1075 511 -485 900000 -1945 -1612 -621 -3285 -3034 -1142 -409 -1569 699 862 -195 622 -2068 16 -317 443 945 -688 1318 1113 1183 774 776 1291 294 1741 393 2385 1417 1971 1945 1056 2814 1939 1064 1502 1799 799 1736 2343 2211 3419 985 1598 1929 1923 2367 1455 3180 942 1783 600 -656 -321 -1018 74 -1171 -250 545 -902 -3 -204 1649 715 240 1351 384 1424 -2136 -1479 -4410 -3138 -2298 -1199 1819 -336 -241 -2213 -2493 -3971 -2711 -360 -2989 -1007 -1567 300 2278 2715 2512 122 -1778 -4439 -2121 -1085 -225 2085 1491 4399 3376 5345 2996 1276 -263 -3587 -441 -1563 -266 -224 -1815 -666 -2099 769 -912 1476 3329 2935 2138 -1235 -1971 -4559 SS 20210304T132735.2Z 7733.560824 264 1 50.41 2 78.96 109.18 73.03 224.24 0.00 1 0.00 1 0 33 5.444e-01 1.513e-02 1.087e-01 2.231e-03 6.835765e-01 1.199168e-03 1.092949e-02 -6.000000e+00 3.093935e-01 225.44 -2.00 3.54 -2.00 321.51 0.00e+00 1.101395e-02 5.819869e-04 1.127817e-02 -6.000000e+00 1.327346e-02 274.10 -2.00 20.00 -2.00 321.06 0.00e+00 5.039 0.002 302.00 328.00 3 6.7736e-01 3.9932e-03 7.4692e-02 -6.0000e+00 7.6700e-01 -9.8102e-05 5.8702e-03 6.5052e-02 -6.0000e+00 8.3388e-01 -1.1817e-01 6.6217e-03 4.6470e-02 -6.0000e+00 4.9526e-01 4.6679e-02 3.1314e-03 2.0197e-02 -6.0000e+00 2.1082e-01 1.0049e-03 1.2044e-03 6.3156e-05 3.4235e-04 -6.0000e+00 1.4645e-02 1.5396e-03 0.0000e+00 12 8 8 10 0 0 99.95 22.86 0.27 0.00154 0.01059 307 58 1 5 0 164.180 25.68 19.99 22.86 6.52 29.8 1006.54 -202063 -114102 -222916 -123262 -166873 -222208 -130171 -181234 -155353 -172409 -169765 -156859 -140125 -31356 -88685 -20738 -47377 -22326 -18448 -48977 -35010 -43667 -12663 -48680 -6809 -40743 -41518 -33851 -42736 11679 -24244 -4355 -10017 -14985 5068 -22309 4167 -17220 -3854 -560 -3398 10144 -1175 8284 2941 7722 9016 4105 9533 5343 11852 5940 11867 8206 5904 7344 1826 1650 -2359 2756 1876 3200 9058 8146 8380 4279 3439 242 1626 3835 2214 4131 1175 2398 -1783 -3706 -6009 -7782 -4722 -4321 -1353 -930 -1899 -1470 -995 540 1590 2258 2091 1910 25 -2053 -3850 -5256 -3441 -2640 -429 1874 1312 315 -798 -2082 -2676 -1377 -1498 -2435 -615 -702 1108 1977 2485 1816 591 -109 -1964 -1687 -946 47 1134 1022 1476 1686 2589 1450 461 -819 -2704 -499 -712 -593 -853 -1382 -1099 -610 -84 -89 467 1669 1241 435 -259 -675 -933 -1599 -521 -3131 -724 -1287 -2813 -736 -1685 -1352 -1739 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0.00e+00 4.629 0.002 302.00 328.00 3 1.1698e+00 4.5316e-03 6.6314e-02 -6.0000e+00 5.9231e-01 -4.8827e-02 6.4670e-03 5.5607e-02 -6.0000e+00 6.4399e-01 -2.2154e-02 7.1931e-03 4.0889e-02 -6.0000e+00 3.8246e-01 2.8855e-03 3.4433e-03 1.8221e-02 -6.0000e+00 1.6306e-01 9.2908e-04 1.0771e-03 7.4136e-05 2.8196e-04 -6.0000e+00 1.1504e-02 1.2994e-03 0.0000e+00 12 8 8 10 0 0 99.99 22.83 0.20 0.00130 0.00939 374 70 1 5 0 135.050 25.68 20.00 22.83 6.71 29.9 1006.89 -150179 -139808 -106696 -158854 900000 -191499 -22380 -162440 -126076 -109694 -169646 21458 -125030 17203 -64074 -54582 -27158 -47137 37784 -51657 18716 -30397 -14825 -12798 -40037 4875 -40250 -14910 -16259 -33642 -13882 -15384 18571 -10229 -925 -7844 -14793 -6734 -9132 6893 -3900 5604 5806 3417 9582 -1015 10124 1305 9680 5771 6275 6881 2365 10624 2568 5796 1483 -1242 1606 -3369 2589 1738 8281 6604 4859 3153 127 1467 -745 3964 1876 2538 1887 663 929 -5020 -4327 -6165 -4856 -2817 -2984 -1115 -2903 -1911 -1083 266 1211 1009 2711 1652 1369 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