File name: Pandora167s1_KenoshaWI_20210312_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T190203.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20210312_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20210312 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210312T124025.0Z 7741.528067 46 1 39.97 2 84.86 98.99 86.31 110.63 0.00 1 0.00 1 0 25 6.440e-01 6.704e-02 5.193e-01 6.553e-02 8.587091e-01 3.991213e-02 1.104480e-02 -6.000000e+00 3.842886e-01 225.78 -2.00 3.54 -2.00 322.08 0.00e+00 1.262427e-02 1.644444e-02 7.481121e-03 -6.000000e+00 2.051945e-02 274.65 -2.00 20.00 -2.00 321.60 0.00e+00 9.644 0.017 302.00 328.00 3 5.2713e-01 1.3350e-01 1.0737e-01 -6.0000e+00 9.6139e-01 1.8027e+00 1.5687e-01 4.8695e-02 -6.0000e+00 1.0555e+00 -1.8811e+00 1.0762e-01 3.0331e-02 -6.0000e+00 6.1418e-01 6.4463e-01 5.8224e-02 1.5684e-02 -6.0000e+00 2.6365e-01 9.1118e-06 1.5091e-04 1.9551e-03 3.1406e-04 -6.0000e+00 1.9057e-02 3.4193e-03 0.0000e+00 12 9 9 12 1 1 73.10 22.90 1.60 0.00342 0.00455 11 3 1 5 0 3315.830 25.68 19.99 22.90 10.02 30.2 1008.02 900000 76997 900000 33894 91752 -31408 900000 213698 900000 900000 -44452 900000 900000 -98410 900000 4721 76048 900000 900000 37004 900000 900000 27568 183858 -50680 -20360 900000 159642 -34013 -63437 -63322 -34866 203180 415 -29554 900000 62117 900000 900000 31633 900000 900000 189854 -22635 77195 65378 295448 900000 69368 900000 -60415 900000 17440 27241 900000 224557 153866 11152 127522 -9888 31270 -15858 15146 -17940 24252 44311 -31897 81746 70491 25212 47897 84788 -1045 15464 -14013 -34257 -4133 -427 -38199 -1748 -7829 21125 13510 27084 -13717 22386 6373 17785 -6945 3813 37478 16877 -25552 -4849 -12330 13675 -2347 26696 2197 -8197 -601 -4701 -12902 -6843 8158 -240 1858 4692 -5372 9446 1284 -2479 1000 1400 -4296 -3166 5431 -8288 3453 1462 218 3464 3994 11230 5790 -6988 -1491 -9315 5770 -1884 537 -3220 1036 -2447 660 -546 2024 3228 -981 682 1201 -1820 -2052 900000 4897 900000 2156 5836 -2331 900000 13592 900000 900000 -2827 900000 900000 -15127 900000 409 4837 900000 900000 2568 900000 900000 1753 11694 -5861 -1648 900000 10154 -2557 -6603 -7689 -3830 12923 38 -3418 900000 3951 900000 900000 2378 900000 900000 12076 -3272 4910 4158 18792 900000 4412 900000 -14323 900000 2219 3308 900000 14283 9787 1548 8111 -1487 3074 -2659 2102 -3942 3786 5637 -8484 7090 7337 4665 7755 9805 -278 3219 -3484 -9112 -741 -74 -10823 -414 -2354 5497 4219 7830 -6266 7508 2616 6685 -3333 1588 10402 5367 -11968 -1907 -5917 6010 -1438 14356 1703 -7300 -473 -3452 -9102 -4353 4717 -161 1289 3418 -4815 8411 1426 -3153 1278 1772 -5564 -3918 6186 -11357 4472 2020 303 4446 4873 12402 6562 -8769 -1724 -12119 7440 -3083 975 -6665 2205 -5802 1636 -1460 5420 8678 -2762 1827 2987 -4326 -4640 SS 20210312T125317.2Z 7741.537005 49 1 50.50 2 82.52 101.21 84.13 112.80 0.00 1 0.00 1 0 25 5.407e-01 1.925e-02 3.436e-01 9.164e-03 7.197660e-01 5.098503e-03 1.153033e-02 -6.000000e+00 3.097431e-01 225.78 -2.00 3.54 -2.00 321.97 0.00e+00 2.131173e-02 2.739817e-03 1.101602e-02 -6.000000e+00 1.378165e-02 274.66 -2.00 20.00 -2.00 321.54 0.00e+00 7.129 0.007 302.00 328.00 3 7.6353e-01 1.8296e-02 8.6187e-02 -6.0000e+00 7.7188e-01 3.6853e-01 2.6340e-02 4.9887e-02 -6.0000e+00 8.3988e-01 -6.0666e-01 2.8159e-02 4.2654e-02 -6.0000e+00 4.9541e-01 2.4974e-01 1.3097e-02 2.5919e-02 -6.0000e+00 2.1099e-01 1.2485e-04 1.1212e-03 2.6964e-04 4.7772e-04 -6.0000e+00 1.4701e-02 1.0162e-03 0.0000e+00 12 8 8 10 0 0 22.44 22.86 0.44 0.00102 0.00944 84 16 1 5 0 601.080 25.68 19.99 22.86 10.21 30.4 1008.22 -206367 -183617 900000 -19575 -117610 -206293 -223437 1978 900000 900000 -145350 -74657 -115992 -153469 214904 -78281 -7590 -31123 -21821 18669 -99124 -29296 45370 900000 77071 -59036 -28852 -28784 -92649 1922 146389 -12268 27387 16202 -39890 74124 -11772 82818 941 5178 15924 -7592 5155 29989 70272 32083 7168 48157 13586 16586 1048 36285 17962 -4419 26670 10054 10577 2964 10814 12889 18456 16419 23884 19209 16997 13987 14658 8579 7336 1859 9729 2683 8238 1546 -1038 -3540 -12206 -3071 -8373 4543 -630 2044 -308 -2944 1994 -720 1794 1368 2233 1981 -900 -1381 -7462 -1317 -5275 -4698 -2036 1805 45 -1504 429 -797 -2604 -1574 -3764 -2259 -2331 -643 -63 1273 1810 833 -111 -843 -1311 -2259 -1382 -4 17 1563 1507 3686 2544 2219 825 -1287 -1865 -74 651 82 -91 -237 -1016 -1121 -490 -43 1036 1840 739 167 -536 -1282 -1332 -3854 -3429 900000 -175 -1146 -4355 -5261 18 900000 900000 -1534 -667 -1318 -3613 1919 -1525 -86 -505 -354 212 -3702 -523 405 900000 688 -1294 -468 -467 -2934 29 1307 -309 556 408 -1716 1059 -373 1257 34 210 646 -419 268 1290 2111 1485 448 2111 893 1131 92 2504 1633 -497 2512 1135 1194 326 1168 1350 1903 1920 3006 2688 2669 2280 2334 1481 1387 426 2302 717 2072 393 -248 -777 -2707 -628 -2031 1173 -205 751 -129 -1350 925 -367 943 751 1230 1070 -472 -679 -3732 -632 -2956 -3094 -1548 1548 44 -1551 414 -703 -2097 -1220 -3180 -2011 -2198 -642 -69 1565 2312 1167 -161 -1208 -1803 -3013 -1832 -6 25 2371 2289 5285 3842 3266 1191 -1842 -2602 -104 1037 141 -174 -493 -2251 -2651 -1236 -115 2805 5033 2055 454 -1378 -3109 -3090 SS 20210312T130321.5Z 7741.543998 52 1 50.93 2 80.71 102.97 82.46 114.52 0.00 1 0.00 1 0 25 4.166e-01 1.520e-02 2.448e-01 3.592e-03 6.272143e-01 1.942953e-03 1.028180e-02 -6.000000e+00 2.370745e-01 225.78 -2.00 3.54 -2.00 321.52 0.00e+00 1.253495e-02 9.480662e-04 1.105478e-02 -6.000000e+00 1.018054e-02 274.66 -2.00 20.00 -2.00 321.04 0.00e+00 5.891 0.004 302.00 328.00 3 6.8567e-01 6.6375e-03 7.8841e-02 -6.0000e+00 5.8806e-01 3.2140e-02 9.4645e-03 6.1981e-02 -6.0000e+00 6.3912e-01 -1.3098e-01 1.0356e-02 4.5754e-02 -6.0000e+00 3.7961e-01 4.7829e-02 4.8976e-03 2.0849e-02 -6.0000e+00 1.6156e-01 4.8716e-04 1.1754e-03 1.0631e-04 3.7130e-04 -6.0000e+00 1.1209e-02 1.4354e-03 0.0000e+00 12 8 8 10 0 0 52.84 22.86 0.36 0.00144 0.01027 181 34 1 5 0 278.240 25.68 20.00 22.86 10.61 30.5 1008.81 -67212 -182931 -6689 -29260 -156945 -17975 -198699 -35430 -173493 89054 -153282 -146404 -57400 -132359 8193 -87196 -15686 -6209 -6597 26561 -41963 14883 -79275 16121 -37245 -33522 -9879 -18618 -2288 -54626 33269 -18964 2910 17315 -21483 -248 -17065 9302 3786 6883 1275 -5388 8909 -3614 18371 -30 2781 9886 1500 11165 2890 15705 7222 7407 6697 572 6663 -5026 -214 276 2323 5530 5273 11149 2946 5526 2902 -23 3420 697 5983 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