File name: Pandora167s1_KenoshaWI_20210722_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T200339.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20210722_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20210722 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210722T130915.9Z 7873.548101 211 1 14.88 2 63.56 86.20 136.80 276.14 0.00 1 0.00 1 0 25 3.282e-02 1.517e-02 1.666e-02 3.924e-03 2.887114e-01 2.019903e-03 3.568140e-03 -6.000000e+00 1.920211e-02 232.70 -2.00 3.54 -2.00 317.89 0.00e+00 7.462971e-04 3.403264e-04 1.030241e-03 -6.000000e+00 8.497359e-04 287.82 -2.00 20.00 -2.00 317.05 0.00e+00 2.233 0.000 302.00 328.00 3 4.3999e+00 5.4402e-03 2.6883e-02 -6.0000e+00 4.8213e-02 -2.6982e-02 6.1334e-03 1.5762e-02 -6.0000e+00 5.2019e-02 1.5465e-02 3.8344e-03 7.4019e-03 -6.0000e+00 3.0943e-02 -1.8317e-02 1.9491e-03 1.9936e-03 -6.0000e+00 1.3234e-02 5.2059e-04 2.7316e-04 1.1338e-04 1.9954e-05 -6.0000e+00 8.9217e-04 -5.9156e-03 0.0000e+00 12 9 9 12 1 1 78.61 23.02 0.30 -0.00592 -0.00386 6 5 1 5 0 2099.490 25.79 20.00 23.02 29.82 35.4 1002.28 900000 -4968 10692 -5788 1612 -3686 -11678 11621 -8708 3311 -11814 -7503 -4589 -8007 5007 412 4273 -238 667 1463 -280 3918 -1829 2849 671 3486 -2703 -4403 2915 -6965 105 -2499 3669 -1365 -7277 -2516 -8597 -1554 -2606 -1868 -1055 -849 1304 -460 3763 914 2058 -403 -1726 -709 7 1165 1460 2580 249 1269 2026 536 779 -766 832 1070 2608 4282 1469 -80 -1317 -2460 -90 1255 1937 1979 2228 1802 824 -1052 -2901 -4348 -4728 -3591 -2834 -2347 -2949 -1793 -817 101 1605 1099 2779 1550 1194 115 -2559 -2236 -2811 -1559 -484 893 1393 -155 -139 -1892 -2285 -1923 -1128 -1722 -1107 -269 493 2347 2212 1647 1425 854 -423 -1541 -310 -945 211 892 1012 1574 1304 1221 559 -263 -1723 -630 -632 -1252 -699 -1205 -803 -522 -66 513 501 1370 894 573 153 -1536 -953 900000 -396 779 -487 116 -258 -897 791 -812 298 -1248 -766 -498 -1033 659 64 684 -42 121 274 -55 748 -371 577 147 783 -656 -1054 616 -1557 23 -603 911 -377 -2072 -654 -2456 -470 -937 -777 -484 -411 641 -235 1856 464 1030 -203 -867 -352 4 628 833 1529 156 805 1304 352 505 -497 540 727 1879 3246 1171 -62 -969 -1762 -65 981 1642 1762 2005 1600 706 -853 -2193 -3146 -3459 -2823 -2448 -2193 -2945 -1845 -873 113 1856 1318 3327 1848 1367 125 -2653 -2214 -2862 -1681 -561 1107 1826 -207 -180 -2350 -2698 -2260 -1392 -2240 -1483 -369 697 3427 3378 2584 2214 1285 -608 -2126 -416 -1304 302 1332 1553 2401 1963 1800 803 -369 -2348 -842 -875 -1839 -1066 -1894 -1276 -846 -111 891 891 2460 1626 1038 272 -2692 -1632 SS 20210722T131429.1Z 7873.551726 214 1 50.42 2 62.60 87.05 137.70 277.10 0.00 1 0.00 1 0 25 2.278e-02 1.369e-02 3.602e-03 8.011e-04 2.788134e-01 4.140406e-04 3.482869e-03 -6.000000e+00 1.333147e-02 232.70 -2.00 3.54 -2.00 318.05 0.00e+00 1.724992e-03 7.240748e-05 1.114674e-03 -6.000000e+00 5.897803e-04 287.82 -2.00 20.00 -2.00 317.21 0.00e+00 2.161 0.000 302.00 328.00 3 2.5059e+00 1.1205e-03 2.6030e-02 -6.0000e+00 3.3473e-02 -2.8661e-02 1.2642e-03 1.5163e-02 -6.0000e+00 3.6112e-02 1.2470e-02 7.9839e-04 7.3649e-03 -6.0000e+00 2.1481e-02 -1.7760e-02 4.0808e-04 2.0486e-03 -6.0000e+00 9.1902e-03 3.7580e-03 6.3876e-04 2.3395e-05 1.9810e-05 -6.0000e+00 6.1917e-04 -8.0420e-03 0.0000e+00 12 9 8 11 8 0 95.01 23.02 0.28 -0.00804 -0.00324 172 32 1 5 0 293.100 25.79 20.00 23.02 30.12 36.0 1004.35 900000 983 -126 -529 -5377 -5870 -5435 -4003 -4204 -4318 -7500 -6911 -5765 -2426 -677 -2 212 1924 664 1676 1916 237 2335 1580 896 -307 87 -1707 -2506 -2638 -1711 -344 640 -1843 -5597 -6139 -6253 -4550 -1689 -1042 -558 26 381 653 1199 1429 466 265 -858 -1026 526 925 1061 1736 1301 1469 1197 348 -202 -210 505 1764 2902 3705 2233 31 -425 -1844 59 1221 1096 2185 1495 1780 357 -1093 -2609 -4724 -3850 -3515 -3075 -2334 -2953 -2329 -915 62 839 1486 2145 1918 1060 -211 -1880 -2183 -1886 -1699 -302 1288 966 104 -833 -2050 -2251 -1462 -1465 -1814 -714 -730 421 1646 2101 1950 1414 674 -500 -825 -780 -501 550 835 984 1031 1485 901 784 -260 -1864 -478 -596 -822 -820 -1299 -889 -529 93 242 498 1325 901 276 37 -906 -1108 900000 70 -10 -40 -386 -389 -363 -291 -345 -384 -697 -639 -577 -273 -87 0 33 308 113 294 348 44 424 302 182 -66 19 -369 -511 -520 -347 -75 152 -478 -1465 -1527 -1622 -1327 -574 -418 -251 12 188 328 603 720 236 132 -424 -506 265 500 561 964 757 873 729 215 -124 -127 309 1131 2009 2755 1743 23 -297 -1248 40 925 931 1952 1368 1585 304 -861 -1872 -3216 -2619 -2646 -2619 -2201 -2808 -2315 -952 69 983 1806 2627 2309 1209 -223 -1842 -2190 -1941 -1768 -346 1619 1230 135 -1044 -2580 -2633 -1694 -1829 -2441 -924 -991 593 2443 3307 3179 2277 1031 -713 -1096 -1086 -667 772 1259 1541 1612 2258 1332 1104 -353 -2627 -651 -857 -1189 -1263 -2087 -1451 -889 154 423 898 2430 1687 513 66 -1586 -1883 SS 20210722T132004.0Z 7873.555602 217 1 23.42 2 61.57 87.97 138.66 278.14 0.00 1 0.00 1 0 17 2.135e-02 1.423e-02 3.204e-03 9.415e-04 2.705605e-01 4.850680e-04 3.343248e-03 -6.000000e+00 1.249090e-02 232.70 -2.00 3.54 -2.00 317.50 0.00e+00 1.483088e-03 7.384357e-05 8.628584e-04 -6.000000e+00 5.525907e-04 287.82 -2.00 20.00 -2.00 316.68 0.00e+00 2.090 0.000 302.00 328.00 3 2.4121e+00 1.2954e-03 2.5055e-02 -6.0000e+00 3.1363e-02 -2.8989e-02 1.4534e-03 1.4303e-02 -6.0000e+00 3.3835e-02 1.2027e-02 8.7978e-04 6.8811e-03 -6.0000e+00 2.0127e-02 -1.6722e-02 4.3787e-04 1.8879e-03 -6.0000e+00 8.6108e-03 4.4751e-03 5.8678e-04 2.7082e-05 1.9128e-05 -6.0000e+00 5.8012e-04 -8.0857e-03 0.0000e+00 12 9 9 12 1 1 99.37 23.02 0.29 -0.00809 -0.00368 81 33 1 5 0 283.280 25.79 20.00 23.02 30.89 36.4 1005.93 900000 1124 1334 -809 -5805 -2482 -4625 -3696 -2302 -3170 -5698 -6130 -2773 -2969 78 225 -425 1711 926 2604 1543 887 1772 1346 1559 309 526 -1886 -1935 -2861 -1514 -259 66 -1562 -6116 -6502 -6522 -4879 -1703 -936 -238 44 668 651 1078 1696 566 697 -682 -685 441 902 1283 1281 1546 1407 1283 428 -66 -110 407 2227 2991 3944 2066 -189 -230 -2098 308 1072 1131 2108 1368 2010 434 -789 -2699 -4586 -4126 -3764 -3043 -2496 -2803 -2382 -917 19 837 1411 2161 1879 1063 -52 -1712 -2309 -1911 -1853 -220 1271 1069 104 -681 -1954 -2304 -1387 -1464 -1844 -622 -614 470 1597 2025 1983 1474 685 -413 -662 -771 -312 784 1055 1076 1079 1590 988 761 -359 -1687 -564 -685 -768 -972 -1220 -955 -498 156 298 451 1413 949 179 -62 -1000 -1032 900000 110 139 -85 -576 -218 -420 -367 -254 -382 -713 -770 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