File name: Pandora167s1_KenoshaWI_20240918_L2Fit_fout2c10d20240614p1-8.txt File generation date: 20241125T091319.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c10p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v3d20221026.txt Instrument calibration file used: Pandora167s1_CF_v10d20240614.txt Level 1 file used: Pandora167s1_KenoshaWI_20240918_L1_smca1c10d20240614p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20240918 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 225 367 Nominal wavelengths inside fitting window [nm]: 305.0255 305.1663 305.3072 305.4480 305.5888 305.7296 305.8703 306.0111 306.1518 306.2926 306.4333 306.5740 306.7147 306.8554 306.9961 307.1368 307.2775 307.4181 307.5587 307.6994 307.8400 307.9806 308.1212 308.2618 308.4023 308.5429 308.6834 308.8240 308.9645 309.1050 309.2455 309.3860 309.5265 309.6670 309.8074 309.9479 310.0883 310.2287 310.3692 310.5096 310.6500 310.7903 310.9307 311.0711 311.2114 311.3517 311.4921 311.6324 311.7727 311.9130 312.0532 312.1935 312.3338 312.4740 312.6142 312.7545 312.8947 313.0349 313.1751 313.3152 313.4554 313.5956 313.7357 313.8758 314.0159 314.1561 314.2962 314.4362 314.5763 314.7164 314.8564 314.9965 315.1365 315.2765 315.4165 315.5565 315.6965 315.8365 315.9764 316.1164 316.2563 316.3962 316.5362 316.6761 316.8160 316.9558 317.0957 317.2356 317.3754 317.5153 317.6551 317.7949 317.9347 318.0745 318.2143 318.3540 318.4938 318.6335 318.7733 318.9130 319.0527 319.1924 319.3321 319.4718 319.6114 319.7511 319.8907 320.0304 320.1700 320.3096 320.4492 320.5888 320.7284 320.8679 321.0075 321.1470 321.2865 321.4261 321.5656 321.7051 321.8445 321.9840 322.1235 322.2629 322.4024 322.5418 322.6812 322.8206 322.9600 323.0994 323.2388 323.3781 323.5175 323.6568 323.7961 323.9354 324.0747 324.2140 324.3533 324.4926 324.6318 324.7711 324.9103 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240918T122829.5Z 9027.519786 281 1 50.22 2 80.99 96.21 94.70 273.84 0.00 1 0.00 1 0 25 4.381e-01 2.428e-02 1.802e-01 5.360e-03 6.429414e-01 2.839185e-03 1.062520e-02 -6.000000e+00 2.487776e-01 228.64 -2.00 3.54 -2.00 321.26 0.00e+00 1.176841e-03 1.371990e-03 1.414810e-02 -6.000000e+00 1.102600e-02 285.34 -2.00 20.00 -2.00 320.68 0.00e+00 6.048 0.004 302.00 328.00 3 2.4326e+00 9.7686e-03 9.9961e-02 -6.0000e+00 6.1924e-01 1.2798e-01 1.3034e-02 1.0413e-01 -6.0000e+00 6.7075e-01 -4.1879e-01 1.1796e-02 3.4948e-02 -6.0000e+00 3.9988e-01 1.8116e-01 5.6091e-03 6.5884e-03 -6.0000e+00 1.7163e-01 7.6286e-05 6.6578e-05 1.4623e-04 1.7085e-04 -6.0000e+00 1.1341e-02 -2.7598e-03 0.0000e+00 12 8 8 10 0 0 40.80 20.08 0.45 -0.00276 -0.00226 40 8 1 5 0 1255.190 23.01 15.00 20.08 21.02 49.90 36.3 996.08 -113135 16664 -176899 -80656 -128691 -17099 -151184 -145812 -122195 -114167 -158060 -166585 -147271 55309 56499 -877 -87759 -51495 -51035 66131 -36993 -60564 5805 -46138 -35139 -30684 1185 11760 -22749 -21604 -24017 5292 10315 -11941 36432 5734 2239 21196 -12602 6719 27710 22798 34998 22238 12778 15173 10449 28386 21311 21972 24822 4421 22652 13586 18834 25611 16543 13643 12022 6117 -4428 5540 17586 19839 10694 3511 1989 4235 4323 1595 4839 7210 6106 -23 -591 -2447 -4178 -8123 -6988 -4585 -5168 -2336 -3258 -1166 -1237 2997 415 3386 2956 1628 618 -3960 -2771 -7796 -2263 -4649 -1568 262 156 -285 -1871 -4488 -5135 -2126 -2294 -2156 -1986 -473 862 1115 2082 2594 863 -819 -1047 -2140 -756 26 1986 1560 1677 2648 4069 2346 1058 478 -3140 -235 -900 -891 -98 -1575 -786 -1275 -139 618 688 1626 1272 374 -223 -1234 -2082 -1505 87 -5632 -958 -2202 -98 -3161 -3257 -2439 -2279 -5033 -6175 -5459 376 473 -14 -3795 -1689 -1795 830 -1213 -2475 124 -1798 -1336 -1181 34 320 -757 -729 -959 189 407 -647 1177 240 103 947 -970 517 1975 1842 2628 1945 1233 1449 1063 2469 2066 2235 2701 609 2862 2048 2880 3827 2811 2401 2090 1095 -891 1093 3493 4382 2795 973 542 1147 1271 560 1853 2641 2273 -9 -225 -849 -1352 -2704 -2511 -1910 -2367 -1202 -1886 -706 -801 2002 302 2491 2206 1203 434 -2715 -1786 -5326 -1617 -3952 -1397 264 176 -333 -2120 -4734 -4929 -1951 -2277 -2294 -2226 -559 1096 1483 3077 4118 1421 -1339 -1629 -3205 -1111 40 3168 2649 2693 4362 6373 3637 1605 706 -4615 -341 -1467 -1556 -188 -3107 -1617 -2798 -324 1440 1651 3946 3128 905 -543 -2853 -4639 SS 20240918T124021.3Z 9027.528024 286 1 50.16 2 78.82 98.26 96.76 275.83 0.00 1 0.00 1 0 25 3.033e-01 1.652e-02 6.723e-02 2.213e-03 5.651644e-01 1.148194e-03 8.441362e-03 -6.000000e+00 1.722424e-01 228.64 -2.00 3.54 -2.00 320.62 0.00e+00 9.355754e-04 4.715556e-04 8.100907e-03 -6.000000e+00 7.634028e-03 285.34 -2.00 20.00 -2.00 319.98 0.00e+00 4.977 0.002 302.00 328.00 3 2.0312e+00 3.6225e-03 6.8927e-02 -6.0000e+00 4.2873e-01 -1.2317e-01 4.6761e-03 5.9931e-02 -6.0000e+00 4.6441e-01 7.6461e-03 4.4288e-03 2.1052e-02 -6.0000e+00 2.7686e-01 -8.1341e-03 2.2033e-03 5.2763e-03 -6.0000e+00 1.1883e-01 3.3107e-04 1.3038e-04 6.0683e-05 9.8496e-05 -6.0000e+00 7.8524e-03 -2.3650e-03 0.0000e+00 12 9 8 11 8 0 8.89 20.08 0.39 -0.00237 -0.00139 100 19 1 5 0 501.540 23.01 15.00 20.08 22.11 50.60 36.7 996.17 -128624 -81621 -97846 -48600 -111164 -97141 -112741 -101030 -80397 -60399 -104494 -93978 -67564 -28075 -31146 -14175 -30324 -32850 -26449 -4921 -20240 -45503 -17666 -18065 -19176 -15763 -15046 -6529 -23003 -18910 -5766 -8950 188 -15625 -5265 -5406 -10436 -2810 -2977 -5680 2555 2896 5563 7270 1424 2989 651 4798 445 1386 4275 2474 4738 3811 2495 4836 3984 1798 1357 -328 -1493 2467 5737 6304 3681 1627 -1408 -2299 938 1192 2297 3211 3215 1676 34 -2359 -4858 -6051 -5861 -4417 -2088 -1982 -2375 -2089 -768 702 1864 2220 2812 2266 548 -797 -3042 -4012 -2933 -1891 -384 1315 1628 466 -1127 -3214 -3729 -2094 -1122 -1724 -978 -405 919 2192 2681 2595 1443 124 -1317 -1449 -1152 -244 969 1398 1316 1812 2116 1181 550 -930 -2553 -1287 -1046 -1157 -761 -1550 -1222 -1065 -248 307 373 1702 1439 441 349 -790 -974 -1471 -705 -1098 -336 -1319 -964 -1411 -1308 -989 -678 -1917 -1683 -1137 -406 -585 -272 -708 -870 -721 -127 -584 -1705 -520 -588 -700 -600 -590 -231 -925 -753 -232 -444 10 -1076 -320 -318 -698 -207 -273 -601 287 353 699 931 196 415 94 684 69 224 737 489 1012 897 638 1268 1015 475 353 -85 -400 690 1759 2175 1400 620 -532 -884 377 556 1110 1637 1655 843 17 -1113 -2148 -2650 -2764 -2242 -1218 -1326 -1770 -1543 -598 581 1620 2003 2549 2017 466 -639 -2350 -3113 -2457 -1801 -389 1502 1937 574 -1343 -3772 -3996 -2185 -1253 -2076 -1229 -507 1226 3210 4089 4232 2402 202 -2052 -2140 -1680 -367 1538 2348 2126 2998 3371 1844 831 -1376 -3889 -1949 -1650 -1956 -1408 -2927 -2403 -2208 -520 683 856 3756 3221 975 769 -1663 -2072 SS 20240918T124617.3Z 9027.532144 289 1 50.13 2 77.74 99.30 97.79 276.84 0.00 1 0.00 1 0 25 2.210e-01 1.648e-02 4.407e-02 1.669e-03 5.261908e-01 8.589652e-04 7.532595e-03 -6.000000e+00 1.255227e-01 228.64 -2.00 3.54 -2.00 320.28 0.00e+00 1.404370e-03 3.132510e-04 6.129803e-03 -6.000000e+00 5.563382e-03 285.34 -2.00 20.00 -2.00 319.61 0.00e+00 4.572 0.002 302.00 328.00 3 1.9408e+00 2.6019e-03 5.9468e-02 -6.0000e+00 3.1244e-01 -1.2964e-01 3.2539e-03 4.6936e-02 -6.0000e+00 3.3844e-01 3.7055e-02 2.9441e-03 1.8231e-02 -6.0000e+00 2.0177e-01 -2.2855e-02 1.4979e-03 4.2084e-03 -6.0000e+00 8.6594e-02 5.4332e-04 1.2125e-04 4.5947e-05 8.0585e-05 -6.0000e+00 5.7227e-03 -2.2394e-03 0.0000e+00 12 8 8 10 0 0 53.92 20.09 0.23 -0.00224 -0.00133 136 26 1 5 0 368.570 23.01 15.00 20.09 22.77 51.40 36.4 996.24 -83189 -84332 -11776 -71899 -37052 -99404 -94243 -66237 -76223 -21357 -77137 -31051 -63402 -30431 -16150 -23669 -15293 -20456 1348 -10829 -4310 -24169 -8127 -7776 -12145 6229 -10980 -4243 -17789 -16247 -3575 -6847 9850 -11028 -8359 -11791 -13487 -1915 -5553 2157 1577 3096 2096 2024 2631 1821 3462 529 824 -1368 1017 2850 2726 4362 1402 3832 2706 889 393 -707 -409 1919 4976 5877 3826 416 -1267 -1030 195 1011 2335 2952 2546 1580 150 -2725 -4711 -6988 -6182 -3777 -3051 -1246 -2751 -1923 -516 510 2116 2626 2933 2025 921 -728 -3441 -3480 -2847 -1508 -306 1519 1413 344 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