File name: Pandora167s1_KenoshaWI_20241110_L2Fit_fout2c3d20221227p1-8.txt File generation date: 20241111T054521.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 167 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora167_OF_v3d20221026.txt Instrument calibration file used: Pandora167s1_CF_v3d20221227.txt Level 1 file used: Pandora167s1_KenoshaWI_20241110_L1_smca1c3d20221227p1-8.txt Full location name: Chiwaukee Prairie WDNR Short location name: KenoshaWI Country of location: United States Location latitude [deg]: 42.5047 Location longitude [deg]: -87.8093 Location altitude [m]: 181 Local noon date: 20241110 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 2 First and last pixel inside fitting window: 225 366 Nominal wavelengths inside fitting window [nm]: 305.1352 305.2760 305.4168 305.5576 305.6984 305.8391 305.9799 306.1206 306.2613 306.4020 306.5427 306.6834 306.8241 306.9647 307.1054 307.2460 307.3867 307.5273 307.6679 307.8085 307.9491 308.0896 308.2302 308.3707 308.5113 308.6518 308.7923 308.9328 309.0733 309.2138 309.3543 309.4947 309.6352 309.7756 309.9160 310.0565 310.1969 310.3373 310.4776 310.6180 310.7584 310.8987 311.0390 311.1794 311.3197 311.4600 311.6003 311.7406 311.8808 312.0211 312.1613 312.3016 312.4418 312.5820 312.7222 312.8624 313.0026 313.1427 313.2829 313.4230 313.5632 313.7033 313.8434 313.9835 314.1236 314.2636 314.4037 314.5438 314.6838 314.8238 314.9639 315.1039 315.2439 315.3838 315.5238 315.6638 315.8037 315.9437 316.0836 316.2235 316.3634 316.5033 316.6432 316.7831 316.9229 317.0628 317.2026 317.3424 317.4823 317.6221 317.7618 317.9016 318.0414 318.1812 318.3209 318.4606 318.6004 318.7401 318.8798 319.0195 319.1591 319.2988 319.4385 319.5781 319.7177 319.8574 319.9970 320.1366 320.2762 320.4157 320.5553 320.6949 320.8344 320.9739 321.1134 321.2530 321.3925 321.5319 321.6714 321.8109 321.9503 322.0898 322.2292 322.3686 322.5080 322.6474 322.7868 322.9262 323.0655 323.2049 323.3442 323.4835 323.6229 323.7622 323.9015 324.0407 324.1800 324.3193 324.4585 324.5977 324.7370 324.8762 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Azimuth motor temperature [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-384: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241110T143448.5Z 9080.607505 150 1 50.35 2 72.86 134.97 144.12 38.60 0.00 1 0.00 1 0 17 3.245e-02 1.642e-02 2.180e-03 3.625e-04 3.608560e-01 1.825521e-04 4.667820e-03 -6.000000e+00 1.832686e-02 223.18 -2.00 3.54 -2.00 318.25 0.00e+00 2.191357e-03 3.415111e-05 1.415408e-03 -6.000000e+00 7.978107e-04 278.70 -2.00 20.00 -2.00 317.65 0.00e+00 3.344 0.001 302.00 328.00 3 2.8398e-01 4.8368e-04 3.7612e-02 -6.0000e+00 4.5185e-02 -2.4358e-02 5.4667e-04 1.9361e-02 -6.0000e+00 4.8916e-02 1.2336e-02 3.7623e-04 9.6461e-03 -6.0000e+00 2.9146e-02 -1.5769e-02 2.0361e-04 2.8081e-03 -6.0000e+00 1.2922e-02 1.0194e-02 -3.3546e-03 9.9113e-06 2.8770e-05 -6.0000e+00 8.3978e-04 -9.0522e-02 1.2003e-04 12 8 8 10 0 0 99.81 20.02 0.21 -0.09052 -0.11573 1007 195 1 5 0 49.890 23.01 14.99 20.02 18.38 44.90 37.5 989.08 1281 2069 1030 -1290 -8918 -8918 -10423 -7899 -6154 -6889 -10783 -12273 -7623 -3340 410 1494 1211 2722 2160 3078 2193 614 1089 985 847 81 -1064 -3568 -5330 -5315 -2795 -1268 502 -1318 -6751 -8577 -7552 -4645 -1126 413 405 379 782 694 1390 1680 1000 460 -922 -1124 488 1462 1627 2173 1552 1674 1377 58 -549 -807 -27 1931 3509 4668 2928 224 -1112 -2639 -652 1523 2020 2553 1910 1796 418 -1844 -3897 -6079 -5214 -3682 -2857 -1768 -2444 -2412 -844 57 1540 1986 2628 2278 1119 -318 -2624 -3070 -2664 -1601 -354 1544 1671 730 -357 -2200 -2781 -1764 -1279 -1579 -903 -559 399 1788 2311 2337 1770 869 -324 -1193 -949 -586 751 1373 1289 1728 1696 1164 633 -466 -2155 -1466 -1128 -1007 -703 -1386 -1318 -967 -376 183 333 1368 1005 479 74 -1021 57 106 57 -72 -486 -450 -553 -458 -399 -448 -740 -873 -592 -300 43 178 158 371 315 467 322 91 162 156 144 15 -199 -662 -950 -934 -516 -260 114 -329 -1717 -2099 -1930 -1239 -352 152 158 158 339 309 620 756 454 209 -423 -523 237 719 861 1221 921 1021 815 35 -327 -475 -16 1205 2385 3258 2180 164 -766 -1892 -477 1175 1650 2203 1681 1535 340 -1466 -2846 -4527 -3741 -2953 -2476 -1621 -2467 -2441 -893 61 1741 2332 3105 2645 1234 -342 -2655 -3130 -2700 -1791 -421 1938 2204 992 -466 -2791 -3404 -2120 -1582 -2016 -1199 -779 559 2671 3568 3637 2745 1343 -487 -1687 -1308 -832 1122 2103 2042 2703 2580 1725 937 -667 -3106 -2061 -1624 -1530 -1105 -2296 -2237 -1638 -672 335 607 2524 1890 893 138 -1837 SS 20241110T143927.9Z 9080.610740 153 1 50.40 2 72.26 135.95 143.58 40.21 0.00 1 0.00 1 0 17 3.123e-02 1.646e-02 1.641e-03 3.116e-04 3.517641e-01 1.570401e-04 4.538360e-03 -6.000000e+00 1.763418e-02 223.18 -2.00 3.54 -2.00 318.04 0.00e+00 2.069816e-03 2.746332e-05 1.246950e-03 -6.000000e+00 7.676831e-04 278.70 -2.00 20.00 -2.00 317.44 0.00e+00 3.238 0.001 302.00 328.00 3 1.2140e-01 4.1474e-04 3.6419e-02 -6.0000e+00 4.3477e-02 -2.1113e-02 4.6678e-04 1.8667e-02 -6.0000e+00 4.7070e-02 8.3846e-03 3.1246e-04 9.2800e-03 -6.0000e+00 2.8046e-02 -1.3804e-02 1.6813e-04 2.6964e-03 -6.0000e+00 1.2431e-02 1.3403e-02 -3.6575e-03 8.5439e-06 2.7220e-05 -6.0000e+00 8.0828e-04 -9.0199e-02 7.1697e-05 12 8 8 10 0 0 40.07 20.02 0.23 -0.09020 -0.11768 1116 216 1 5 0 45.030 23.01 15.00 20.02 18.82 44.40 37.4 989.12 -37 1823 2012 -3287 -6983 -10255 -8641 -7001 -5128 -6188 -11493 -11387 -7152 -2848 480 1421 808 1656 2579 2750 2718 812 1138 1543 627 477 -946 -2924 -5065 -4715 -2046 -1393 923 -1263 -6440 -8541 -7629 -4560 -1314 747 493 622 889 669 1360 1565 997 369 -720 -1125 500 1386 1390 2306 1447 1774 1448 129 -503 -872 114 1893 3437 4610 2906 231 -1239 -2478 -520 1655 1949 2536 1861 1681 465 -1857 -3752 -6125 -5265 -3577 -2899 -1692 -2549 -2390 -894 29 1451 1825 2590 2223 1114 -194 -2611 -2984 -2701 -1605 -387 1557 1688 729 -320 -2157 -2735 -1800 -1301 -1580 -856 -570 397 1781 2309 2372 1811 932 -323 -1174 -895 -585 779 1365 1338 1738 1701 1187 623 -425 -2120 -1439 -1115 -1057 -635 -1374 -1237 -976 -395 177 244 1344 933 498 79 -1057 -2 109 129 -218 -431 -606 -519 -464 -379 -460 -912 -919 -631 -289 56 191 119 256 420 468 444 135 189 271 119 96 -197 -599 -999 -911 -413 -314 227 -344 -1784 -2281 -2129 -1325 -448 279 209 280 418 323 657 763 490 181 -355 -563 244 730 789 1382 864 1085 913 83 -319 -547 72 1258 2348 3419 2175 179 -903 -1767 -378 1272 1677 2188 1638 1439 398 -1474 -2881 -4530 -3965 -2842 -2498 -1620 -2561 -2523 -943 33 1638 2142 3056 2579 1282 -208 -2752 -3011 -2843 -1777 -456 1937 2210 983 -415 -2711 -3311 -2142 -1596 -2088 -1130 -789 553 2641 3540 3665 2786 1425 -481 -1639 -1265 -819 1147 2066 2097 2692 2563 1809 910 -601 -3012 -1994 -1581 -1584 -1019 -2241 -2064 -1627 -694 317 439 2447 1732 917 146 -1878 SS 20241110T144514.1Z 9080.614747 156 1 50.60 2 71.53 137.18 142.89 42.14 0.00 1 0.00 1 0 17 2.995e-02 1.658e-02 1.323e-03 2.826e-04 3.403940e-01 1.423301e-04 4.373623e-03 -6.000000e+00 1.691731e-02 223.18 -2.00 3.54 -2.00 317.87 0.00e+00 2.035044e-03 2.372543e-05 1.117481e-03 -6.000000e+00 7.364618e-04 278.70 -2.00 20.00 -2.00 317.27 0.00e+00 3.117 0.001 302.00 328.00 3 6.5324e-02 3.7426e-04 3.5048e-02 -6.0000e+00 4.1710e-02 -1.8969e-02 4.2070e-04 1.7862e-02 -6.0000e+00 4.5155e-02 6.1200e-03 2.7541e-04 8.9032e-03 -6.0000e+00 2.6905e-02 -1.2432e-02 1.4707e-04 2.6014e-03 -6.0000e+00 1.1927e-02 1.6100e-02 -3.5583e-03 7.7396e-06 2.6335e-05 -6.0000e+00 7.7527e-04 -9.0527e-02 9.5152e-05 12 8 8 10 0 0 69.37 20.02 0.24 -0.09053 -0.11727 1239 240 1 5 0 40.570 23.01 15.00 20.02 19.49 45.60 37.2 989.03 2509 1569 2715 -2013 -7300 -9042 -9218 -5091 -4882 -5166 -9799 -10645 -6683 -3393 729 1605 1236 2298 2343 3286 2760 1097 1011 1570 1184 504 -418 -2984 -4525 -4934 -2120 -1204 840 -1125 -6495 -8237 -7670 -4448 -1005 669 638 487 849 692 1328 1520 1074 449 -696 -989 421 1441 1426 2258 1581 1729 1476 143 -518 -745 80 1856 3485 4579 2870 254 -1224 -2595 -625 1487 1916 2486 1840 1714 454 -1766 -3679 -5971 -5229 -3663 -2956 -1762 -2605 -2411 -880 8 1442 1851 2562 2212 1132 -248 -2581 -3033 -2720 -1570 -371 1548 1627 734 -253 -2131 -2714 -1792 -1283 -1554 -897 -536 359 1751 2338 2349 1809 936 -260 -1169 -878 -581 729 1395 1330 1704 1679 1145 679 -382 -2003 -1426 -1043 -1000 -659 -1355 -1252 -1004 -387 151 276 1300 945 448 36 -1067 149 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