File name: Pandora167s1_KenoshaWI_20210817_L2Fit_fout2c11d20201111p1-8.txt File generation date: 20241129T201750.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c11p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v11d20201111.txt Level 1 file used: Pandora167s1_KenoshaWI_20210817_L1_smca1c11d20201111p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20210817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 223 365 Nominal wavelengths inside fitting window [nm]: 305.0007 305.1417 305.2826 305.4236 305.5645 305.7055 305.8464 305.9873 306.1282 306.2691 306.4099 306.5508 306.6916 306.8325 306.9733 307.1141 307.2549 307.3957 307.5365 307.6773 307.8180 307.9588 308.0995 308.2402 308.3810 308.5217 308.6624 308.8030 308.9437 309.0844 309.2250 309.3656 309.5063 309.6469 309.7875 309.9281 310.0686 310.2092 310.3498 310.4903 310.6308 310.7714 310.9119 311.0524 311.1929 311.3333 311.4738 311.6143 311.7547 311.8951 312.0356 312.1760 312.3164 312.4567 312.5971 312.7375 312.8778 313.0182 313.1585 313.2988 313.4391 313.5794 313.7197 313.8600 314.0002 314.1405 314.2807 314.4209 314.5611 314.7013 314.8415 314.9817 315.1219 315.2620 315.4022 315.5423 315.6824 315.8225 315.9626 316.1027 316.2428 316.3828 316.5229 316.6629 316.8030 316.9430 317.0830 317.2230 317.3630 317.5029 317.6429 317.7828 317.9228 318.0627 318.2026 318.3425 318.4824 318.6223 318.7622 318.9020 319.0418 319.1817 319.3215 319.4613 319.6011 319.7409 319.8807 320.0204 320.1602 320.2999 320.4396 320.5794 320.7191 320.8587 320.9984 321.1381 321.2778 321.4174 321.5570 321.6967 321.8363 321.9759 322.1154 322.2550 322.3946 322.5341 322.6737 322.8132 322.9527 323.0922 323.2317 323.3712 323.5107 323.6501 323.7896 323.9290 324.0684 324.2078 324.3472 324.4866 324.6260 324.7654 324.9047 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20210817T114601.4Z 7899.490294 65 1 49.80 2 82.77 78.63 153.67 306.24 0.00 1 0.00 1 0 33 7.149e-01 3.915e-02 4.909e-01 2.856e-02 7.464492e-01 1.668210e-02 1.037873e-02 -6.000000e+00 4.235335e-01 231.67 -2.00 3.54 -2.00 322.12 0.00e+00 9.624358e-04 9.777456e-03 1.914118e-02 -6.000000e+00 2.142585e-02 288.20 -2.00 20.00 -2.00 321.59 0.00e+00 7.319 0.007 302.00 328.00 3 2.0986e+00 6.8267e-02 1.3717e-01 -6.0000e+00 1.0624e+00 7.3559e-01 8.7463e-02 1.4911e-01 -6.0000e+00 1.1511e+00 -1.2383e+00 6.4391e-02 4.7759e-02 -6.0000e+00 6.7988e-01 5.1092e-01 3.0265e-02 8.8632e-03 -6.0000e+00 2.9072e-01 2.7123e-05 1.5941e-03 8.5922e-04 2.2320e-04 -6.0000e+00 2.0146e-02 -4.4860e-03 0.0000e+00 12 8 8 10 0 0 0.32 23.17 0.89 -0.00449 0.00749 23 4 1 5 0 2164.980 25.90 20.00 23.17 24.31 36.7 999.69 900000 -5937 163354 -64930 900000 -12993 900000 -69171 -162142 900000 -19056 900000 138847 -83609 -60982 -44310 126216 84982 900000 25844 401875 900000 140285 900000 7983 900000 67777 30469 203024 2947 -52534 -69019 339446 35349 68331 -55485 -66138 41740 95691 900000 55687 107899 136502 186797 40771 -4937 81472 66558 127573 96400 4837 30298 63259 89785 50502 26833 -10600 8701 34420 8842 116134 -20224 56343 2172 17991 52785 -10601 28901 7117 28789 27400 2174 19391 284 16887 13611 -9364 4195 -23074 5131 -17361 13206 -3997 18816 10443 -4335 10429 2699 10202 -2696 1275 -5609 -12657 -11349 -9722 -5540 1061 198 -2440 -2901 -4334 -6730 -2690 4941 1975 -4563 -4311 -444 -3174 4622 -3230 4095 2711 -1389 -159 -4840 1720 -2350 4181 1987 1257 815 1020 5098 -530 2605 -727 -1355 3468 -2172 1162 -2713 993 -551 -2254 1336 639 2779 -446 -869 1432 -2061 -1287 900000 -165 4540 -2302 900000 -361 900000 -1969 -12046 900000 -530 900000 3859 -4230 -2953 -2102 3508 2362 900000 733 11170 900000 3899 900000 264 900000 1884 847 5643 89 -3029 -5452 9434 1240 1899 -4152 -5618 1415 2660 900000 2567 3173 3794 5192 2309 -429 3081 2941 3546 3437 451 2452 4067 4802 4158 2862 -1649 1120 3325 1044 4880 -3325 5007 364 2795 5853 -2099 4007 1314 4944 5303 563 4255 71 3305 2466 -1941 762 -5961 1195 -5925 3873 -1540 6240 3997 -2042 4494 1301 4611 -1347 580 -2560 -5974 -5404 -5087 -3240 682 149 -2101 -2597 -3772 -5480 -1911 3196 1409 -3710 -3709 -395 -3189 4883 -4167 5363 3707 -1959 -213 -6562 2192 -3261 5802 2964 1902 1198 1446 6778 -724 3359 -939 -1813 4988 -3792 2188 -5748 2155 -1294 -5790 3522 1746 7573 -1260 -2397 3642 -5085 -3017 SS 20210817T115705.5Z 7899.497981 68 1 50.64 2 80.77 80.45 155.20 310.50 0.00 1 0.00 1 0 25 5.781e-01 1.918e-02 2.923e-01 7.911e-03 6.577409e-01 4.464738e-03 1.138729e-02 -6.000000e+00 3.415296e-01 231.66 -2.00 3.54 -2.00 321.75 0.00e+00 6.768580e-03 2.525413e-03 1.924127e-02 -6.000000e+00 1.541911e-02 288.20 -2.00 20.00 -2.00 321.19 0.00e+00 5.916 0.004 302.00 328.00 3 1.8669e+00 1.7379e-02 1.2289e-01 -6.0000e+00 8.5790e-01 1.1143e-01 2.4433e-02 1.3969e-01 -6.0000e+00 9.2914e-01 -3.4534e-01 2.3236e-02 4.9265e-02 -6.0000e+00 5.5054e-01 1.3992e-01 1.0672e-02 6.1645e-03 -6.0000e+00 2.3385e-01 1.4449e-04 1.6298e-03 2.3693e-04 2.7227e-04 -6.0000e+00 1.6075e-02 -4.6046e-03 0.0000e+00 12 8 8 10 0 0 8.08 23.17 0.44 -0.00460 0.00764 65 12 1 5 0 778.420 25.90 20.00 23.17 25.85 36.7 999.99 900000 -209918 39782 -163447 -37961 134100 -216595 900000 -174388 -94165 -123248 -181853 900000 -124923 900000 -65804 900000 -37336 -74997 900000 -36550 148362 -70558 21277 -3781 -31636 -32057 -69601 325469 -24801 126977 -36149 24395 14649 -33205 87947 -40078 24846 -3290 9963 19544 -6375 54144 1746 46082 -198 18323 10907 8846 23156 9104 20823 6705 13147 14595 8721 15532 4194 16659 -5248 9501 14987 7400 16384 6375 9867 3413 4823 8159 1748 6886 2534 10369 -1772 -1191 -223 -6995 -6230 -9599 -4119 -3718 -2408 283 -2551 647 -433 3341 177 1295 1485 -1154 -1826 -6293 -2024 -6192 -2611 -1063 740 920 -2391 94 -4005 -2364 -2012 -1896 -1565 -2636 -276 1572 2931 2370 1668 1900 -623 -608 -2121 -848 -291 473 1334 897 2653 2289 1897 998 -1333 -2048 -1070 -151 -756 -1039 -1648 -1518 -107 -227 277 469 1657 1680 29 15 -1576 -596 900000 -4106 307 -2228 -293 1033 -4365 900000 -3024 -786 -1425 -3773 900000 -2567 900000 -1183 900000 -647 -1912 900000 -751 1143 -2039 260 -63 -731 -762 -2369 2508 -557 979 -1300 564 414 -1378 1130 -1806 734 -144 461 938 -431 2295 120 2249 -15 1151 763 661 1592 793 1814 743 1488 1739 1148 1970 599 2054 -790 1262 2052 1246 2875 1342 2000 720 1021 1809 443 1865 762 2899 -536 -330 -59 -1833 -1607 -2805 -1256 -1340 -990 127 -1254 329 -239 1885 107 786 880 -661 -984 -3377 -1050 -3701 -1750 -820 649 900 -2490 91 -3681 -1937 -1613 -1627 -1435 -2583 -283 1730 3575 3258 2491 2886 -948 -881 -2981 -1173 -419 720 2127 1448 4091 3416 2759 1412 -1868 -2788 -1472 -230 -1321 -2021 -3472 -3370 -250 -530 684 1194 4253 4348 73 37 -3913 -1405 SS 20210817T120717.8Z 7899.505067 73 1 50.59 2 78.91 82.12 156.52 314.81 0.00 1 0.00 1 0 25 3.091e-01 1.434e-02 1.756e-01 3.370e-03 5.799879e-01 1.846915e-03 9.823635e-03 -6.000000e+00 1.800784e-01 231.66 -2.00 3.54 -2.00 321.32 0.00e+00 5.413599e-03 9.231428e-04 1.269606e-02 -6.000000e+00 8.013745e-03 288.20 -2.00 20.00 -2.00 320.70 0.00e+00 5.012 0.002 302.00 328.00 3 1.5605e+00 6.5021e-03 8.5371e-02 -6.0000e+00 4.5091e-01 -9.6746e-02 9.0059e-03 8.9296e-02 -6.0000e+00 4.8691e-01 -1.9518e-02 8.8087e-03 3.3642e-02 -6.0000e+00 2.8996e-01 1.6393e-03 4.1684e-03 4.9768e-03 -6.0000e+00 1.2429e-01 4.9499e-04 1.4429e-03 1.0011e-04 1.4834e-04 -6.0000e+00 8.3985e-03 -3.9286e-03 0.0000e+00 12 8 8 10 0 0 41.58 23.19 0.37 -0.00393 0.00691 137 26 1 5 0 369.160 25.90 20.00 23.19 27.05 36.6 999.73 900000 -149892 -65702 -69697 -18874 -144157 -76909 -131427 -69431 -79000 -100419 -65442 -56958 -89867 -23243 -22754 -33464 -33854 5433 -28716 -34386 -15828 -34990 -17622 -35288 -27732 -22755 -30392 -44766 -41995 -19063 820 -8440 -74 -16369 1280 -17695 -8402 7691 2434 5947 -1370 4339 2400 3033 432 5542 -1002 1042 -1190 398 5527 3507 4347 7689 3587 2755 565 390 -2396 966 5060 6068 6054 3933 1935 1151 -496 970 3242 3732 3392 1882 975 277 -2436 -3926 -7615 -6023 -2980 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