File name: Pandora167s1_KenoshaWI_20240813_L2Fit_fout2c10d20240614p1-8.txt File generation date: 20241125T085501.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v3d20221026.txt Instrument calibration file used: Pandora167s1_CF_v10d20240614.txt Level 1 file used: Pandora167s1_KenoshaWI_20240813_L1_smca1c10d20240614p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20240813 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 225 367 Nominal wavelengths inside fitting window [nm]: 305.0255 305.1663 305.3072 305.4480 305.5888 305.7296 305.8703 306.0111 306.1518 306.2926 306.4333 306.5740 306.7147 306.8554 306.9961 307.1368 307.2775 307.4181 307.5587 307.6994 307.8400 307.9806 308.1212 308.2618 308.4023 308.5429 308.6834 308.8240 308.9645 309.1050 309.2455 309.3860 309.5265 309.6670 309.8074 309.9479 310.0883 310.2287 310.3692 310.5096 310.6500 310.7903 310.9307 311.0711 311.2114 311.3517 311.4921 311.6324 311.7727 311.9130 312.0532 312.1935 312.3338 312.4740 312.6142 312.7545 312.8947 313.0349 313.1751 313.3152 313.4554 313.5956 313.7357 313.8758 314.0159 314.1561 314.2962 314.4362 314.5763 314.7164 314.8564 314.9965 315.1365 315.2765 315.4165 315.5565 315.6965 315.8365 315.9764 316.1164 316.2563 316.3962 316.5362 316.6761 316.8160 316.9558 317.0957 317.2356 317.3754 317.5153 317.6551 317.7949 317.9347 318.0745 318.2143 318.3540 318.4938 318.6335 318.7733 318.9130 319.0527 319.1924 319.3321 319.4718 319.6114 319.7511 319.8907 320.0304 320.1700 320.3096 320.4492 320.5888 320.7284 320.8679 321.0075 321.1470 321.2865 321.4261 321.5656 321.7051 321.8445 321.9840 322.1235 322.2629 322.4024 322.5418 322.6812 322.8206 322.9600 323.0994 323.2388 323.3781 323.5175 323.6568 323.7961 323.9354 324.0747 324.2140 324.3533 324.4926 324.6318 324.7711 324.9103 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240813T114214.7Z 8991.487671 100 1 50.09 2 82.80 77.01 161.09 338.40 0.00 1 0.00 1 0 25 4.015e-01 3.444e-02 2.595e-01 1.191e-02 7.809066e-01 6.567192e-03 9.862532e-03 -6.000000e+00 2.307931e-01 231.85 -2.00 3.54 -2.00 321.86 0.00e+00 -1.200718e-02 3.297074e-03 1.590841e-02 -6.000000e+00 1.023417e-02 288.29 -2.00 20.00 -2.00 321.29 0.00e+00 7.346 0.007 302.00 328.00 3 2.1972e+00 2.4291e-02 1.3071e-01 -6.0000e+00 5.7839e-01 7.6392e-01 3.1544e-02 1.5128e-01 -6.0000e+00 6.2460e-01 -1.2964e+00 2.3219e-02 4.3905e-02 -6.0000e+00 3.7205e-01 5.3190e-01 1.1015e-02 1.5843e-02 -6.0000e+00 1.5911e-01 2.3977e-05 4.3240e-04 3.2238e-04 6.6774e-05 -6.0000e+00 1.0400e-02 -4.4878e-03 0.0000e+00 12 8 8 10 0 0 -50.50 19.83 0.65 -0.00449 -0.00124 22 4 1 5 0 2276.470 22.80 15.00 19.83 24.10 52.10 34.7 999.59 -7265 53391 107710 65168 -77459 80751 -119223 -16506 -38641 -21600 -84849 -106390 -51321 118346 73951 -42309 -8883 -27011 -42455 191860 12994 10478 -37070 -76068 8683 18619 -30925 8711 -57321 -29078 22863 57601 81594 -12917 95502 29255 11216 33133 21597 51828 30423 69766 26309 75869 21024 13782 31595 42303 4174 43173 58913 33004 77476 37269 42159 58900 42074 29212 63260 7887 -6158 23767 49217 37519 30631 34471 -3344 21235 18514 -7372 23304 15387 24216 6730 8039 2981 -12195 4446 -9080 -2564 -5445 2398 -5404 7323 -178 8388 -1209 6091 3832 3193 3467 -7246 -4398 -14994 255 -4003 -3960 -2786 -2819 107 -5598 -9445 -6080 -3567 -6595 -2920 -5175 43 483 -502 -814 1175 1828 -3296 -946 -1458 -402 1969 1413 2447 2033 3532 6538 4556 1722 923 -206 768 218 -701 846 -1737 776 -1234 -463 592 240 1910 989 -74 -417 -1707 -3164 -184 789 1251 757 -3108 938 -6798 -383 -1265 -639 -4748 -7526 -2330 1375 1374 -2546 -403 -1512 -2824 2228 480 414 -2153 -7229 394 887 -2155 405 -4116 -1504 850 1739 2180 -859 2218 1223 586 1616 1455 3130 2345 4214 2250 4230 1754 1193 2459 2948 397 3209 4105 3335 5489 3896 4496 6157 4931 3886 6245 1149 -1001 3011 5945 5229 4916 5241 -724 3700 3636 -2180 5684 4289 6162 1926 2063 711 -3090 948 -2435 -766 -1989 942 -2579 3301 -85 3929 -659 3195 2062 1678 1860 -3724 -2317 -8286 136 -2611 -3021 -2437 -2773 105 -5591 -8876 -4972 -2793 -5745 -2634 -5044 43 527 -632 -1082 1682 2691 -5065 -1366 -2034 -555 2776 2135 3858 3223 5318 9183 6370 2405 1264 -298 1130 338 -1275 1703 -3622 1679 -2921 -1175 1587 665 5296 2783 -203 -1078 -4159 -7427 SS 20240813T115317.4Z 8991.495340 103 1 50.52 2 80.81 78.82 161.72 345.65 0.00 1 0.00 1 0 25 5.606e-01 1.952e-02 2.111e-01 3.987e-03 7.141523e-01 2.173183e-03 1.127671e-02 -6.000000e+00 3.222713e-01 231.85 -2.00 3.54 -2.00 321.40 0.00e+00 -6.218163e-04 1.134330e-03 1.585603e-02 -6.000000e+00 1.449502e-02 288.29 -2.00 20.00 -2.00 320.81 0.00e+00 5.943 0.004 302.00 328.00 3 1.9402e+00 7.8630e-03 1.1059e-01 -6.0000e+00 8.0771e-01 1.4708e-02 1.1057e-02 1.2082e-01 -6.0000e+00 8.7224e-01 -2.3390e-01 1.0854e-02 3.4501e-02 -6.0000e+00 5.1989e-01 1.0011e-01 5.0770e-03 1.1723e-02 -6.0000e+00 2.2288e-01 1.2668e-04 2.6488e-04 1.0670e-04 1.6426e-04 -6.0000e+00 1.4689e-02 -3.7799e-03 0.0000e+00 12 8 8 10 0 0 23.75 19.83 0.44 -0.00378 -0.00179 64 12 1 5 0 789.160 22.80 15.00 19.83 25.07 52.40 34.4 999.50 -190877 -135468 -197977 900000 -230941 69531 -242329 52394 -200644 -110682 -104713 -156362 -109872 -90701 167223 -60781 -114645 18175 -104715 55368 -68188 -97503 -37871 -103388 -11235 -47540 126 -27758 -50132 -57845 -42194 25187 8738 -29737 -10319 11788 -26478 1155 -2714 -10051 14247 1084 8882 13505 3732 14450 6455 21075 -1919 11919 10935 11021 22873 6262 -1204 13016 11410 7306 6156 4631 -3036 8626 12355 11458 9379 4093 3332 723 7245 337 6439 3763 6036 4815 -226 -1084 -8482 -6284 -5347 -2383 -1233 -2020 -1473 -1265 -921 1511 1341 3599 2908 2225 239 -2874 -3907 -5990 -1796 -2563 -932 428 1040 91 -2561 -3537 -4999 -1783 -2277 -2295 -1824 -154 1479 1837 2474 2268 1165 -393 -1388 -1436 -886 304 808 1562 2002 2221 3255 1197 881 -471 -2591 -1394 -992 -432 -394 -1665 -1625 -985 -352 443 704 1665 1422 339 74 -995 -1470 -1551 -766 -2309 900000 -3428 270 -4196 204 -3120 -860 -814 -2044 -1239 -1093 650 -773 -2876 148 -2923 366 -1470 -2825 -692 -3690 -197 -1176 2 -626 -1240 -1615 -1193 490 238 -1208 -339 330 -1067 42 -129 -632 816 77 621 931 286 1016 504 1475 -178 1036 1074 1235 2538 830 -186 1847 1726 1167 969 719 -514 1414 2233 2401 2190 1005 809 186 1915 103 2097 1340 2115 1631 -74 -348 -2698 -1952 -1817 -869 -530 -1017 -827 -760 -591 1016 890 2432 1996 1500 166 -1933 -2543 -4051 -1206 -2028 -848 445 1127 102 -2830 -3567 -4930 -1670 -2306 -2492 -1939 -172 1785 2498 3539 3531 1878 -632 -2148 -2123 -1297 460 1294 2619 3355 3584 4992 1821 1299 -681 -3681 -1993 -1591 -746 -759 -3510 -3417 -2193 -839 1058 1726 4121 3557 833 172 -2305 -3262 SS 20240813T120414.9Z 8991.502951 108 1 50.47 2 78.83 80.60 162.09 353.20 0.00 1 0.00 1 0 25 3.990e-01 1.750e-02 6.680e-02 1.943e-03 6.180508e-01 1.027393e-03 9.458068e-03 -6.000000e+00 2.293497e-01 231.85 -2.00 3.54 -2.00 320.76 0.00e+00 6.383060e-04 4.413906e-04 9.772471e-03 -6.000000e+00 1.017027e-02 288.29 -2.00 20.00 -2.00 320.11 0.00e+00 4.979 0.002 302.00 328.00 3 1.7074e+00 3.3119e-03 7.6025e-02 -6.0000e+00 5.7477e-01 -1.1193e-01 4.3716e-03 7.2364e-02 -6.0000e+00 6.2070e-01 -1.2841e-02 4.1882e-03 2.2555e-02 -6.0000e+00 3.6972e-01 2.5756e-03 2.0582e-03 7.5997e-03 -6.0000e+00 1.5811e-01 4.2415e-04 3.2177e-04 5.2011e-05 9.8426e-05 -6.0000e+00 1.0336e-02 -4.3260e-03 0.0000e+00 12 9 8 11 8 0 0.08 19.84 0.28 -0.00433 -0.00191 129 25 1 5 0 391.170 22.80 14.99 19.84 25.60 53.60 34.9 999.69 -114625 -102946 -158989 -96067 -161742 -123184 -173332 -88397 -107419 -115372 -83463 -144479 -73472 -66341 -19697 -36519 -57980 -4347 -43501 8398 -33150 -34660 -16655 -46309 -16218 -25953 -2998 -23234 -21649 -29341 -15336 -4815 -10288 -9790 -11770 -9868 -14168 -8146 -980 -4133 7394 5191 5945 6617 2581 6385 -613 3105 -1297 3755 5218 1599 6902 2108 5928 4099 5132 3588 2281 677 -2914 4067 6235 7816 5588 403 -1227 -2815 1019 995 4419 3510 2324 2651 -626 -2213 -5762 -6507 -5331 -4448 -2602 -1966 -1603 -2398 -584 940 1832 2737 2887 2232 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