File name: Pandora167s1_KenoshaWI_20210311_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T190226.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20210311_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20210311 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210311T125145.2Z 7740.535940 59 1 50.40 2 83.12 101.18 80.47 123.85 0.00 1 0.00 1 0 25 5.280e-01 2.624e-02 3.759e-01 1.565e-02 7.827709e-01 8.908116e-03 1.254764e-02 -6.000000e+00 3.034275e-01 225.74 -2.00 3.54 -2.00 322.16 0.00e+00 1.884569e-02 4.867557e-03 1.414200e-02 -6.000000e+00 1.480836e-02 274.59 -2.00 20.00 -2.00 321.73 0.00e+00 7.649 0.008 302.00 328.00 3 9.2976e-01 3.3198e-02 1.0001e-01 -6.0000e+00 7.5426e-01 7.3957e-01 4.4415e-02 6.6418e-02 -6.0000e+00 8.2153e-01 -1.1123e+00 4.1943e-02 4.6695e-02 -6.0000e+00 4.8623e-01 4.5096e-01 1.9858e-02 2.4387e-02 -6.0000e+00 2.0713e-01 5.8783e-05 1.4064e-03 4.6597e-04 5.5651e-04 -6.0000e+00 1.4460e-02 1.4178e-03 0.0000e+00 12 8 8 10 0 0 47.61 22.87 0.56 0.00142 0.01199 50 9 1 5 0 1007.700 25.68 20.01 22.87 13.05 30.1 991.69 -100995 -139878 96793 23108 187417 -127069 163557 -60064 -125564 900000 -88829 900000 -170322 -49826 -113359 -40969 82546 147610 900000 -23881 -2660 900000 -21012 900000 -68090 900000 -51039 -79538 900000 -44785 900000 -45444 54672 -18194 35967 63987 -23222 229697 -22283 67833 -6043 45801 23581 10444 40602 29886 70180 37784 1579 110965 13412 82456 17296 63231 43334 42655 62051 19827 37620 692 39177 8136 -339 22277 23860 21704 13506 28842 -3093 20890 17832 7722 10727 13393 20327 5880 -9792 -8141 -13699 7369 4372 10113 2174 -5583 303 1842 2626 1930 9378 -98 -1905 -6633 -10577 -5025 -8940 -2442 -4190 1791 281 -1311 -1849 -6176 -1173 -4731 -2144 -699 -4086 -2468 -1903 1955 876 683 206 -720 -1046 -3721 -546 -1263 677 1738 2075 4449 1917 4108 2783 -871 -1275 -87 1997 -955 112 -1699 -435 -291 338 -105 301 1816 1235 590 -531 -2062 -1568 -2181 -4919 1475 352 2856 -3228 2493 -915 -2711 900000 -1354 900000 -7355 -886 -5039 -1093 1258 2250 900000 -728 -64 900000 -534 900000 -2594 900000 -1556 -3131 900000 -1365 900000 -2135 1111 -832 914 1138 -1003 3501 -1217 1723 -353 1687 1138 597 1753 1480 2407 1871 118 2959 1039 3561 1560 3855 3357 3359 4019 1914 2914 76 2985 930 -49 2942 3394 3170 2110 3956 -584 3551 3470 1738 2314 2638 3666 1090 -1814 -1634 -3035 1607 1179 2988 775 -2291 124 793 1182 907 4123 -46 -860 -2939 -4699 -2180 -4569 -1391 -2893 1369 245 -1205 -1630 -5119 -827 -3355 -1579 -542 -3478 -2236 -1906 2159 1115 953 298 -1037 -1453 -5125 -733 -1796 1006 2681 3177 6390 2710 5529 3680 -1161 -1660 -116 2998 -1718 224 -3775 -1015 -674 838 -276 811 4901 3363 1565 -1331 -5263 -3796 SS 20210311T130155.5Z 7740.543003 62 1 50.99 2 81.29 102.95 78.95 125.70 0.00 1 0.00 1 0 33 5.117e-01 1.535e-02 2.779e-01 4.943e-03 6.997376e-01 2.677518e-03 1.100230e-02 -6.000000e+00 2.911982e-01 225.74 -2.00 3.54 -2.00 321.75 0.00e+00 1.149979e-02 1.393414e-03 1.260884e-02 -6.000000e+00 1.250173e-02 274.59 -2.00 20.00 -2.00 321.31 0.00e+00 6.238 0.005 302.00 328.00 3 7.9744e-01 9.4614e-03 8.7737e-02 -6.0000e+00 7.2226e-01 1.0079e-01 1.4257e-02 7.3506e-02 -6.0000e+00 7.8498e-01 -2.3881e-01 1.6025e-02 5.0964e-02 -6.0000e+00 4.6625e-01 9.7746e-02 7.4432e-03 2.1538e-02 -6.0000e+00 1.9846e-01 2.9227e-04 1.3704e-03 1.4362e-04 3.9015e-04 -6.0000e+00 1.3768e-02 7.2914e-04 0.0000e+00 12 8 8 10 0 0 17.20 22.90 0.39 0.00073 0.01103 128 24 1 5 0 395.170 25.68 20.01 22.90 13.32 30.1 991.83 -146882 -188177 -129943 -162599 -81518 -226731 -163185 -104897 -170862 -8729 -155254 -16506 -193259 -123296 -85879 -8135 -49249 -85975 -13230 -98219 -30608 -41142 -37478 -26312 -65410 -30419 -60866 -17980 -52890 -46158 52545 -14480 -2180 -32687 16215 4516 -7392 12129 -17601 -3619 4767 1818 15760 5928 17528 8234 19565 1965 11171 6663 10959 20006 15144 7239 5198 9215 7681 -13 8308 -3087 1578 -1647 13765 10008 7980 4147 4702 3060 3080 3400 4686 5747 3712 -1218 -1683 -4200 -5279 -7441 -4627 -3670 -2050 1317 -2941 -2944 -1168 466 711 1886 1649 1549 150 -1626 -3899 -5000 -3566 -2409 -651 1687 843 9 -369 -2709 -972 -1972 -1234 -2058 -274 -887 1671 1997 2113 1801 604 -16 -2044 -2155 -1198 -431 910 1500 1519 2145 2628 1801 124 -1360 -3182 -686 -941 -731 -720 -1490 -638 -666 296 -140 569 1390 1028 401 -354 -1004 -719 -708 -1567 -752 -1211 -393 -2782 -1180 -506 -1565 -42 -1347 -80 -3218 -1545 -994 -55 -594 -1545 -140 -2367 -428 -635 -560 -368 -1290 -484 -1350 -260 -1096 -979 507 -342 -55 -1132 375 113 -201 345 -740 -159 219 94 760 333 906 487 1080 136 749 502 879 1657 1460 825 645 1139 990 -2 1041 -427 215 -255 2111 1685 1500 815 905 613 672 854 1304 1676 1106 -363 -463 -1064 -1251 -1811 -1219 -1150 -754 543 -1411 -1509 -627 263 424 1157 1023 940 87 -895 -2102 -2776 -2177 -1704 -532 1566 882 10 -383 -2602 -825 -1653 -1096 -1968 -272 -951 1917 2581 3070 2621 908 -23 -2942 -3220 -1769 -660 1350 2325 2355 3456 4049 2715 183 -1976 -4549 -984 -1524 -1253 -1373 -3091 -1386 -1540 728 -366 1521 3748 2797 1065 -893 -2387 -1631 SS 20210311T131541.2Z 7740.552560 67 1 50.36 2 78.82 105.39 76.95 128.27 0.00 1 0.00 1 0 25 3.383e-01 1.509e-02 1.068e-01 2.932e-03 5.772357e-01 1.539882e-03 8.951143e-03 -6.000000e+00 1.925220e-01 225.74 -2.00 3.54 -2.00 321.14 0.00e+00 8.500000e-03 6.737000e-04 8.999045e-03 -6.000000e+00 8.266432e-03 274.59 -2.00 20.00 -2.00 320.67 0.00e+00 4.982 0.002 302.00 328.00 3 1.3887e+00 4.9357e-03 6.7176e-02 -6.0000e+00 4.7751e-01 6.9815e-03 6.6327e-03 5.4023e-02 -6.0000e+00 5.1900e-01 -7.8533e-02 6.9577e-03 3.6497e-02 -6.0000e+00 3.0826e-01 2.7330e-02 3.4042e-03 1.4964e-02 -6.0000e+00 1.3120e-01 5.7913e-04 1.0802e-03 8.5756e-05 2.4965e-04 -6.0000e+00 9.1036e-03 1.4901e-03 0.0000e+00 12 8 8 10 0 0 99.73 22.87 0.25 0.00149 0.00961 144 27 1 5 0 349.700 25.68 19.99 22.87 13.63 30.0 991.51 -170912 -116897 -71023 -32074 -53651 -68193 -120239 -84854 -88486 -119879 -87429 -142324 -80472 -80516 -65373 -33361 -38077 18273 -30788 -16767 -22181 -15868 -10451 -15007 -5105 -22263 -14937 -37782 -32674 -2080 -22004 -9456 -3610 1144 -14239 1791 -3783 -1597 4389 8513 6005 1059 5075 848 3689 5886 3076 5006 2232 3660 7382 5291 7569 5164 6863 2516 4070 -143 -3400 -35 1578 4163 5894 7393 4491 1369 1428 -885 1234 2503 3289 3140 1627 1837 -2471 -1609 -6212 -6318 -5337 -3422 -2333 -1546 -2011 -2607 -518 -228 950 2227 2089 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