File name: Pandora167s1_KenoshaWI_20240712_L2Fit_fout2c10d20240614p1-8.txt File generation date: 20241125T084006.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v3d20221026.txt Instrument calibration file used: Pandora167s1_CF_v10d20240614.txt Level 1 file used: Pandora167s1_KenoshaWI_20240712_L1_smca1c10d20240614p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20240712 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 225 367 Nominal wavelengths inside fitting window [nm]: 305.0255 305.1663 305.3072 305.4480 305.5888 305.7296 305.8703 306.0111 306.1518 306.2926 306.4333 306.5740 306.7147 306.8554 306.9961 307.1368 307.2775 307.4181 307.5587 307.6994 307.8400 307.9806 308.1212 308.2618 308.4023 308.5429 308.6834 308.8240 308.9645 309.1050 309.2455 309.3860 309.5265 309.6670 309.8074 309.9479 310.0883 310.2287 310.3692 310.5096 310.6500 310.7903 310.9307 311.0711 311.2114 311.3517 311.4921 311.6324 311.7727 311.9130 312.0532 312.1935 312.3338 312.4740 312.6142 312.7545 312.8947 313.0349 313.1751 313.3152 313.4554 313.5956 313.7357 313.8758 314.0159 314.1561 314.2962 314.4362 314.5763 314.7164 314.8564 314.9965 315.1365 315.2765 315.4165 315.5565 315.6965 315.8365 315.9764 316.1164 316.2563 316.3962 316.5362 316.6761 316.8160 316.9558 317.0957 317.2356 317.3754 317.5153 317.6551 317.7949 317.9347 318.0745 318.2143 318.3540 318.4938 318.6335 318.7733 318.9130 319.0527 319.1924 319.3321 319.4718 319.6114 319.7511 319.8907 320.0304 320.1700 320.3096 320.4492 320.5888 320.7284 320.8679 321.0075 321.1470 321.2865 321.4261 321.5656 321.7051 321.8445 321.9840 322.1235 322.2629 322.4024 322.5418 322.6812 322.8206 322.9600 323.0994 323.2388 323.3781 323.5175 323.6568 323.7961 323.9354 324.0747 324.2140 324.3533 324.4926 324.6318 324.7711 324.9103 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20240712T111605.2Z 8959.469505 120 1 51.61 2 82.53 67.10 138.86 11.65 0.00 1 0.00 1 0 33 9.435e-01 4.208e-02 3.842e-01 1.419e-02 8.167288e-01 8.466427e-03 1.121666e-02 -6.000000e+00 5.766788e-01 232.93 -2.00 3.54 -2.00 322.02 0.00e+00 5.647105e-03 4.997679e-03 1.611269e-02 -6.000000e+00 3.194867e-02 287.45 -2.00 20.00 -2.00 321.50 0.00e+00 7.118 0.007 302.00 328.00 3 2.6623e+00 3.3975e-02 1.1822e-01 -6.0000e+00 1.4817e+00 8.5043e-01 4.5645e-02 1.1581e-01 -6.0000e+00 1.6277e+00 -1.2481e+00 3.9034e-02 4.4792e-02 -6.0000e+00 9.2603e-01 4.8752e-01 1.8033e-02 7.1804e-03 -6.0000e+00 3.8819e-01 1.5388e-05 -6.1561e-05 4.0217e-04 2.8966e-04 -6.0000e+00 2.7132e-02 4.5113e-04 0.0000e+00 12 9 8 11 32 0 -32.11 19.85 0.73 0.00045 -0.00001 14 3 1 5 0 3685.730 22.80 14.99 19.85 24.96 54.10 33.3 999.26 900000 900000 25017 -95817 -34460 900000 19072 900000 900000 900000 900000 -149055 900000 900000 900000 -123088 550397 900000 72690 900000 -54910 43818 132847 -52371 125727 -20894 900000 900000 -16822 83661 900000 900000 900000 900000 900000 244057 243861 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7320 5466 6019 3210 -1457 1653 197 1456 5351 791 -15135 6020 -276 6573 2086 5499 1493 549 313 -2994 135 -6652 2118 -3899 -2414 -3859 2526 3980 -3239 -6621 -3910 -1281 -1508 -4951 -5783 -1557 145 -203 333 2930 -252 -8446 -2273 -2462 -1788 2383 -164 4633 3767 3473 10570 4090 2643 524 -4642 2240 1619 -3040 1820 -2890 332 -2873 1485 2323 1351 4937 2770 -1752 -1691 1183 -9658 SU 20240712T111930.1Z 8959.471876 123 1 50.13 2 81.95 67.65 138.75 12.88 0.00 1 0.00 1 0 25 5.607e-01 2.754e-02 3.143e-01 9.734e-03 8.220700e-01 5.808736e-03 1.178657e-02 -6.000000e+00 3.391699e-01 232.93 -2.00 3.54 -2.00 321.93 0.00e+00 -2.414979e-03 3.475970e-03 1.932991e-02 -6.000000e+00 1.760806e-02 287.45 -2.00 20.00 -2.00 321.42 0.00e+00 6.674 0.006 302.00 328.00 3 2.6432e+00 2.3402e-02 1.3435e-01 -6.0000e+00 8.6337e-01 2.7687e-01 3.5917e-02 1.5655e-01 -6.0000e+00 9.4442e-01 -5.8761e-01 3.6476e-02 5.9775e-02 -6.0000e+00 5.4208e-01 2.4174e-01 1.6214e-02 8.0695e-03 -6.0000e+00 2.3139e-01 2.7448e-05 1.1136e-03 2.7474e-04 2.4744e-04 -6.0000e+00 1.6147e-02 1.2509e-03 0.0000e+00 12 9 8 11 8 0 39.58 19.85 0.81 0.00125 0.00962 21 4 1 5 0 2386.710 22.80 15.00 19.85 25.04 52.10 33.3 999.21 900000 900000 -238116 900000 900000 900000 -64800 900000 900000 900000 -131400 -241155 900000 900000 900000 189364 41295 -87245 -88737 900000 -109674 -129963 900000 -137593 -31608 -149243 900000 117037 -70740 -119 900000 900000 900000 -51544 900000 900000 103000 120626 7171 65384 47590 41540 88072 45184 74462 -16671 53253 123952 -5900 19910 53547 26485 21365 44651 -5119 62233 28059 652 20194 14320 -14151 24163 41704 29446 18271 17154 -6597 19114 18550 -9439 7737 7495 20930 3903 8552 8708 -454 16370 -4048 2000 5325 -3593 -20653 4705 -1692 7473 104 6849 5245 2950 -698 -7347 -2343 -9151 2110 1310 -1995 -627 2701 1219 -354 -5813 -6074 -2486 -3296 -1949 -3588 18 1811 100 8 2608 -547 -3700 -671 -2257 572 1069 1621 1959 1179 2317 4745 3698 -902 1124 -2566 451 -61 -1822 111 -2666 -625 -824 -328 829 857 1596 1585 305 -485 -2044 -1299 900000 900000 -3565 900000 900000 900000 -613 900000 900000 900000 -1242 -5700 900000 900000 900000 1790 390 -1500 -1678 900000 -2734 -3584 900000 -4770 -462 -6938 900000 1107 -1520 -1 900000 900000 900000 -1861 900000 900000 974 1141 216 1349 1350 1357 1893 1515 1856 -1046 1694 2024 -375 1061 2301 1707 1616 2955 -553 3959 2629 74 1979 1309 -1728 2389 3979 3364 2548 2419 -1175 2756 2996 -2365 1835 1884 4585 956 1819 1647 -87 2709 -928 523 1615 -1393 -9854 1869 -767 3310 53 3343 2609 1457 -335 -3553 -1048 -4566 1071 794 -1473 -533 2493 1174 -329 -5124 -4807 -1866 -2688 -1676 -3312 18 1894 113 10 3604 -805 -5553 -938 -3087 763 1489 2389 3011 1810 3363 6442 4938 -1222 1448 -3312 586 -91 -3020 202 -5452 -1335 -1775 -759 2017 2140 4023 4006 753 -1126 -4479 -2871 SU 20240712T112247.8Z 8959.474164 126 1 49.73 2 81.39 68.17 138.62 14.07 0.00 1 0.00 1 0 25 4.974e-01 2.736e-02 2.353e-01 7.366e-03 7.878840e-01 4.079029e-03 1.190016e-02 -6.000000e+00 2.887773e-01 232.93 -2.00 3.54 -2.00 321.67 0.00e+00 -4.456263e-03 2.215100e-03 1.943855e-02 -6.000000e+00 1.272455e-02 287.45 -2.00 20.00 -2.00 321.12 0.00e+00 6.292 0.005 302.00 328.00 3 2.4827e+00 1.5332e-02 1.3379e-01 -6.0000e+00 7.2674e-01 3.8443e-01 2.0955e-02 1.5671e-01 -6.0000e+00 7.8493e-01 -7.4526e-01 1.8728e-02 4.6481e-02 -6.0000e+00 4.6520e-01 3.0746e-01 8.6753e-03 1.3184e-02 -6.0000e+00 1.9849e-01 4.6833e-05 1.1686e-03 1.9462e-04 1.8302e-04 -6.0000e+00 1.3120e-02 -6.3627e-04 0.0000e+00 12 8 8 10 0 0 17.04 19.85 0.36 -0.00064 0.00814 29 6 1 5 0 1714.630 22.80 15.00 19.85 25.13 55.10 33.4 999.19 -86695 900000 -158721 -10762 -129758 -180905 -99169 900000 -138429 109821 -148196 -149585 -174763 -50112 182401 -67105 -44204 -65703 -30034 19080 -31182 -107927 -53146 -55607 -58313 -27965 25622 -27534 -53224 -62114 49079 -16521 133900 -49314 37382 -19437 -23594 66515 -25184 -2672 32523 61976 32679 36144 30563 9200 11482 43180 -249 29986 44492 7601 21504 28540 6821 51516 27601 29576 28653 -5683 4542 5948 30399 28497 23726 18020 1686 12120 10074 -3058 14834 10226 16606 7665 9439 144 -7528 555 -8208 -2344 -2700 -706 -12915 3447 -243 5131 1952 4147 3823 1579 -214 -4104 -5553 -8798 -2020 -4223 -2979 -1035 211 1641 -1766 -7105 -7218 -4581 -2068 -1800 -4019 -426 523 2041 924 2461 777 -2138 -1169 -2608 -392 550 1785 3175 1701 2328 3570 2997 391 968 -1637 -812 272 -1026 295 -1143 -474 -1086 -182 516 283 1607 849 847 -233 -1655 -2154 -778 900000 -3514 -77 -1786 -3897 -1101 900000 -2734 789 -3636 -4028 -7321 -818 1310 -1727 -1005 -2005 -683 299 -746 -5425 -1590 -1897 -2268 -853 502 -791 -1847 -2416 801 -573 1311 -3010 1001 -803 -1087 1607 -1733 -179 1752 2670 1956 2098 1847 688 845 2377 -22 2117 3035 851 2316 3143 927 5117 3354 3529 3584 -882 635 884 4030 4408 4168 3325 361 2430 2282 -922 4195 3197 4853 2312 2544 38 -1971 135 -2439 -790 -1011 -302 -6989 1696 -133 2843 1179 2538 2353 964 -125 -2334 -3102 -5253 -1275 -3206 -2446 -970 219 1720 -1820 -6953 -6348 -3864 -1835 -1703 -4102 -452 606 2495 1299 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