File name: Pandora167s1_KenoshaWI_20210419_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T191756.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20210419_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20210419 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210419T145811.9Z 7779.623749 209 1 1.79 2 48.57 116.84 99.09 44.79 0.00 1 0.00 1 0 25 2.224e-02 1.625e-02 9.791e-03 4.833e-03 2.413437e-01 2.471291e-03 2.894889e-03 -6.000000e+00 1.281175e-02 228.66 -2.00 3.54 -2.00 316.17 0.00e+00 1.397876e-03 2.670951e-04 3.101853e-04 -6.000000e+00 5.541774e-04 278.74 -2.00 20.00 -2.00 315.56 0.00e+00 1.508 0.000 302.00 328.00 3 2.3057e+00 6.4151e-03 1.9306e-02 -6.0000e+00 3.1951e-02 -1.8616e-02 7.1501e-03 1.2188e-02 -6.0000e+00 3.4637e-02 1.0485e-02 4.1564e-03 5.9685e-03 -6.0000e+00 2.0561e-02 -1.4853e-02 1.9525e-03 1.7925e-03 -6.0000e+00 8.7937e-03 8.9994e-03 6.8268e-04 1.3640e-04 1.8540e-05 -6.0000e+00 6.0374e-04 -4.8416e-03 0.0000e+00 12 9 9 12 1 1 999.00 23.03 0.27 -0.00484 0.00029 2 18 2 5 0 536.110 25.79 19.99 23.03 14.82 31.5 991.75 900000 -1432 7168 -2423 -232 -4122 -2081 3368 -2318 -3106 -7218 -5290 -2585 -403 1744 -491 1723 462 1056 2644 2560 2120 1147 2611 1165 830 -1120 -48 -1930 -733 -319 -1365 1406 -2198 -6719 -6125 -6280 -3476 -757 -1038 -2422 1051 344 1508 3401 1576 1034 40 -911 -730 -296 347 1164 1848 819 2177 1109 898 -259 -541 887 1805 3245 3727 2730 416 -453 -2428 -434 747 798 1570 1292 1774 922 -1090 -3033 -4424 -4998 -3290 -3068 -2427 -2800 -2651 -1259 -133 1265 1202 2281 2303 1329 124 -1766 -2797 -1754 -1841 203 1761 1341 -27 -352 -2565 -2137 -1387 -1944 -1205 -567 -572 347 1745 2034 2056 1641 582 -186 -927 222 -564 582 993 981 1844 1493 439 709 -452 -2321 -632 156 -949 -814 -1071 -881 -123 -175 336 355 1794 1036 155 -148 -446 -2144 900000 -283 1377 -494 -43 -728 -365 610 -487 -697 -1684 -1211 -619 -106 504 -158 572 159 374 952 944 785 428 991 465 343 -475 -20 -763 -279 -123 -564 603 -1008 -3108 -2708 -2865 -1705 -412 -633 -1607 709 238 1051 2343 1101 720 28 -623 -495 -205 250 867 1415 647 1726 896 729 -210 -436 716 1503 2819 3376 2531 378 -392 -2056 -369 676 770 1564 1300 1757 888 -1005 -2647 -3719 -4229 -2925 -2934 -2457 -2974 -2894 -1412 -155 1510 1471 2796 2791 1563 139 -1901 -2918 -1847 -2040 236 2158 1722 -35 -446 -3150 -2513 -1625 -2389 -1533 -738 -763 472 2438 2930 3009 2376 820 -252 -1205 282 -733 780 1383 1399 2616 2097 609 955 -597 -3003 -801 203 -1291 -1140 -1532 -1270 -180 -264 521 561 2847 1665 249 -234 -693 -3306 SS 20210419T150740.3Z 7779.630328 212 1 0.61 2 47.02 119.19 97.90 46.49 0.00 1 0.00 1 0 25 2.144e-02 1.562e-02 1.046e-02 5.880e-03 2.367491e-01 3.014338e-03 2.863420e-03 -6.000000e+00 1.235006e-02 228.66 -2.00 3.54 -2.00 315.78 0.00e+00 1.290917e-03 2.996494e-04 2.683413e-04 -6.000000e+00 5.341790e-04 278.74 -2.00 20.00 -2.00 315.19 0.00e+00 1.465 0.000 302.00 328.00 3 2.3697e+00 7.7902e-03 1.8848e-02 -6.0000e+00 3.0800e-02 -1.0864e-02 8.6691e-03 1.1993e-02 -6.0000e+00 3.3388e-02 4.7986e-03 5.0037e-03 5.8558e-03 -6.0000e+00 1.9820e-02 -1.1622e-02 2.3058e-03 1.7178e-03 -6.0000e+00 8.4772e-03 8.8574e-03 5.5207e-04 1.6489e-04 1.9202e-05 -6.0000e+00 5.8195e-04 -5.1914e-03 0.0000e+00 12 9 9 12 1 1 999.00 23.05 0.30 -0.00519 -0.00104 1 44 1 5 0 213.260 25.79 20.00 23.05 15.68 31.2 989.85 900000 -154 6690 217 -5309 -726 -5808 -1331 -3893 -1178 -2637 -6759 -2198 -5361 1928 -746 1722 1330 122 3650 3145 2611 2166 464 1028 1098 989 1744 -1097 140 475 2216 1605 -1744 -4226 -3591 -7669 -3609 -946 -658 -909 579 744 -4 825 1408 253 -953 -852 -543 850 -698 -119 1634 56 1096 1002 666 766 -704 1138 2390 3007 4417 1705 32 -428 -1819 615 918 1368 1124 478 1595 260 -73 -2462 -4120 -4589 -3043 -2775 -2376 -3213 -2203 -833 650 315 2382 2128 1241 1324 402 -2228 -1630 -2418 -2125 -215 2070 1041 385 -370 -1861 -2101 -948 -1726 -2576 -601 -705 312 1436 2463 1990 1727 294 -810 -812 -54 352 804 1446 1425 1040 1083 466 1424 -651 -1623 142 -331 -1511 43 -1451 -934 -873 112 412 697 1263 355 438 -367 -1031 -930 900000 -36 1562 52 -1231 -152 -1271 -303 -990 -310 -704 -1852 -618 -1704 642 -274 650 516 49 1468 1297 1080 900 200 457 502 458 783 -479 59 202 983 754 -869 -2093 -1704 -3838 -1913 -551 -425 -630 412 539 -3 605 1031 185 -693 -609 -385 610 -525 -92 1296 45 902 834 558 635 -585 944 2035 2676 4065 1619 30 -378 -1570 531 844 1333 1135 488 1600 255 -68 -2182 -3529 -3947 -2742 -2676 -2422 -3436 -2406 -933 753 377 2888 2603 1509 1556 451 -2412 -1696 -2562 -2356 -250 2516 1327 497 -466 -2263 -2459 -1103 -2104 -3275 -776 -931 420 1984 3490 2869 2462 409 -1082 -1043 -68 450 1061 1979 1996 1460 1502 636 1886 -849 -2066 177 -424 -2028 59 -2042 -1321 -1254 165 624 1073 1964 558 686 -568 -1569 -1394 SS 20210419T151241.4Z 7779.633813 216 1 50.83 2 46.22 120.47 97.25 47.38 0.00 1 0.00 1 0 25 2.556e-02 1.494e-02 1.320e-02 3.923e-03 2.431103e-01 1.985512e-03 3.032209e-03 -6.000000e+00 1.471944e-02 228.66 -2.00 3.54 -2.00 317.65 0.00e+00 1.127331e-03 3.033383e-04 8.133903e-04 -6.000000e+00 6.367055e-04 278.74 -2.00 20.00 -2.00 316.97 0.00e+00 1.443 0.000 302.00 328.00 3 5.4088e+00 5.2658e-03 1.9058e-02 -6.0000e+00 3.6709e-02 2.7999e-02 5.9243e-03 1.2603e-02 -6.0000e+00 3.9795e-02 9.0922e-03 3.6389e-03 6.2257e-03 -6.0000e+00 2.3623e-02 -1.8867e-02 1.8210e-03 1.7838e-03 -6.0000e+00 1.0103e-02 4.2045e-04 5.1300e-04 1.1445e-04 1.7774e-05 -6.0000e+00 6.9364e-04 -4.7467e-03 0.0000e+00 12 8 8 10 0 0 99.97 23.02 0.79 -0.00475 -0.00089 69 13 1 5 0 727.580 25.79 20.00 23.02 15.82 31.2 989.63 900000 4953 3210 -6687 1904 -5987 2687 -2454 -5339 734 -5702 -5180 -9035 1009 -1418 148 1952 -1582 6625 -500 5501 1373 2285 4682 -2810 3111 -2369 729 -2164 -2382 -2486 -2822 2387 -2024 -4382 -7394 -4985 -4419 -2568 562 -1998 805 -722 552 1134 1694 2115 -456 -615 -1910 -509 880 202 2553 435 1644 807 610 -624 -517 896 828 4649 3398 2655 -60 -976 -2046 -566 1025 291 2554 1790 1429 1838 -1771 -2020 -5585 -4274 -3712 -2865 -1286 -3447 -1661 -856 151 1229 1277 2039 1133 1437 -695 -1776 -2429 -2046 -1107 -636 1326 974 336 -883 -2047 -1987 -2098 -1272 -2601 -283 -734 405 1928 2043 2244 1219 673 -606 -951 -773 -1236 851 779 1304 1015 1610 1182 238 -186 -1960 -649 -1134 -1254 -677 -1513 -421 -823 405 189 467 1248 703 821 -279 -641 -1279 900000 504 348 -779 186 -578 242 -253 -636 89 -736 -662 -1292 150 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