File name: Pandora167s1_KenoshaWI_20220304_L2Fit_fout2c14d20211014p1-8.txt File generation date: 20250118T103330.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora167_OF_v5d20200117.txt Instrument calibration file used: Pandora167s1_CF_v14d20211014.txt Level 1 file used: Pandora167s1_KenoshaWI_20220304_L1_smca1c14d20211014p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20220304 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 365 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2495 305.3904 305.5313 305.6722 305.8131 305.9540 306.0949 306.2357 306.3766 306.5174 306.6582 306.7991 306.9399 307.0807 307.2214 307.3622 307.5030 307.6437 307.7844 307.9252 308.0659 308.2066 308.3473 308.4880 308.6286 308.7693 308.9099 309.0506 309.1912 309.3318 309.4724 309.6130 309.7536 309.8941 310.0347 310.1752 310.3157 310.4563 310.5968 310.7373 310.8778 311.0182 311.1587 311.2991 311.4396 311.5800 311.7204 311.8608 312.0012 312.1416 312.2820 312.4223 312.5627 312.7030 312.8434 312.9837 313.1240 313.2643 313.4045 313.5448 313.6851 313.8253 313.9656 314.1058 314.2460 314.3862 314.5264 314.6666 314.8067 314.9469 315.0870 315.2271 315.3673 315.5074 315.6475 315.7876 315.9276 316.0677 316.2077 316.3478 316.4878 316.6278 316.7678 316.9078 317.0478 317.1878 317.3277 317.4677 317.6076 317.7475 317.8874 318.0273 318.1672 318.3071 318.4470 318.5868 318.7267 318.8665 319.0063 319.1461 319.2859 319.4257 319.5655 319.7052 319.8450 319.9847 320.1245 320.2642 320.4039 320.5436 320.6832 320.8229 320.9626 321.1022 321.2418 321.3815 321.5211 321.6607 321.8003 321.9398 322.0794 322.2189 322.3585 322.4980 322.6375 322.7770 322.9165 323.0560 323.1955 323.3349 323.4744 323.6138 323.7532 323.8926 324.0320 324.1714 324.3108 324.4502 324.5895 324.7289 324.8682 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220304T130918.7Z 8098.548134 61 1 50.47 2 82.25 105.98 95.86 86.48 0.00 1 0.00 1 0 25 6.054e-01 2.034e-02 3.932e-01 9.949e-03 7.955463e-01 5.655216e-03 1.251086e-02 -6.000000e+00 3.474206e-01 225.44 -2.00 3.54 -2.00 322.11 0.00e+00 2.116845e-02 3.120111e-03 1.427055e-02 -6.000000e+00 1.532432e-02 274.10 -2.00 20.00 -2.00 321.71 0.00e+00 6.912 0.006 302.00 328.00 3 9.7950e-01 2.1276e-02 9.5309e-02 -6.0000e+00 8.6446e-01 4.0378e-01 3.2115e-02 6.7679e-02 -6.0000e+00 9.4028e-01 -7.1038e-01 3.5309e-02 5.2442e-02 -6.0000e+00 5.5611e-01 2.9767e-01 1.6179e-02 2.8680e-02 -6.0000e+00 2.4022e-01 1.1447e-04 4.8624e-04 2.8865e-04 6.2462e-04 -6.0000e+00 1.6429e-02 2.2571e-03 0.0000e+00 12 9 8 11 8 0 -6.48 22.98 0.44 0.00226 0.00591 74 14 1 5 0 681.820 25.79 20.00 22.98 6.79 34.9 1012.58 -209974 900000 -87763 -11659 -236125 -161852 -246689 -213598 900000 -133649 -81042 -189803 -38313 -73342 -27598 83553 -58799 15928 900000 -89562 -82668 -63464 900000 -52558 -48693 -103182 20440 -6599 -19437 272542 9641 24917 -16788 16027 -9467 -19115 32626 -35090 159686 -20937 -5314 44943 144 87456 446 22109 18652 12174 20906 17061 30353 33983 57890 18917 11026 5927 3427 13533 -2790 22912 6934 22329 20406 9626 21193 14561 22699 -3077 7961 4097 11363 16948 3604 6141 -1430 1101 -9837 -5711 -2246 1230 2516 -1813 636 -2426 -1054 2542 2992 1376 2654 -1499 247 -6515 -3016 -4675 -6249 -2580 953 1056 439 775 -2537 -3766 -3504 -3987 -3511 -1230 -1449 -147 2141 1490 1268 -454 -383 -2234 -3216 -691 -462 1362 1577 2560 3321 2552 3225 765 -589 -1433 -1589 288 -1004 122 -1298 -695 -958 -668 213 281 2353 1380 -17 -309 -1547 -1117 -3392 900000 -851 -113 -4768 -1569 -4982 -3106 900000 -1295 -786 -2913 -371 -776 -268 810 -984 154 900000 -2243 -1870 -1230 900000 -880 -772 -2584 198 -70 -257 2642 153 417 -488 339 -242 -539 604 -1360 1548 -930 -219 1307 6 1850 22 911 844 629 1064 992 1741 2086 3039 1559 1006 574 338 1170 -277 1795 694 2218 2423 1438 2927 2129 3117 -584 1543 864 2381 3387 785 1295 -291 199 -1970 -1213 -514 331 786 -671 248 -1031 -472 1162 1423 677 1272 -712 108 -2900 -1306 -2279 -3662 -1745 736 936 417 714 -2205 -2934 -2552 -3041 -2864 -1036 -1315 -145 2350 1889 1791 -684 -576 -3303 -4606 -955 -663 2038 2488 4040 5017 3706 4510 1063 -806 -1916 -2148 428 -1766 242 -2869 -1515 -2232 -1666 564 768 6399 3823 -48 -802 -3781 -2754 SS 20220304T132811.0Z 8098.561239 66 1 50.43 2 78.93 109.34 92.44 89.52 0.00 1 0.00 1 0 33 3.920e-01 1.462e-02 2.440e-01 4.425e-03 6.231422e-01 2.399778e-03 9.638703e-03 -6.000000e+00 2.238293e-01 225.44 -2.00 3.54 -2.00 321.34 0.00e+00 1.103892e-02 1.103175e-03 9.560455e-03 -6.000000e+00 9.590652e-03 274.10 -2.00 20.00 -2.00 320.89 0.00e+00 5.027 0.002 302.00 328.00 3 1.8008e+00 7.9276e-03 6.9547e-02 -6.0000e+00 5.5501e-01 -1.8888e-02 1.1196e-02 5.7038e-02 -6.0000e+00 6.0267e-01 -6.9475e-02 1.2288e-02 4.2724e-02 -6.0000e+00 3.5762e-01 2.5578e-02 5.8978e-03 1.9282e-02 -6.0000e+00 1.5417e-01 3.5221e-04 5.9532e-04 1.2897e-04 3.0903e-04 -6.0000e+00 1.0615e-02 2.4471e-03 0.0000e+00 12 9 8 11 8 0 99.34 22.98 0.23 0.00245 0.00692 109 20 1 5 0 462.580 25.68 19.99 22.98 8.39 34.6 1019.62 -180129 7493 -142681 -23867 -85918 -160729 -114682 -84475 -89357 -139205 -108760 -101478 -92013 -58352 -22157 96416 13735 -24652 -16717 -44500 -38932 -41268 125844 -10479 -15501 -13103 -35870 -49916 -7770 -23465 -7487 8369 -6982 -16813 17923 -13531 -4309 -5744 -8066 -1469 2634 -9789 2693 6253 5305 7870 3049 974 8988 4233 14142 7533 8244 4198 548 1219 -3140 -1797 4435 2947 1682 4402 10352 5001 5238 1738 -1360 322 1667 2058 2507 2290 1598 -541 -3908 -3397 -6749 -6745 -3473 -2167 -3 -2370 -2736 -824 657 1809 2359 2133 1729 1124 -936 -3363 -3307 -3537 -2450 -1868 1110 1872 609 128 -1990 -2105 -1011 -1978 -2135 -1405 -791 382 2121 2008 2074 1226 -101 -1415 -1989 -587 -412 951 1344 868 1906 2045 1650 757 -719 -2642 -1291 -241 -656 -1040 -1439 -1377 -748 -230 -39 22 1612 1513 449 108 -740 -952 -2057 32 -1462 -103 -440 -1734 -835 -501 -602 -1614 -997 -1067 -1191 -724 -245 416 144 -400 -272 -1005 -840 -911 615 -186 -303 -259 -901 -1444 -156 -643 -217 249 -261 -709 541 -545 -180 -292 -507 -100 189 -811 209 487 434 654 277 95 855 460 1564 989 1172 666 94 213 -580 -323 736 506 316 916 2213 1248 1328 443 -358 88 512 717 935 872 593 -191 -1292 -1015 -2021 -2153 -1256 -921 -2 -1314 -1635 -513 432 1250 1697 1566 1257 780 -617 -2135 -2062 -2376 -1871 -1654 1105 1989 689 141 -2149 -2042 -924 -1919 -2231 -1534 -870 449 2723 2887 3239 1986 -162 -2192 -2932 -835 -604 1458 2178 1442 3062 3155 2476 1104 -1026 -3694 -1771 -358 -1111 -1970 -2957 -2973 -1615 -526 -95 56 4088 3891 1148 264 -1711 -2196 SS 20220304T133404.3Z 8098.565328 69 1 50.04 2 77.91 110.41 91.37 90.47 0.00 1 0.00 1 0 33 2.763e-01 1.424e-02 8.252e-02 1.742e-03 5.810533e-01 9.296144e-04 8.542978e-03 -6.000000e+00 1.577778e-01 225.44 -2.00 3.54 -2.00 321.03 0.00e+00 7.506628e-03 3.986913e-04 8.091027e-03 -6.000000e+00 6.760137e-03 274.10 -2.00 20.00 -2.00 320.58 0.00e+00 4.634 0.002 302.00 328.00 3 8.0703e-01 2.9771e-03 6.3366e-02 -6.0000e+00 3.9123e-01 -5.1964e-02 4.0268e-03 5.1288e-02 -6.0000e+00 4.2481e-01 -1.5230e-02 4.2796e-03 3.4622e-02 -6.0000e+00 2.5208e-01 -2.4542e-03 2.0914e-03 1.4170e-02 -6.0000e+00 1.0868e-01 1.4441e-03 6.5686e-04 5.0859e-05 2.3781e-04 -6.0000e+00 7.4817e-03 1.9721e-03 0.0000e+00 12 8 8 10 0 0 60.59 22.97 0.23 0.00197 0.00691 283 53 1 5 0 176.780 25.68 20.00 22.97 8.38 34.4 1018.88 -110810 -8949 -93678 -46670 -104120 -118880 -98155 -107645 -16380 -93029 -20151 -99004 -71639 -35738 -39543 20403 -26115 13865 -20389 -17768 -10871 -24532 3013 -15664 4042 -21597 -23957 -17602 -30659 7407 -4106 6575 1031 -9568 -6678 -14829 305 -6390 1275 -859 -3155 -45 -581 4281 1139 5926 2343 1330 4228 1426 5286 4057 6815 3868 3498 1904 -2212 -743 -1609 1185 1293 3929 6349 4034 2822 -103 -150 720 2143 2288 2083 2620 907 366 -2751 -4596 -7047 -6295 -3654 -2801 -1027 -1957 -2109 -1474 -384 1476 1750 2649 2281 1170 -280 -3355 -3530 -3442 -2519 -719 1207 1898 539 -305 -1990 -2141 -1682 -846 -1947 -1132 -525 403 1933 2382 2083 1068 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