File name: Pandora167s1_KenoshaWI_20210610_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T194259.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20210610_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20210610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210610T111302.8Z 7831.467393 76 1 51.30 2 81.18 66.73 81.56 66.04 0.00 1 0.00 1 0 33 4.441e-01 2.500e-02 4.069e-01 1.653e-02 6.776981e-01 9.470628e-03 1.121410e-02 -6.000000e+00 2.644005e-01 232.54 -2.00 3.54 -2.00 321.87 0.00e+00 8.480173e-03 5.175284e-03 1.774681e-02 -6.000000e+00 1.249206e-02 284.34 -2.00 20.00 -2.00 321.34 0.00e+00 6.165 0.004 302.00 328.00 3 2.6313e+00 3.6108e-02 1.1448e-01 -6.0000e+00 6.6426e-01 3.0317e-01 4.9083e-02 1.2214e-01 -6.0000e+00 7.1859e-01 -5.8995e-01 4.5362e-02 5.1431e-02 -6.0000e+00 4.2254e-01 2.4509e-01 2.1097e-02 8.2157e-03 -6.0000e+00 1.7929e-01 5.0041e-05 1.4433e-03 5.0511e-04 3.2691e-04 -6.0000e+00 1.2542e-02 -7.8127e-03 0.0000e+00 12 8 8 10 0 0 92.91 23.07 0.65 -0.00781 0.00303 27 5 1 5 0 1899.580 25.79 20.00 23.07 25.77 35.1 995.80 900000 -31456 -76973 170393 900000 -154612 900000 900000 -94742 -110916 900000 63732 -70191 -74442 -85009 -35145 -68774 -7232 17559 42636 121652 -75331 -20636 -60567 -71498 900000 -102786 97823 -1302 -21761 -65875 -31077 102000 -53761 186813 -62871 27737 -721 -47361 8776 30369 47919 -21377 37348 46201 -2311 104466 793 -3622 18510 58302 16130 29498 67577 -8448 37218 24478 16185 -7299 18484 25005 207 16616 15577 2190 12778 29323 5579 -5115 22688 -766 11288 9199 11301 9202 -5076 -980 -12300 17269 -6771 -9281 3613 -5676 -2583 -933 3664 -1146 3676 7281 415 1453 -496 -2869 -10095 -6122 -2025 -3446 -491 -287 1005 -2797 -2859 -5360 -4333 -678 -4224 -1624 73 1113 4038 186 4368 -1084 -671 -1000 -1568 214 -2103 1418 625 1974 3132 2771 2265 1680 -1804 -4022 956 -39 -627 -411 -2353 75 -612 93 588 363 1248 685 828 -530 -719 -1823 900000 -507 -1239 2744 900000 -2905 900000 900000 -1526 -1786 900000 1026 -1130 -1340 -2053 -666 -1969 -130 283 687 1959 -2830 -469 -2005 -2750 900000 -5609 1575 -26 -557 -2888 -1236 1642 -3270 3008 -3881 762 -30 -3559 447 1496 2133 -1893 2016 2319 -182 3067 64 -317 1374 3369 1501 2639 4473 -1270 3662 2803 2013 -1117 2133 2751 32 2453 2648 462 2423 4591 1123 -1171 4770 -217 3004 2510 3043 2329 -1331 -226 -3147 3599 -2020 -3374 1335 -2569 -1213 -460 1847 -643 2047 3955 236 772 -251 -1415 -5398 -3476 -1285 -2599 -417 -273 976 -2702 -2513 -4365 -3412 -550 -3809 -1509 72 1180 4682 251 6145 -1648 -995 -1420 -2140 286 -3009 2087 981 3081 4692 4014 3202 2305 -2480 -5454 1257 -58 -1072 -780 -4911 162 -1408 229 1529 976 3388 1884 2216 -1357 -1732 -4244 SS 20210610T113047.4Z 7831.479715 84 1 48.91 2 78.15 69.50 78.61 68.69 0.00 1 0.00 1 0 25 4.318e-01 1.972e-02 3.107e-01 1.051e-02 5.489490e-01 5.762753e-03 8.624970e-03 -6.000000e+00 2.528439e-01 232.54 -2.00 3.54 -2.00 321.14 0.00e+00 7.648658e-03 2.632777e-03 9.564736e-03 -6.000000e+00 1.150971e-02 284.34 -2.00 20.00 -2.00 320.54 0.00e+00 4.716 0.002 302.00 328.00 3 3.6575e+00 1.9435e-02 6.9894e-02 -6.0000e+00 6.3673e-01 3.4682e-02 2.5389e-02 6.3056e-02 -6.0000e+00 6.8810e-01 -1.5286e-01 2.3651e-02 2.9170e-02 -6.0000e+00 4.0761e-01 6.1973e-02 1.1439e-02 6.5377e-03 -6.0000e+00 1.7580e-01 7.8024e-05 4.4753e-04 3.1823e-04 1.8954e-04 -6.0000e+00 1.1836e-02 -6.9803e-03 0.0000e+00 12 8 8 10 0 0 99.56 23.07 0.42 -0.00698 -0.00362 15 3 1 5 0 3259.970 25.79 19.99 23.07 26.98 35.1 996.32 900000 900000 -120499 900000 64312 149189 -74158 -197711 -126069 900000 -28527 -125498 193152 -13825 -98355 152625 -28514 -24473 113729 -11566 -52571 -75882 49060 33901 9629 20205 91577 117932 -62553 -2913 2156 16912 -7971 -11044 8242 -18689 10202 20512 1601 8992 12364 -3960 7840 1218 16306 2384 4347 2677 31928 9058 11659 13728 6032 7063 5006 6506 -1087 -44 -1365 4649 2355 8483 3705 3989 439 8512 5074 -6690 -3901 7190 2058 6169 3794 3913 480 -1523 -114 -2374 -2112 -6470 -5633 -1517 -3832 -2338 -1924 2315 2560 1089 1879 2403 1007 -2551 -663 -6878 -4977 -2965 -857 1560 177 306 -982 -1824 -3026 -2965 278 -3067 -2248 -855 1448 1668 3274 1660 1472 576 -1074 -2560 -762 -1184 458 287 2037 900 3269 1814 801 48 -2970 -452 -2015 84 -188 -1687 -1211 -273 316 -84 832 1634 1137 -144 -545 -818 -987 900000 900000 -2129 900000 659 1528 -759 -6980 -2524 900000 -292 -2917 1978 -171 -3373 1563 -700 -637 1165 -308 -2138 -3851 777 645 243 482 1149 1208 -3245 -89 71 577 -396 -624 386 -1082 471 980 109 680 1029 -416 780 135 1600 275 503 323 3000 1103 1498 1915 993 1241 951 1262 -233 -9 -291 925 490 1798 924 1115 137 2429 1439 -2115 -1276 2408 813 2498 1590 1586 188 -553 -37 -772 -729 -2697 -2726 -803 -2294 -1470 -1281 1588 1854 835 1452 1817 730 -1781 -429 -4640 -3549 -2352 -766 1553 197 352 -1095 -1888 -2895 -2778 270 -3284 -2515 -999 1777 2245 4769 2611 2342 898 -1610 -3705 -1071 -1735 700 464 3316 1451 5005 2735 1176 68 -4195 -626 -3079 140 -342 -3311 -2462 -576 705 -198 2016 4005 2828 -356 -1295 -1857 -2165 SS 20210610T113621.5Z 7831.483582 87 1 19.32 2 77.18 70.36 77.68 69.51 0.00 1 0.00 1 0 25 2.761e-01 1.892e-02 2.505e-01 9.182e-03 5.213895e-01 4.979305e-03 7.512425e-03 -6.000000e+00 1.629528e-01 232.54 -2.00 3.54 -2.00 320.72 0.00e+00 1.354435e-03 2.013955e-03 7.193892e-03 -6.000000e+00 7.273042e-03 284.34 -2.00 20.00 -2.00 320.09 0.00e+00 4.387 0.002 302.00 328.00 3 3.5147e+00 1.5846e-02 6.1595e-02 -6.0000e+00 4.1084e-01 -6.2069e-02 2.0211e-02 5.3299e-02 -6.0000e+00 4.4429e-01 -1.5545e-02 1.8800e-02 1.9828e-02 -6.0000e+00 2.6178e-01 2.1630e-04 9.3263e-03 4.3211e-03 -6.0000e+00 1.1170e-01 1.2958e-04 3.2815e-04 2.7430e-04 9.7391e-05 -6.0000e+00 7.6709e-03 -7.6698e-03 0.0000e+00 12 9 9 12 1 1 84.50 23.07 0.45 -0.00767 -0.00520 7 4 1 5 0 2392.200 25.79 20.01 23.07 27.45 35.3 996.27 900000 -127092 900000 -159115 134315 -1795 17605 900000 -135844 900000 -23660 -29628 -233 -11606 900000 -17147 36565 -18950 -26161 -13895 -8592 5065 -68443 36853 -6398 60174 -21295 5728 58319 12284 3745 -27913 18752 6658 -8548 -1932 -19608 -8714 -5955 2518 608 2544 4205 20099 9852 2804 7697 6375 10682 5883 -1000 5290 -8060 8432 1836 5757 242 -2816 -3215 -1924 3112 -5964 5519 6272 6537 3602 -3575 -2362 -1231 1589 2677 2725 5284 251 3485 -2997 -1517 -4904 -3935 -1873 -4806 -1873 -784 -3609 -1270 677 1522 9 4441 1616 435 1322 -2904 -3694 -4246 -2236 -1890 3367 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