File name: Pandora167s1_KenoshaWI_20240915_L2Fit_fout2c10d20240614p1-8.txt File generation date: 20241125T091236.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v3d20221026.txt Instrument calibration file used: Pandora167s1_CF_v10d20240614.txt Level 1 file used: Pandora167s1_KenoshaWI_20240915_L1_smca1c10d20240614p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20240915 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 225 367 Nominal wavelengths inside fitting window [nm]: 305.0255 305.1663 305.3072 305.4480 305.5888 305.7296 305.8703 306.0111 306.1518 306.2926 306.4333 306.5740 306.7147 306.8554 306.9961 307.1368 307.2775 307.4181 307.5587 307.6994 307.8400 307.9806 308.1212 308.2618 308.4023 308.5429 308.6834 308.8240 308.9645 309.1050 309.2455 309.3860 309.5265 309.6670 309.8074 309.9479 310.0883 310.2287 310.3692 310.5096 310.6500 310.7903 310.9307 311.0711 311.2114 311.3517 311.4921 311.6324 311.7727 311.9130 312.0532 312.1935 312.3338 312.4740 312.6142 312.7545 312.8947 313.0349 313.1751 313.3152 313.4554 313.5956 313.7357 313.8758 314.0159 314.1561 314.2962 314.4362 314.5763 314.7164 314.8564 314.9965 315.1365 315.2765 315.4165 315.5565 315.6965 315.8365 315.9764 316.1164 316.2563 316.3962 316.5362 316.6761 316.8160 316.9558 317.0957 317.2356 317.3754 317.5153 317.6551 317.7949 317.9347 318.0745 318.2143 318.3540 318.4938 318.6335 318.7733 318.9130 319.0527 319.1924 319.3321 319.4718 319.6114 319.7511 319.8907 320.0304 320.1700 320.3096 320.4492 320.5888 320.7284 320.8679 321.0075 321.1470 321.2865 321.4261 321.5656 321.7051 321.8445 321.9840 322.1235 322.2629 322.4024 322.5418 322.6812 322.8206 322.9600 323.0994 323.2388 323.3781 323.5175 323.6568 323.7961 323.9354 324.0747 324.2140 324.3533 324.4926 324.6318 324.7711 324.9103 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240915T122536.5Z 9024.517784 178 1 50.63 2 80.93 94.67 135.02 285.05 0.00 1 0.00 1 0 25 4.239e-01 2.987e-02 1.749e-01 8.571e-03 6.385319e-01 4.629372e-03 1.045136e-02 -6.000000e+00 2.438681e-01 228.99 -2.00 3.54 -2.00 321.29 0.00e+00 1.358349e-03 2.186601e-03 1.423684e-02 -6.000000e+00 1.119521e-02 285.71 -2.00 20.00 -2.00 320.69 0.00e+00 6.011 0.004 302.00 328.00 3 3.2281e+00 1.5925e-02 1.0107e-01 -6.0000e+00 6.0738e-01 2.7508e-01 2.0642e-02 1.0568e-01 -6.0000e+00 6.5840e-01 -5.8467e-01 1.7497e-02 3.2824e-02 -6.0000e+00 3.9052e-01 2.5423e-01 8.3826e-03 7.8968e-03 -6.0000e+00 1.6821e-01 3.3974e-05 -6.1107e-04 2.4196e-04 1.5633e-04 -6.0000e+00 1.1322e-02 -1.0652e-03 0.0000e+00 12 8 8 10 0 0 53.10 20.08 1.10 -0.00107 -0.00566 17 3 1 5 0 2977.330 23.01 14.99 20.08 28.42 57.40 36.5 1001.12 -76434 900000 -153754 900000 -142542 900000 -185634 900000 -109182 -84932 -126086 -145417 89024 -36649 900000 -37079 5296 2247 -46479 105820 -77114 -27784 -1073 -40599 -42483 -39168 51471 -21011 -34333 -46445 9727 45680 95885 35323 79676 91342 5437 32608 627 20054 69729 31078 23025 45576 33590 19683 29818 36726 -1540 57949 20703 16142 43278 8444 22093 33212 25294 4402 25473 4662 8387 8730 28752 19959 9677 11469 3279 9432 13933 -5080 8068 2790 10655 3018 -3040 8778 -9540 994 -10329 598 -5086 -5172 -3318 3454 -4613 2836 -3728 3434 3878 2350 -1019 -4244 -4193 -8525 -1185 -5373 -1673 -4091 560 30 -1432 -5048 -4333 -202 -4492 -2824 -5268 -1205 2213 -457 1405 2424 936 -2108 -1434 -2158 567 2092 1267 3545 1680 3166 3854 3512 1212 584 -761 -362 327 -1345 1178 -1018 -713 -1449 113 270 375 1473 1177 -726 -347 -1165 -1969 -1277 900000 -6815 900000 -4762 900000 -8944 900000 -3016 -1964 -4455 -6539 743 -824 900000 -1215 126 59 -2120 1178 -5003 -1071 -32 -1904 -2183 -2038 1182 -877 -1544 -2387 352 1367 2002 1475 2052 1971 291 1543 46 1456 3785 2456 2056 3308 2740 1859 2567 2996 -190 4477 2341 2136 4782 1432 3477 4864 4143 891 4042 880 1536 1716 5227 4487 2599 2977 891 2436 3714 -1896 2970 1065 4066 1187 -1170 2684 -3199 295 -3729 229 -2263 -2656 -1864 1935 -2989 1832 -2729 2436 2764 1661 -700 -2807 -2631 -5609 -798 -4375 -1526 -4118 602 33 -1546 -5127 -4229 -186 -4339 -2882 -5807 -1364 2635 -627 1990 3671 1466 -3325 -2132 -3075 833 2964 1930 5597 2733 4929 5743 5107 1855 869 -1103 -528 496 -2365 2238 -2000 -1467 -3180 262 630 900 3563 2880 -1764 -841 -2670 -4338 SS 20240915T123707.2Z 9024.525778 183 1 50.37 2 78.82 96.65 136.93 287.54 0.00 1 0.00 1 0 25 3.220e-01 1.743e-02 1.057e-01 3.129e-03 5.594077e-01 1.633738e-03 8.555562e-03 -6.000000e+00 1.830858e-01 228.98 -2.00 3.54 -2.00 320.64 0.00e+00 1.143160e-03 6.682875e-04 8.581382e-03 -6.000000e+00 8.117466e-03 285.71 -2.00 20.00 -2.00 319.99 0.00e+00 4.975 0.002 302.00 328.00 3 2.6689e+00 5.1790e-03 7.0502e-02 -6.0000e+00 4.5604e-01 -9.8336e-02 6.6827e-03 6.3600e-02 -6.0000e+00 4.9386e-01 -3.1156e-02 6.1945e-03 2.1876e-02 -6.0000e+00 2.9440e-01 1.0340e-02 3.0705e-03 5.4098e-03 -6.0000e+00 1.2628e-01 1.7562e-04 1.4190e-05 8.6137e-05 1.0306e-04 -6.0000e+00 8.3387e-03 -1.1571e-03 0.0000e+00 12 8 8 10 0 0 83.52 20.08 0.41 -0.00116 -0.00105 54 10 1 5 0 932.510 23.01 15.00 20.08 28.87 56.40 36.9 1001.12 -124337 8887 -103500 -24423 -89236 -129199 -143630 -127424 -96469 -67160 -97581 -89895 -82422 -44550 -26774 -35510 -52982 -31934 613 2195 -17590 -44081 -9804 -23196 -19420 -469 -23051 -4110 -19656 -23539 -3653 -7885 -4637 -17416 3656 -18946 -11763 349 -9692 1650 6345 3581 1680 8510 1619 2533 5029 1430 -1795 1624 1854 3583 7297 6588 3219 7684 3296 1608 2392 -1730 -1049 3705 6797 8070 5125 2392 -2292 -147 1109 293 3166 2696 4704 952 26 -3310 -5658 -5633 -5839 -3134 -2845 -1514 -2870 -1897 -1329 689 1218 2204 3198 2258 833 -1230 -3581 -4609 -3243 -1713 -563 1227 1255 330 -1421 -3652 -3324 -1957 -1504 -1733 -1021 -272 636 2413 2094 2603 1328 -60 -850 -1525 -547 -404 1128 1183 1202 2228 2407 1744 408 -722 -2655 -1226 -1113 -1175 -217 -1816 -1247 -933 -227 409 498 1518 1221 585 69 -925 -991 -1556 35 -1390 -149 -953 -1971 -2717 -2372 -1531 -881 -1816 -1673 -1735 -816 -515 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302.00 328.00 3 2.5322e+00 3.5343e-03 5.9168e-02 -6.0000e+00 3.0118e-01 -1.1633e-01 4.4342e-03 4.6625e-02 -6.0000e+00 3.2617e-01 2.4539e-02 4.0031e-03 1.8305e-02 -6.0000e+00 1.9444e-01 -1.6301e-02 2.0325e-03 4.1127e-03 -6.0000e+00 8.3395e-02 2.9996e-04 -6.0494e-05 6.2619e-05 7.6906e-05 -6.0000e+00 5.5080e-03 -5.0523e-04 0.0000e+00 12 8 8 10 0 0 34.95 20.08 0.24 -0.00051 -0.00096 72 14 1 5 0 701.120 23.01 14.99 20.08 29.08 56.40 36.8 1001.05 -101830 -38848 -35693 -29097 -66086 -79781 -107758 -22902 -68360 37616 -69990 -74074 -53133 -28893 10065 -28270 -16794 -16114 -19314 2088 -16871 -16129 -17322 -9225 -15839 -356 -1524 -2997 -12664 -13387 4607 -7850 7528 -12478 -8216 -5832 -12241 -1490 -6014 -1318 5804 603 5003 633 2325 2124 4342 1284 -2212 1875 -65 2517 2975 2884 2731 4005 2914 -163 1413 -236 -892 1951 5132 7205 3329 1164 -1237 -2126 -223 688 2650 2371 2792 1593 218 -2528 -5021 -6778 -6486 -3505 -3340 -1449 -2473 -1818 -361 477 1851 2724 2956 1991 1026 -778 -3189 -3612 -2814 -1586 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