File name: Pandora167s1_KenoshaWI_20210701_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T195210.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20210701_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20210701 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210701T110707.5Z 7852.463281 193 1 50.04 2 82.90 65.07 46.07 168.96 0.00 1 0.00 1 0 33 9.871e-01 6.005e-02 4.900e-01 3.703e-02 7.968836e-01 2.269684e-02 1.151747e-02 -6.000000e+00 6.054434e-01 232.90 -2.00 3.54 -2.00 322.18 0.00e+00 1.302286e-02 1.218710e-02 1.594114e-02 -6.000000e+00 3.306678e-02 286.34 -2.00 20.00 -2.00 321.69 0.00e+00 7.436 0.008 302.00 328.00 3 2.1284e+00 8.8484e-02 1.1351e-01 -6.0000e+00 1.5398e+00 1.1237e+00 1.0718e-01 9.2651e-02 -6.0000e+00 1.6763e+00 -1.5403e+00 7.2801e-02 3.4256e-02 -6.0000e+00 9.6963e-01 6.0279e-01 3.6829e-02 7.1702e-03 -6.0000e+00 4.1132e-01 1.8259e-05 -2.4971e-03 1.1280e-03 4.0460e-04 -6.0000e+00 2.9282e-02 -8.5628e-03 0.0000e+00 12 8 8 10 0 0 51.19 23.11 1.08 -0.00856 -0.02733 17 3 1 5 0 2943.000 25.79 19.98 23.11 25.24 34.7 995.77 900000 -39737 18090 -79709 900000 900000 -83081 900000 900000 900000 900000 900000 113414 900000 900000 -42469 12906 900000 78505 68198 60128 900000 238745 900000 900000 2124 -4355 -43895 -52491 -133659 49680 -27734 75209 663490 89569 900000 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6145 6615 4331 8382 7800 3745 8611 -985 -2176 4864 4144 -5336 -5802 3667 -4626 4871 2773 2537 2552 -5518 6654 5044 8376 2042 -3122 5560 -4868 3439 -611 385 -357 3291 -3630 -17533 2849 -3159 3211 -7087 -3674 -5913 -5987 -5704 -5048 6930 2512 2597 3960 -6054 -5434 -11235 -6115 3772 3981 4266 4053 10548 8319 3464 6395 914 4604 -2203 4138 -6833 -3071 -1636 -5238 3868 1562 2591 1380 4329 524 5695 661 -5036 -11464 SS 20210701T111849.8Z 7852.471410 196 1 50.57 2 80.94 66.92 45.69 172.93 0.00 1 0.00 1 0 25 4.856e-01 1.877e-02 3.164e-01 8.746e-03 6.954660e-01 5.048870e-03 1.140754e-02 -6.000000e+00 2.890240e-01 232.90 -2.00 3.54 -2.00 321.86 0.00e+00 5.078733e-03 2.931431e-03 1.920532e-02 -6.000000e+00 1.390813e-02 286.34 -2.00 20.00 -2.00 321.33 0.00e+00 6.014 0.004 302.00 328.00 3 1.9302e+00 1.9947e-02 1.2415e-01 -6.0000e+00 7.3085e-01 1.0174e-01 2.8974e-02 1.4074e-01 -6.0000e+00 7.9120e-01 -3.4228e-01 2.8797e-02 5.2925e-02 -6.0000e+00 4.6873e-01 1.3950e-01 1.3059e-02 6.5351e-03 -6.0000e+00 2.0136e-01 1.1940e-04 1.2282e-03 2.6376e-04 2.8290e-04 -6.0000e+00 1.3799e-02 -9.4793e-03 0.0000e+00 12 8 8 10 0 0 71.56 23.11 0.57 -0.00948 -0.00025 56 11 1 5 0 902.980 25.79 20.00 23.11 25.33 34.4 995.54 900000 -241334 900000 900000 900000 -148205 -93971 -248481 900000 47735 900000 -102234 -203280 7543 -118688 -47813 900000 900000 -45852 -69792 -14501 -74827 -103613 19008 -40205 70314 -71657 -25726 -90775 -66834 91844 -16513 -23774 -1769 46785 -11826 -4075 66302 -9414 32170 16991 50640 21995 21229 40569 5421 62633 6903 36743 -9909 16299 28450 12123 16646 7890 19965 13611 2648 1926 3777 14450 -3139 14426 8520 7165 12303 2337 12449 3793 9758 1282 2642 4452 4282 179 -1856 1039 -2289 -9604 -5930 -2800 3047 -2317 -291 -1598 -1282 2654 1646 6108 2058 -369 -2838 -5233 -3136 -5429 -523 -2250 999 1232 -856 -1306 -4347 -2328 -1675 -2793 -3578 -899 -1088 137 2237 1938 1371 931 -462 -1913 -1562 -719 -133 1085 932 2273 2257 2804 2460 705 -62 -2910 -1121 -92 -296 -955 -1345 -1246 -879 215 8 669 1920 619 454 -508 -975 -1033 900000 -4302 900000 900000 900000 -1262 -800 -5282 900000 407 900000 -871 -4758 64 -2051 -514 900000 900000 -686 -1399 -177 -1635 -3023 182 -735 599 -1928 -441 -2843 -1748 782 -379 -689 -46 770 -328 -111 1059 -375 1039 726 1715 1035 1048 1699 324 2247 434 1829 -814 1153 2015 1109 1589 876 2071 1553 339 243 459 1614 -447 1972 1402 1304 2145 440 2170 777 2169 348 753 1259 1168 47 -451 227 -512 -2512 -1765 -959 1137 -1017 -135 -796 -683 1441 941 3391 1166 -203 -1498 -2711 -1605 -3134 -333 -1697 843 1158 -851 -1253 -3938 -1877 -1308 -2352 -3247 -840 -1087 148 2643 2571 1977 1381 -685 -2752 -2152 -978 -188 1605 1452 3537 3410 4072 3490 986 -85 -3950 -1524 -137 -504 -1807 -2750 -2682 -1997 517 20 1750 5061 1665 1196 -1284 -2338 -2382 SS 20210701T113032.0Z 7852.479537 201 1 50.42 2 78.94 68.75 45.46 176.94 0.00 1 0.00 1 0 25 4.053e-01 1.456e-02 1.498e-01 3.562e-03 6.058837e-01 1.973990e-03 9.974329e-03 -6.000000e+00 2.373557e-01 232.90 -2.00 3.54 -2.00 321.39 0.00e+00 5.499311e-03 9.940605e-04 1.285904e-02 -6.000000e+00 1.042631e-02 286.34 -2.00 20.00 -2.00 320.79 0.00e+00 5.024 0.002 302.00 328.00 3 1.5933e+00 6.9804e-03 8.6542e-02 -6.0000e+00 5.9657e-01 -6.5780e-02 9.7129e-03 9.0084e-02 -6.0000e+00 6.4365e-01 -5.8383e-02 9.6299e-03 3.5861e-02 -6.0000e+00 3.8246e-01 1.9339e-02 4.5347e-03 5.4443e-03 -6.0000e+00 1.6335e-01 4.5299e-04 1.2275e-03 1.0567e-04 1.7133e-04 -6.0000e+00 1.1014e-02 -9.1327e-03 0.0000e+00 12 8 8 10 0 0 36.19 23.12 0.32 -0.00913 0.00009 126 24 1 5 0 400.110 25.79 20.00 23.12 25.30 34.6 995.66 900000 -105267 -156462 -95971 -143054 -82706 -151697 -133327 -124037 -150070 -136997 -160896 -80209 -94070 -28003 -2956 -34237 -13052 -44355 -30029 -23117 -14255 688 -38757 -23367 -10653 3549 -10468 -8813 -24844 -24850 -4336 -6637 9670 -5333 -14637 -8681 -8519 -3272 -1892 -706 1123 5986 12265 3591 3378 -3061 2728 1499 7533 6975 3931 6375 1994 8601 3095 5913 2165 -914 -926 -1003 9423 10908 6527 6497 1866 257 -2208 3751 2285 3326 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