File name: Pandora167s1_KenoshaWI_20210807_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T201046.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20210807_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20210807 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210807T115826.2Z 7889.498914 99 1 50.13 2 78.84 78.08 66.30 79.73 0.00 1 0.00 1 0 33 4.688e-01 2.106e-02 3.619e-01 1.300e-02 6.000299e-01 7.307566e-03 8.119431e-03 -6.000000e+00 2.753576e-01 232.11 -2.00 3.54 -2.00 321.30 0.00e+00 -2.231705e-03 3.605603e-03 9.625909e-03 -6.000000e+00 1.380019e-02 288.15 -2.00 20.00 -2.00 320.67 0.00e+00 4.982 0.002 302.00 328.00 3 3.6572e+00 2.6008e-02 7.9008e-02 -6.0000e+00 6.8956e-01 6.7229e-04 3.5584e-02 7.9232e-02 -6.0000e+00 7.4470e-01 -7.5424e-02 3.3816e-02 2.4623e-02 -6.0000e+00 4.4284e-01 2.3519e-02 1.5991e-02 8.2256e-03 -6.0000e+00 1.9419e-01 5.8666e-05 1.4922e-03 3.9630e-04 8.5871e-05 -6.0000e+00 1.3336e-02 -7.2079e-03 0.0000e+00 12 8 8 10 0 0 46.21 23.17 1.06 -0.00721 0.00400 15 3 1 5 0 3341.140 25.90 20.00 23.17 27.87 35.6 995.65 900000 900000 -136675 900000 900000 900000 -92982 -211537 -164330 -75328 900000 -72134 -134750 900000 900000 176775 -62815 -72617 39184 -89606 -11992 37622 80069 -72424 21310 1363 211318 154675 43440 900000 63630 -60716 499 -15225 29907 50234 5023 33975 -8619 1692 2739 14258 -19979 18220 -7897 6208 26495 -5134 11482 3898 28142 -6775 4029 16723 2001 8953 -6898 3354 -2164 -2039 9258 -180 12347 9234 933 4984 -1961 4668 6789 6144 3761 7884 -732 3683 -2732 2172 -4954 -10120 -4165 -3697 -2976 -3415 2825 -1381 -2163 -1228 -117 3563 4380 1034 4477 -565 -724 -4993 -2348 -1362 -2067 -383 -950 -1875 -452 -438 -3559 -1843 -874 -2494 -1618 558 1185 1985 3054 3410 -1069 863 -1834 -2922 -713 -1153 -234 1752 1206 1454 2752 933 1687 -695 -3423 662 -2114 -34 -1097 -1316 -1097 -631 394 -900 1711 2497 1704 299 -267 -1287 -2311 900000 900000 -1730 900000 900000 900000 -1177 -4980 -2886 -954 900000 -913 -2741 900000 900000 2238 -1334 -1871 496 -3170 -211 476 1014 -2651 353 30 2675 1958 620 900000 850 -3186 17 -663 843 1130 187 1120 -527 114 212 1079 -2214 1445 -810 565 2015 -540 1065 410 2571 -968 574 2300 341 1505 -1411 633 -423 -389 1600 -36 2491 2157 254 1293 -528 1189 1826 1912 1348 2898 -296 1379 -1014 696 -1558 -3273 -1364 -1398 -1309 -1724 1491 -812 -1366 -825 -82 2520 3104 741 2930 -362 -441 -3156 -1573 -1028 -1805 -375 -1031 -2110 -480 -427 -3261 -1634 -822 -2542 -1721 617 1400 2575 4328 5138 -1701 1315 -2718 -4174 -987 -1662 -354 2743 1926 2257 4087 1370 2373 -967 -4693 883 -3174 -56 -1996 -2557 -2222 -1341 885 -2163 4132 6102 4228 736 -629 -2907 -5082 SS 20210807T120447.7Z 7889.503330 102 1 50.41 2 77.69 79.11 65.18 80.69 0.00 1 0.00 1 0 33 3.034e-01 1.490e-02 2.850e-01 6.921e-03 5.424859e-01 3.801736e-03 9.047605e-03 -6.000000e+00 1.793605e-01 232.11 -2.00 3.54 -2.00 321.08 0.00e+00 7.829996e-03 1.769839e-03 1.060872e-02 -6.000000e+00 8.436301e-03 288.15 -2.00 20.00 -2.00 320.44 0.00e+00 4.552 0.002 302.00 328.00 3 3.2358e+00 1.2966e-02 7.2394e-02 -6.0000e+00 4.5102e-01 -7.5524e-02 1.7448e-02 7.0985e-02 -6.0000e+00 4.8774e-01 2.2696e-02 1.6849e-02 3.1220e-02 -6.0000e+00 2.8745e-01 -1.8981e-02 8.1145e-03 5.8174e-03 -6.0000e+00 1.2301e-01 1.4057e-04 1.5227e-03 2.0823e-04 1.8170e-04 -6.0000e+00 8.4524e-03 -7.1503e-03 0.0000e+00 12 8 8 10 0 0 61.28 23.17 0.57 -0.00715 0.00429 30 6 1 5 0 1680.040 25.90 20.00 23.17 28.36 35.6 995.83 900000 -181435 -119741 900000 -16573 -79737 900000 -52495 900000 -117701 900000 -43121 101845 -40264 -16313 33780 16552 32870 115786 -26205 11566 -34120 116150 -25187 -20910 -4756 -32101 -7288 -21499 -10945 1293 13112 -11726 7660 -12281 3255 15668 -4976 -5251 67 -7957 -3248 6931 13439 6695 2800 1726 4785 -1159 6225 -2908 -2541 3570 5177 -298 1452 1084 760 -5046 816 -1391 2605 7343 8708 5544 -536 -383 -4158 427 1738 3554 2413 3054 2102 -1275 -3622 -5373 -5481 -3750 -5518 -2189 -787 -1080 -2048 -319 1839 1408 2058 1801 2118 -292 -208 -3704 -3357 -1851 -3575 833 903 798 -836 6 -2343 -2918 -1580 -503 -1857 352 -501 1725 1194 2657 2035 711 34 -1124 -674 -1571 14 342 1671 296 1150 2431 1319 304 -937 -2456 -800 -955 -1308 -1486 -1549 -1613 -343 -232 209 610 1438 1883 376 -78 -721 -1091 900000 -3113 -1280 900000 -112 -538 900000 -354 900000 -1580 900000 -319 687 -459 -188 296 197 373 781 -615 200 -917 783 -668 -568 -117 -1059 -190 -637 -307 37 401 -527 318 -613 136 617 -274 -349 5 -740 -314 647 1238 676 304 195 540 -143 751 -417 -403 587 907 -59 291 225 160 -1105 168 -301 589 1789 2354 1661 -168 -116 -1301 137 627 1413 1033 1312 882 -516 -1365 -1890 -1887 -1359 -2358 -1059 -427 -648 -1318 -215 1302 1058 1603 1425 1640 -219 -145 -2521 -2246 -1318 -2933 751 926 900 -982 7 -2456 -2819 -1485 -501 -1996 390 -591 2140 1633 3924 3200 1137 54 -1681 -956 -2226 20 524 2669 488 1839 3732 1989 447 -1344 -3435 -1111 -1446 -2207 -2721 -3007 -3256 -718 -514 488 1457 3477 4578 911 -183 -1615 -2374 SS 20210807T121036.3Z 7889.507364 105 1 50.52 2 76.64 80.05 64.16 81.57 0.00 1 0.00 1 0 25 2.396e-01 1.516e-02 1.671e-01 4.772e-03 5.111815e-01 2.571676e-03 8.001620e-03 -6.000000e+00 1.398887e-01 232.11 -2.00 3.54 -2.00 320.79 0.00e+00 3.781867e-03 1.095330e-03 8.589213e-03 -6.000000e+00 6.305391e-03 288.15 -2.00 20.00 -2.00 320.11 0.00e+00 4.218 0.001 302.00 328.00 3 3.0658e+00 8.4268e-03 6.4365e-02 -6.0000e+00 3.5069e-01 -6.2866e-02 1.0838e-02 6.0895e-02 -6.0000e+00 3.7849e-01 -1.3015e-02 9.8054e-03 2.2410e-02 -6.0000e+00 2.2546e-01 -1.4585e-03 4.8332e-03 4.1107e-03 -6.0000e+00 9.6914e-02 2.3777e-04 1.2527e-03 1.4293e-04 1.1762e-04 -6.0000e+00 6.5523e-03 -6.9423e-03 0.0000e+00 12 8 8 10 0 0 75.63 23.17 0.40 -0.00694 0.00247 40 8 1 5 0 1262.850 25.90 19.99 23.17 28.71 35.5 995.44 900000 -89093 -62101 900000 -58465 -1415 -66967 111924 -106844 -67007 -79035 -81888 1554 -58528 37662 -46095 9566 -50288 6723 32530 -1660 16247 -39244 18517 -3380 5596 10890 -8865 8341 -29947 364 -25675 -7457 -1170 -12886 -4898 -7550 -1144 -9027 2705 4225 2652 8121 -72 10750 1917 2788 -2909 -2315 1945 -231 7109 1598 3345 2083 872 3669 -1477 3354 -1895 -565 560 1614 7680 2840 3117 44 -425 1323 986 3777 2343 3986 2224 -77 -2498 -6034 -4949 -6154 -3600 -3522 -2035 -1741 -2071 -894 852 1770 1595 2602 1864 1108 -406 -3569 -2227 -3319 -1629 -1480 1342 1806 -568 -531 -2852 -2611 -1932 -1636 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