File name: Pandora167s1_KenoshaWI_20220310_L2Fit_fout2c14d20211014p1-8.txt File generation date: 20250129T100119.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c14p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora167_OF_v5d20200117.txt Instrument calibration file used: Pandora167s1_CF_v14d20211014.txt Level 1 file used: Pandora167s1_KenoshaWI_20220310_L1_smca1c14d20211014p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20220310 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 224 365 Nominal wavelengths inside fitting window [nm]: 305.1085 305.2495 305.3904 305.5313 305.6722 305.8131 305.9540 306.0949 306.2357 306.3766 306.5174 306.6582 306.7991 306.9399 307.0807 307.2214 307.3622 307.5030 307.6437 307.7844 307.9252 308.0659 308.2066 308.3473 308.4880 308.6286 308.7693 308.9099 309.0506 309.1912 309.3318 309.4724 309.6130 309.7536 309.8941 310.0347 310.1752 310.3157 310.4563 310.5968 310.7373 310.8778 311.0182 311.1587 311.2991 311.4396 311.5800 311.7204 311.8608 312.0012 312.1416 312.2820 312.4223 312.5627 312.7030 312.8434 312.9837 313.1240 313.2643 313.4045 313.5448 313.6851 313.8253 313.9656 314.1058 314.2460 314.3862 314.5264 314.6666 314.8067 314.9469 315.0870 315.2271 315.3673 315.5074 315.6475 315.7876 315.9276 316.0677 316.2077 316.3478 316.4878 316.6278 316.7678 316.9078 317.0478 317.1878 317.3277 317.4677 317.6076 317.7475 317.8874 318.0273 318.1672 318.3071 318.4470 318.5868 318.7267 318.8665 319.0063 319.1461 319.2859 319.4257 319.5655 319.7052 319.8450 319.9847 320.1245 320.2642 320.4039 320.5436 320.6832 320.8229 320.9626 321.1022 321.2418 321.3815 321.5211 321.6607 321.8003 321.9398 322.0794 322.2189 322.3585 322.4980 322.6375 322.7770 322.9165 323.0560 323.1955 323.3349 323.4744 323.6138 323.7532 323.8926 324.0320 324.1714 324.3108 324.4502 324.5895 324.7289 324.8682 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20220310T135227.1Z 8104.578092 133 1 49.87 2 72.81 112.44 108.15 26.47 0.00 1 0.00 1 0 25 3.329e-01 1.865e-02 2.139e-01 7.824e-03 5.324658e-01 4.139500e-03 7.575061e-03 -6.000000e+00 1.915192e-01 225.69 -2.00 3.54 -2.00 320.59 0.00e+00 6.762325e-03 1.536335e-03 5.806857e-03 -6.000000e+00 8.294417e-03 274.52 -2.00 20.00 -2.00 320.10 0.00e+00 3.335 0.001 302.00 328.00 3 4.5347e+00 1.2425e-02 4.7850e-02 -6.0000e+00 4.7481e-01 2.9671e-02 1.5658e-02 3.8456e-02 -6.0000e+00 5.1562e-01 -6.7368e-02 1.5041e-02 2.5362e-02 -6.0000e+00 3.0511e-01 2.0696e-02 7.6138e-03 1.0572e-02 -6.0000e+00 1.3121e-01 1.1366e-04 4.5494e-04 2.2773e-04 1.6170e-04 -6.0000e+00 9.0673e-03 2.4033e-03 0.0000e+00 12 9 8 11 8 0 99.93 22.96 0.46 0.00240 0.00582 15 3 1 5 0 3323.990 25.68 19.97 22.96 1.12 33.5 1006.25 36168 -131405 -96832 157477 -155803 900000 -50998 -10787 -156601 153050 -18802 -65935 900000 -58023 27259 -14299 3216 -4570 18939 45472 -9999 -992 -24772 -41420 -5117 -14340 10162 -38677 15625 -28124 -17715 -2540 4570 7135 -8336 18161 -11873 -1135 16248 6438 7154 -894 2234 -787 7727 1765 22912 11779 -1632 7905 -716 12318 10425 -682 2883 2064 5958 2361 3663 -3747 4106 4357 4640 8316 530 -1371 1044 -924 6767 2765 5366 -736 981 -612 -3005 -3370 -7600 -3485 -4783 -5044 -3247 -2379 -1550 -1358 -73 587 1316 1803 2252 1795 -563 -3217 -4983 -5086 -3557 -1174 1914 664 182 -668 -1675 -1518 -1033 -1932 -2026 -247 -721 -21 2550 2603 2622 1728 1154 -1509 -1152 -1822 -809 187 1299 1093 820 2070 1372 426 91 -2197 -299 -1442 -575 -523 -1239 -1349 -1163 109 -296 739 1134 1137 1149 -318 -526 -1505 276 -3465 -1916 1201 -4674 900000 -619 -100 -6133 1167 -222 -1405 900000 -1821 471 -417 88 -146 517 1012 -377 -34 -1113 -2306 -213 -672 378 -2224 548 -1646 -1109 -160 300 463 -597 1038 -1014 -104 1510 754 907 -130 329 -122 1131 280 3028 1777 -290 1373 -149 2480 2301 -178 754 559 1571 634 954 -1058 1145 1353 1614 3035 209 -526 385 -362 2767 1326 2690 -398 508 -301 -1380 -1407 -3158 -1449 -2290 -2827 -2036 -1640 -1130 -1042 -59 499 1161 1609 1974 1502 -447 -2456 -3742 -4027 -3109 -1146 2057 801 230 -821 -1923 -1580 -1027 -2038 -2286 -288 -886 -27 3525 3935 4228 2850 1867 -2369 -1705 -2642 -1192 286 2086 1805 1334 3229 2091 632 130 -3085 -408 -2121 -932 -920 -2332 -2637 -2359 231 -664 1694 2637 2672 2666 -717 -1132 -3137 SS 20220310T140243.7Z 8104.585228 139 1 22.34 2 71.07 114.42 107.30 28.63 0.00 1 0.00 1 0 25 2.387e-01 1.503e-02 1.950e-01 6.156e-03 4.814123e-01 3.198067e-03 6.263735e-03 -6.000000e+00 1.364951e-01 225.70 -2.00 3.54 -2.00 320.09 0.00e+00 6.304030e-03 1.043526e-03 3.466098e-03 -6.000000e+00 6.034924e-03 274.52 -2.00 20.00 -2.00 319.59 0.00e+00 3.046 0.000 302.00 328.00 3 4.2443e+00 9.2429e-03 4.0334e-02 -6.0000e+00 3.3855e-01 -6.2534e-02 1.1240e-02 2.7900e-02 -6.0000e+00 3.6754e-01 2.7071e-02 1.0462e-02 1.8993e-02 -6.0000e+00 2.1837e-01 -1.8545e-02 5.4491e-03 9.0359e-03 -6.0000e+00 9.5013e-02 2.1710e-04 5.4190e-04 1.7773e-04 1.1219e-04 -6.0000e+00 6.5738e-03 2.1764e-03 0.0000e+00 12 9 9 12 1 1 98.80 22.92 0.35 0.00218 0.00625 7 3 1 5 0 2765.700 25.68 20.01 22.92 1.37 33.2 1006.79 -82478 900000 -81781 900000 -82112 57494 80865 -63412 73303 -82149 149656 -34064 24953 -6648 -21672 -26536 11723 9946 9115 -9018 -3378 -8495 16890 -8159 32776 24646 13214 2039 -5066 -6655 -13205 16750 -250 -307 -7479 -11972 -7020 -9384 10100 -5676 4936 2553 1192 -1125 -2428 2667 -1180 -183 -2425 2523 2098 97 2699 3037 1805 979 -2952 -3169 -3850 6071 2357 7538 3067 3367 2079 -1416 -1563 -2422 672 777 2673 3552 2015 1914 -2377 -4137 -4672 -5353 -3008 -3641 309 -2417 -337 -1106 -314 1353 474 3351 723 1313 -15 -2232 -2765 -2469 -1858 -1505 2163 920 1358 -170 -1952 -1149 -2365 -892 -1410 -1998 -956 5 1594 2089 2496 1162 729 -617 -1877 -1006 -1193 340 469 1079 726 2416 1845 16 -30 -2060 -1116 -634 -641 -492 -1206 -1111 -695 -633 89 601 1665 634 470 422 -925 -817 -1583 900000 -1814 900000 -1610 345 485 -1271 444 -2221 898 -710 375 -167 -760 -1113 377 354 349 -429 -154 -410 667 -433 1246 1049 626 105 -282 -412 -1017 1118 -22 -27 -676 -1163 -733 -1195 1278 -958 819 459 227 -225 -502 537 -251 -39 -548 579 530 27 795 946 588 330 -1046 -1110 -1338 1948 833 2814 1328 1567 975 -654 -708 -1145 344 446 1612 2165 1217 1093 -1297 -2087 -2259 -2685 -1659 -2327 214 -1884 -273 -949 -284 1272 468 3280 716 1236 -13 -1899 -2279 -2116 -1748 -1585 2464 1158 1763 -216 -2360 -1270 -2555 -999 -1686 -2504 -1240 7 2290 3220 4039 1917 1177 -957 -2796 -1453 -1763 519 753 1768 1180 3779 2827 24 -43 -2940 -1559 -931 -1026 -843 -2181 -2066 -1330 -1267 186 1285 3585 1390 1022 890 -1894 -1617 SS 20220310T140752.0Z 8104.588797 142 1 32.27 2 70.21 115.43 106.85 29.70 0.00 1 0.00 1 0 25 1.236e-01 1.407e-02 1.128e-01 4.163e-03 4.721169e-01 2.145497e-03 6.160931e-03 -6.000000e+00 7.066880e-02 225.70 -2.00 3.54 -2.00 320.02 0.00e+00 4.071553e-03 6.794297e-04 3.507045e-03 -6.000000e+00 3.029862e-03 274.52 -2.00 20.00 -2.00 319.51 0.00e+00 2.922 0.000 302.00 328.00 3 3.9625e+00 6.1581e-03 3.9550e-02 -6.0000e+00 1.7531e-01 -6.1819e-02 7.4787e-03 2.8940e-02 -6.0000e+00 1.9030e-01 3.1599e-02 6.8475e-03 1.7724e-02 -6.0000e+00 1.1293e-01 -2.3052e-02 3.5724e-03 6.9408e-03 -6.0000e+00 4.8683e-02 3.2821e-04 3.5042e-04 1.1930e-04 9.1038e-05 -6.0000e+00 3.3477e-03 1.2914e-03 0.0000e+00 12 9 9 12 9 1 99.88 22.91 0.22 0.00129 0.00392 17 5 1 5 0 1782.450 25.68 20.00 22.91 1.45 33.3 1006.89 28345 -9473 27574 -43798 39508 -73873 -25144 43203 -23051 -16921 -55845 7715 -29760 27805 -7991 -14565 4293 -12533 8081 3668 6546 -325 -1449 -7582 -18005 -7468 -8776 -5863 -6814 -9736 1431 -7392 -4453 -3245 -6522 -5578 -9336 -1541 -918 -2116 -283 2113 -1166 2454 695 -669 2243 -505 -472 1442 2672 3683 3840 2385 2492 1354 -550 -2707 -4 -2171 1803 2288 3809 4110 341 1877 -2183 -171 454 1186 3721 1838 3268 436 -1165 -4406 -4974 -3614 -3467 -3370 -2069 -2408 -2318 -751 -195 894 1811 1793 2154 1276 126 -2217 -1552 -2703 -2543 -811 1335 1609 514 -23 -2296 -2280 -1623 -1544 -1538 -910 -114 499 1457 2309 1954 1386 330 -643 -1354 -936 -538 -186 964 895 1092 2602 1187 354 -717 -2290 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