File name: Pandora167s1_KenoshaWI_20210809_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T201100.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20210809_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20210809 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210809T182438.0Z 7891.767107 283 1 14.26 2 27.54 194.66 28.58 161.40 0.00 1 0.00 1 0 25 1.710e-02 1.459e-02 1.093e-03 7.955e-04 1.561004e-01 4.176760e-04 1.943824e-03 -6.000000e+00 9.987146e-03 232.03 -2.00 3.54 -2.00 314.65 0.00e+00 7.762763e-04 3.386922e-05 1.727142e-04 -6.000000e+00 4.433484e-04 288.19 -2.00 20.00 -2.00 314.02 0.00e+00 1.127 0.000 302.00 328.00 3 2.8927e+00 1.0749e-03 1.3760e-02 -6.0000e+00 2.5032e-02 2.4730e-02 1.1857e-03 8.0697e-03 -6.0000e+00 2.7011e-02 -7.3669e-03 6.8003e-04 3.8817e-03 -6.0000e+00 1.6080e-02 -8.8588e-03 3.0007e-04 1.0559e-03 -6.0000e+00 6.8974e-03 8.4761e-03 2.7452e-04 2.2341e-05 1.6506e-05 -6.0000e+00 4.6451e-04 -1.2829e-02 0.0000e+00 12 9 9 12 1 1 99.74 23.18 0.31 -0.01283 -0.01077 47 32 1 5 0 293.350 25.90 20.00 23.18 28.11 34.8 989.64 900000 1281 1843 -588 -2222 -2146 -1832 -433 -20 -1005 -3622 -3260 -2185 -1141 199 854 64 1377 1792 2068 2280 863 2273 1764 1884 1713 1248 96 -559 -1056 -285 13 1024 -1420 -4715 -5439 -5583 -4217 -1469 -739 -547 16 347 458 835 1080 31 -80 -634 -946 473 304 976 1638 905 1693 1126 505 -136 -21 312 1559 2437 3325 1972 -103 -527 -2017 -64 1055 776 1945 1535 2001 735 -686 -2302 -4207 -3418 -3418 -3067 -2484 -3104 -2309 -1010 -131 702 1299 1832 1780 1051 -93 -1566 -1827 -1501 -1480 -234 1284 1033 339 -633 -1592 -2106 -1588 -1342 -1838 -665 -817 225 1594 2086 2186 1529 989 -115 -575 -615 -489 663 1076 1069 1060 1367 974 797 32 -1588 -356 -607 -716 -624 -1055 -824 -497 99 205 300 1179 759 313 -210 -860 -1400 900000 484 717 -227 -775 -732 -618 -143 -8 -401 -1477 -1282 -887 -509 90 423 33 716 951 1122 1267 484 1246 997 1031 973 720 54 -311 -553 -148 7 580 -862 -2845 -3081 -3253 -2539 -1019 -559 -432 13 294 393 711 913 26 -65 -494 -765 382 243 816 1420 815 1533 1041 444 -126 -19 287 1403 2341 3370 1948 -103 -476 -1827 -57 970 798 1984 1603 2043 766 -662 -2137 -3621 -2855 -3089 -2909 -2583 -3299 -2545 -1100 -152 863 1575 2245 2144 1262 -103 -1668 -1903 -1563 -1564 -269 1515 1253 420 -792 -1862 -2440 -1831 -1577 -2218 -829 -1065 300 2103 2872 3070 2102 1340 -144 -697 -720 -587 839 1395 1460 1392 1843 1274 990 41 -1907 -430 -721 -905 -786 -1370 -1078 -663 138 288 437 1744 1096 451 -310 -1237 -1968 SS 20210809T182845.4Z 7891.769970 286 1 50.39 2 27.75 196.75 28.37 163.39 0.00 1 0.00 1 0 25 1.752e-02 1.323e-02 7.372e-03 3.672e-03 1.586574e-01 1.893259e-03 1.963511e-03 -6.000000e+00 1.023634e-02 232.03 -2.00 3.54 -2.00 316.38 0.00e+00 8.806811e-04 2.149773e-04 3.419355e-04 -6.000000e+00 4.543795e-04 288.19 -2.00 20.00 -2.00 315.57 0.00e+00 1.130 0.000 302.00 328.00 3 4.8276e+00 4.9664e-03 1.3846e-02 -6.0000e+00 2.5656e-02 1.5424e-02 5.5283e-03 8.1578e-03 -6.0000e+00 2.7684e-02 8.9410e-03 3.1886e-03 3.9392e-03 -6.0000e+00 1.6481e-02 -1.6659e-02 1.4815e-03 1.0862e-03 -6.0000e+00 7.0703e-03 1.2108e-03 2.3036e-04 1.0653e-04 1.3547e-05 -6.0000e+00 4.7604e-04 -1.3678e-02 0.0000e+00 12 8 8 10 0 0 99.99 23.18 0.63 -0.01368 -0.01195 761 143 1 5 0 66.200 25.90 20.01 23.18 28.19 35.1 990.75 900000 912 -2001 1230 -2790 1597 -2804 3575 -908 -3216 -1606 -6060 -1561 -1708 580 500 -1737 916 -506 2890 1925 1358 2130 980 1969 317 2284 -165 -1160 -80 -758 1597 277 597 -4068 -4458 -4285 -5756 -1189 -553 -303 -761 435 374 -276 1485 -567 1025 -474 -1009 123 -134 1380 697 1586 1068 1522 454 -357 -207 279 1960 1369 3620 1024 -1131 -541 -2625 655 1026 1087 1861 1055 2274 74 -35 -1926 -3570 -3204 -3530 -2388 -2423 -2249 -2496 -488 -266 -236 1158 1291 1941 1165 145 -1554 -2466 -1060 -2285 218 1156 1325 280 -890 -1358 -2528 -925 -1991 -1664 -688 -867 30 1263 2210 1672 1486 527 -201 -1015 -1247 -234 103 1332 862 591 1382 462 1271 -294 -1109 -206 -598 -610 -1416 -994 -841 -134 -23 161 231 989 953 407 180 -978 -1252 900000 199 -465 270 -575 288 -523 679 -200 -772 -380 -1458 -376 -456 169 159 -589 309 -177 1007 695 493 764 363 756 128 919 -66 -431 -28 -263 570 106 238 -1640 -1691 -1667 -2541 -591 -319 -194 -514 299 262 -194 1023 -392 676 -305 -635 78 -89 957 506 1179 808 1164 353 -276 -158 215 1561 1177 3237 958 -1017 -439 -2026 493 848 996 1799 1047 2198 69 -31 -1526 -2632 -2311 -2749 -2050 -2281 -2268 -2636 -533 -311 -293 1482 1677 2470 1411 163 -1604 -2374 -1012 -2361 242 1390 1711 370 -1136 -1625 -2863 -1031 -2411 -2151 -921 -1209 42 1874 3405 2646 2295 772 -271 -1279 -1524 -290 136 1865 1276 884 2016 659 1716 -384 -1382 -248 -743 -805 -1967 -1414 -1205 -195 -35 260 384 1676 1643 702 303 -1618 -2025 SS 20210809T183308.0Z 7891.773010 289 1 6.87 2 28.00 198.95 28.17 165.54 0.00 1 0.00 1 0 25 1.767e-02 1.488e-02 2.946e-03 2.126e-03 1.561008e-01 1.114758e-03 1.936521e-03 -6.000000e+00 1.032012e-02 232.03 -2.00 3.54 -2.00 314.69 0.00e+00 8.501922e-04 9.074804e-05 1.673769e-04 -6.000000e+00 4.581180e-04 288.19 -2.00 20.00 -2.00 314.05 0.00e+00 1.132 0.000 302.00 328.00 3 4.0027e+00 2.8717e-03 1.3798e-02 -6.0000e+00 2.5866e-02 3.7559e-02 3.1689e-03 8.0823e-03 -6.0000e+00 2.7911e-02 -4.0288e-03 1.8169e-03 3.8767e-03 -6.0000e+00 1.6616e-02 -1.0314e-02 8.0301e-04 1.0585e-03 -6.0000e+00 7.1277e-03 2.7636e-03 2.9191e-04 5.9555e-05 1.6003e-05 -6.0000e+00 4.7998e-04 -1.3181e-02 0.0000e+00 12 9 9 12 1 1 99.96 23.18 0.18 -0.01318 -0.01099 10 16 1 5 0 608.340 25.90 20.00 23.18 28.56 35.3 991.38 900000 1454 3264 36 -1697 -3677 -2236 -1156 -736 -1309 -3509 -3844 -2326 -774 -60 1024 -54 2145 2273 2002 1997 315 2397 2096 1928 1598 1211 -125 -1201 -1094 -643 -367 235 -1154 -4855 -4954 -5194 -4147 -1626 -226 -357 360 284 711 893 738 -19 151 -732 -1221 391 304 886 1365 907 1622 1031 575 -275 102 208 1182 2691 3255 1942 126 -616 -2276 -5 1341 1006 1859 1526 2033 849 -607 -2084 -4499 -3368 -3547 -3519 -2392 -3094 -2487 -1203 98 411 1371 2037 1646 1194 -252 -1332 -1843 -1462 -1356 -151 1436 1050 62 -555 -1715 -2255 -1506 -1020 -2222 -475 -524 463 1496 2265 2165 1660 978 -256 -215 -790 -646 626 963 1243 766 1075 837 991 192 -1710 -422 -568 -840 -929 -1191 -758 -447 -38 198 494 1214 857 440 -300 -662 -1467 900000 537 1225 14 -592 -1201 -718 -392 -273 -514 -1399 -1503 -930 -332 -28 505 -28 1095 1180 1063 1082 173 1287 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