File name: Pandora167s1_KenoshaWI_20211231_L2Fit_fwvt1c14d20211014p1-8.txt File generation date: 20250118T101637.3Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c14p1-8 Local principal investigator: Luke Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora167_OF_v4d20200117.txt Instrument calibration file used: Pandora167s1_CF_v14d20211014.txt Level 1 file used: Pandora167s1_KenoshaWI_20211231_L1_smca1c14d20211014p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20211231 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1644 1794 Nominal wavelengths inside fitting window [nm]: 492.0161 492.1370 492.2578 492.3787 492.4996 492.6204 492.7412 492.8620 492.9828 493.1036 493.2244 493.3451 493.4658 493.5865 493.7072 493.8279 493.9485 494.0692 494.1898 494.3104 494.4310 494.5515 494.6721 494.7926 494.9131 495.0336 495.1541 495.2746 495.3950 495.5155 495.6359 495.7563 495.8766 495.9970 496.1174 496.2377 496.3580 496.4783 496.5986 496.7188 496.8391 496.9593 497.0795 497.1997 497.3199 497.4400 497.5602 497.6803 497.8004 497.9205 498.0406 498.1606 498.2806 498.4007 498.5207 498.6407 498.7606 498.8806 499.0005 499.1204 499.2403 499.3602 499.4801 499.5999 499.7198 499.8396 499.9594 500.0791 500.1989 500.3187 500.4384 500.5581 500.6778 500.7975 500.9171 501.0368 501.1564 501.2760 501.3956 501.5152 501.6347 501.7543 501.8738 501.9933 502.1128 502.2322 502.3517 502.4711 502.5905 502.7099 502.8293 502.9487 503.0680 503.1874 503.3067 503.4260 503.5453 503.6645 503.7838 503.9030 504.0222 504.1414 504.2606 504.3797 504.4989 504.6180 504.7371 504.8562 504.9753 505.0943 505.2134 505.3324 505.4514 505.5704 505.6893 505.8083 505.9272 506.0461 506.1650 506.2839 506.4028 506.5216 506.6404 506.7592 506.8780 506.9968 507.1156 507.2343 507.3530 507.4717 507.5904 507.7091 507.8278 507.9464 508.0650 508.1836 508.3022 508.4208 508.5393 508.6578 508.7763 508.8948 509.0133 509.1318 509.2502 509.3687 509.4871 509.6055 509.7238 509.8422 509.9605 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20211231T174158.4Z 8035.737481 242 1 5.94 2 65.61 176.84 71.55 207.37 0.00 1 0.00 1 0 15 5.348e-03 5.345e-03 3.067e-03 3.061e-03 8.015852e+02 1.708314e+02 7.732105e+01 -6.000000e+00 2.925004e+02 273.83 -2.00 20.00 -2.00 505.25 0.00e+00 4.017504e-04 8.276436e-05 2.054224e-05 -6.000000e+00 1.478519e-04 273.83 -2.00 20.00 -2.00 500.38 0.00e+00 8.333359e-02 6.075682e-02 4.152695e-03 -6.000000e+00 1.065239e-01 222.99 -2.00 3.54 -2.00 501.99 0.00e+00 2.405 0.000 489.00 513.00 1 6.7995e+00 4.6560e-03 3.4199e-03 -6.0000e+00 8.1609e-03 1.6661e-02 1.1962e-03 2.1716e-04 -6.0000e+00 2.0940e-03 1.5447e-03 3.2758e-04 3.1903e-04 1.3654e-05 -6.0000e+00 5.7162e-04 1.6416e-03 1.8953e-05 12 9 9 12 1 1 999.00 22.83 1.32 0.00164 0.00391 1 3 1 4 0 2878.710 25.58 20.00 22.83 10.95 34.1 996.17 -956 -509 -506 -825 217 717 588 1246 458 178 318 296 -816 -180 -933 -1058 -838 107 480 -177 491 426 585 162 521 715 316 2 -459 -310 -1016 -408 -204 30 694 -126 34 -196 181 -158 -285 428 -34 657 641 553 624 746 157 -210 -471 -714 -1440 -789 -634 9 -271 148 546 249 526 132 835 104 345 276 183 -2 -156 -301 -695 -811 -370 346 -193 135 329 -434 -116 -545 -13 -177 -680 97 -102 -286 -687 -458 -356 407 212 801 14 494 1164 821 588 141 -519 -635 -914 -930 -658 -47 -300 -115 214 -576 -212 -276 -402 -551 -15 583 698 681 1420 404 510 372 783 -343 1 106 -3 712 612 -329 47 -18 -356 -280 -167 -1135 -782 -249 -188 -383 140 186 213 389 448 162 256 20 431 -31 191 -828 -821 -954 -495 -505 -852 222 747 625 1293 481 186 335 307 -846 -183 -947 -1075 -859 111 494 -186 516 449 616 172 552 757 334 3 -474 -320 -1032 -409 -207 30 720 -134 36 -206 187 -163 -292 437 -35 683 671 583 655 773 161 -211 -475 -704 -1405 -766 -626 9 -274 151 556 255 535 135 853 107 353 279 182 -2 -156 -297 -684 -797 -365 342 -189 131 324 -425 -112 -525 -12 -171 -665 96 -99 -279 -677 -452 -351 399 210 797 13 490 1144 821 578 137 -494 -610 -872 -892 -627 -46 -293 -114 209 -560 -209 -272 -389 -543 -15 583 702 689 1431 401 517 373 769 -336 1 102 -3 689 592 -321 46 -17 -343 -267 -161 -1088 -743 -237 -181 -368 136 183 211 386 435 159 250 20 424 -30 181 -781 -776 SQ 20211231T180255.8Z 8035.752035 254 1 50.79 2 65.57 182.14 73.43 211.82 0.00 1 0.00 1 0 15 5.048e-03 5.055e-03 6.024e-04 6.005e-04 9.015475e+02 3.398795e+01 5.582794e+01 -6.000000e+00 2.760938e+02 273.82 -2.00 20.00 -2.00 505.25 0.00e+00 4.605742e-04 1.625278e-05 2.437733e-05 -6.000000e+00 1.395552e-04 273.82 -2.00 20.00 -2.00 500.30 0.00e+00 7.510095e-02 1.198420e-02 1.056061e-02 -6.000000e+00 1.005373e-01 222.99 -2.00 3.54 -2.00 501.93 0.00e+00 2.402 0.000 489.00 513.00 1 6.1063e+00 9.1945e-04 3.5133e-03 -6.0000e+00 7.7024e-03 1.7396e-02 2.3596e-04 2.7904e-04 -6.0000e+00 1.9761e-03 3.0896e-03 3.3949e-04 6.2441e-05 1.0257e-05 -6.0000e+00 5.3959e-04 5.7725e-03 3.7136e-06 12 8 8 10 0 0 99.99 22.82 1.26 0.00577 0.00813 61 11 1 4 0 832.510 25.58 20.00 22.82 11.79 34.8 995.54 -1298 -1043 -669 -399 65 657 838 862 719 573 566 -90 -428 -499 -813 -871 -411 -46 -88 -16 379 231 347 495 543 734 562 -7 -324 -538 -710 -854 -256 246 75 83 313 69 -124 -121 49 203 275 533 749 776 847 741 325 -229 -685 -976 -1098 -1091 -544 -387 -153 -11 6 273 623 562 550 610 449 266 336 -10 -243 -470 -184 -359 -202 211 74 -22 -200 -321 -384 -424 -598 -725 -614 -244 -295 -359 -400 -276 -150 -239 244 483 597 422 695 621 264 -140 -373 -609 -912 -781 -90 -133 -219 -268 -341 -457 -97 -183 -316 -92 207 566 611 778 940 743 776 595 308 188 409 189 75 105 255 292 424 242 -138 -206 -329 -852 -650 -392 -467 -594 -150 8 105 258 480 584 538 205 -79 -342 -388 -574 -649 -1293 -1045 -685 -399 66 685 888 924 773 611 596 -93 -442 -509 -824 -883 -420 -47 -94 -17 410 251 377 537 592 797 609 -7 -343 -556 -719 -861 -260 256 80 86 323 71 -132 -128 51 213 292 542 767 798 868 751 341 -236 -692 -964 -1068 -1062 -537 -393 -158 -11 6 273 620 562 552 611 448 263 343 -10 -243 -465 -180 -351 -198 210 74 -22 -198 -313 -371 -408 -577 -704 -601 -240 -280 -343 -385 -266 -144 -231 236 471 589 421 689 608 255 -133 -346 -584 -868 -747 -84 -127 -216 -265 -337 -445 -93 -176 -307 -91 206 568 618 790 956 757 787 598 305 183 396 184 73 103 249 284 411 235 -133 -197 -311 -796 -603 -365 -442 -574 -146 8 100 246 458 559 516 196 -75 -334 -370 -542 -615 SQ 20211231T180721.8Z 8035.755113 257 1 26.20 2 65.61 183.26 73.86 212.74 0.00 1 0.00 1 0 15 5.380e-03 5.372e-03 1.520e-03 1.516e-03 1.148059e+03 8.648703e+01 7.205985e+01 -6.000000e+00 2.942792e+02 273.82 -2.00 20.00 -2.00 505.26 0.00e+00 4.380746e-04 4.098622e-05 2.459414e-05 -6.000000e+00 1.487400e-04 273.82 -2.00 20.00 -2.00 500.37 0.00e+00 1.065237e-02 3.013972e-02 1.283632e-02 -6.000000e+00 1.071243e-01 222.99 -2.00 3.54 -2.00 501.98 0.00e+00 2.405 0.000 489.00 513.00 1 7.2446e+00 2.3084e-03 3.5692e-03 -6.0000e+00 8.2074e-03 1.5077e-02 5.9225e-04 3.1990e-04 -6.0000e+00 2.1048e-03 9.9387e-04 2.0286e-04 1.5829e-04 1.1756e-05 -6.0000e+00 5.7509e-04 3.3047e-03 4.4305e-05 12 9 9 12 1 1 99.95 22.82 1.23 0.00330 0.00471 7 3 1 4 0 3252.850 25.58 20.00 22.82 12.08 34.8 991.96 -1130 -1005 -662 -552 218 661 791 603 782 614 608 -64 -593 -407 -836 -821 -275 -44 10 65 149 109 644 783 595 702 242 -53 -434 -545 -674 -955 -269 234 122 -125 426 -30 -50 98 52 137 306 490 694 785 933 640 375 -21 -652 -1151 -1247 -1096 -685 -537 -192 9 66 588 411 579 616 508 671 643 824 -81 -461 -605 -582 -346 -268 503 -99 -475 -1 -495 -279 -523 -393 -739 -904 -464 -231 -315 -313 -141 -265 -395 216 539 457 323 805 834 51 146 -716 -526 -967 -712 46 -153 -416 -312 -253 -373 -225 -213 -14 -59 543 357 840 859 999 690 656 700 425 119 681 152 -100 91 146 35 50 303 -410 -180 -339 -703 -648 -92 -492 -539 34 284 31 389 367 702 544 76 -69 -576 -392 -811 -562 -1109 -994 -669 -563 227 686 834 644 835 651 636 -67 -609 -422 -862 -846 -279 -45 11 69 158 116 678 825 630 744 257 -55 -448 -561 -679 -959 -273 243 128 -133 449 -31 -52 101 53 140 316 510 728 827 977 665 384 -21 -656 -1134 -1210 -1064 -675 -543 -194 9 67 600 421 593 632 522 685 649 817 -79 -451 -598 -571 -337 -263 496 -97 -467 -1 -484 -269 -503 -378 -717 -866 -447 -224 -309 -309 -139 -262 -392 215 529 455 323 800 819 49 141 -684 -492 -900 -665 43 -147 -412 -311 -250 -365 -218 -206 -14 -58 542 354 836 859 1001 694 657 692 415 117 662 149 -98 90 143 35 49 295 -400 -173 -321 -661 -605 -86 -470 -513 33 276 30 382 363 694 539 76 -68 -555 -369 -758 -526 SQ 20211231T181202.7Z 8035.758365 260 1 50.49 2 65.67 184.44 74.33 213.70 0.00 1 0.00 1 0 8 4.991e-03 4.984e-03 1.038e-03 1.034e-03 9.743733e+02 5.818957e+01 6.999021e+01 -6.000000e+00 2.729968e+02 273.82 -2.00 20.00 -2.00 505.21 0.00e+00 4.500209e-04 2.790047e-05 2.239572e-05 -6.000000e+00 1.379819e-04 273.82 -2.00 20.00 -2.00 500.30 0.00e+00 7.136162e-02 2.055090e-02 9.077088e-03 -6.000000e+00 9.937209e-02 222.99 -2.00 3.54 -2.00 501.91 0.00e+00 2.411 0.000 489.00 513.00 1 7.0808e+00 1.5740e-03 3.4958e-03 -6.0000e+00 7.6136e-03 1.7456e-02 4.0519e-04 2.7015e-04 -6.0000e+00 1.9524e-03 1.1649e-03 -1.2275e-04 1.0775e-04 1.2130e-05 -6.0000e+00 5.3350e-04 3.5964e-03 4.6269e-05 12 8 8 10 0 0 99.49 22.82 1.27 0.00360 0.00274 20 4 1 4 0 2523.950 25.58 19.99 22.82 12.23 34.6 987.05 -1231 -956 -811 -307 185 552 785 720 721 443 513 -99 -488 -512 -794 -744 -508 -45 9 -77 536 170 338 477 528 764 657 12 -475 -433 -734 -949 -283 404 87 106 235 333 -189 -98 24 104 290 510 572 683 685 768 266 -177 -481 -829 -1333 -864 -690 -394 -163 16 160 172 653 476 399 411 598 366 321 30 -312 -414 -134 -349 -386 327 148 -349 -202 -440 -244 -511 -515 -640 -549 -223 -337 -293 -435 -66 -30 -207 331 617 720 515 731 759 106 -145 -306 -614 -1023 -622 -284 -136 -247 -189 -187 -295 -421 -468 -285 -212 432 494 554 983 819 690 760 570 264 59 443 114 45 15 176 165 331 1 -110 -240 -219 -993 -672 -268 -485 -228 -54 90 190 133 523 535 461 90 -152 -238 -323 -629 -825 -1210 -944 -821 -318 197 598 819 760 762 466 532 -102 -523 -542 -836 -782 -539 -46 9 -82 570 182 361 509 565 817 699 12 -496 -439 -730 -942 -283 414 91 113 250 351 -199 -102 25 107 303 536 606 726 726 804 275 -180 -477 -804 -1278 -825 -671 -393 -166 16 165 178 671 491 414 427 616 373 323 29 -307 -403 -129 -335 -374 319 146 -346 -197 -423 -232 -484 -488 -611 -528 -215 -330 -289 -432 -66 -30 -207 330 622 733 529 748 767 106 -142 -293 -579 -958 -584 -272 -135 -238 -184 -180 -296 -419 -466 -272 -205 422 487 550 976 818 691 757 562 256 57 421 109 43 15 169 157 315 1 -104 -226 -202 -911 -611 -244 -451 -215 -51 87 185 131 513 527 454 88 -148 -227 -302 -583 -769 SQ 20211231T182203.0Z 8035.765313 263 1 49.87 2 65.85 186.95 75.36 215.73 0.00 1 0.00 1 0 15 4.930e-03 4.943e-03 7.129e-04 7.107e-04 9.092657e+02 4.020284e+01 5.962758e+01 -6.000000e+00 2.696413e+02 273.82 -2.00 20.00 -2.00 505.25 0.00e+00 4.398822e-04 1.925212e-05 2.259340e-05 -6.000000e+00 1.362870e-04 273.82 -2.00 20.00 -2.00 500.31 0.00e+00 9.181232e-02 1.417608e-02 9.965548e-03 -6.000000e+00 9.815544e-02 222.99 -2.00 3.54 -2.00 501.94 0.00e+00 2.427 0.000 489.00 513.00 1 6.4204e+00 1.0878e-03 3.5314e-03 -6.0000e+00 7.5203e-03 1.8126e-02 2.7907e-04 2.7610e-04 -6.0000e+00 1.9286e-03 2.2465e-03 -2.1738e-04 7.3950e-05 1.0210e-05 -6.0000e+00 5.2694e-04 3.4347e-03 4.3817e-05 12 8 8 10 0 0 99.65 22.81 1.30 0.00343 0.00193 34 6 1 4 0 1466.490 25.58 19.99 22.81 12.26 34.2 985.63 -1275 -924 -577 -523 -40 616 790 892 798 541 458 -165 -324 -537 -619 -678 -505 30 52 49 331 160 402 448 723 654 660 150 -565 -446 -719 -971 -213 260 -9 99 128 117 -28 -59 -81 -113 366 556 625 787 689 637 301 -256 -526 -1022 -1100 -926 -653 -402 -252 -44 210 362 495 569 607 600 498 313 466 -57 -277 -334 -283 -392 -203 303 57 -66 -220 -486 -404 -439 -392 -630 -705 -249 -293 -369 -374 -251 -178 -206 332 600 593 451 639 584 155 -70 -363 -578 -780 -651 -341 -102 -366 -140 -293 -485 -349 -224 -115 -108 225 353 556 834 864 856 653 557 349 205 454 141 151 206 257 209 332 244 -278 -99 -400 -794 -747 -397 -506 -462 -35 45 61 279 533 577 374 287 -18 -236 -311 -750 -565 -1274 -927 -592 -526 -41 644 840 959 859 580 484 -173 -335 -549 -628 -688 -517 31 56 53 359 174 437 488 788 679 716 162 -602 -462 -730 -982 -217 271 -10 103 133 120 -30 -62 -85 -119 389 567 643 812 708 648 302 -265 -532 -1012 -1072 -901 -647 -409 -249 -44 211 362 494 570 610 602 498 309 453 -58 -278 -330 -278 -384 -200 300 58 -66 -219 -476 -390 -423 -378 -612 -691 -246 -278 -353 -360 -242 -171 -199 321 585 586 449 635 573 150 -66 -338 -555 -742 -622 -317 -97 -360 -139 -289 -473 -336 -216 -111 -106 224 355 563 847 880 873 664 560 346 200 440 137 147 201 251 203 322 237 -269 -95 -377 -742 -694 -370 -480 -446 -34 44 58 266 509 553 360 275 -17 -229 -296 -710 -535