File name: Pandora91s1_Kigali_20250509_L2Fit_fwvt1c2d20250101p1-8.txt File generation date: 20250828T081912.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 91 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora91_OF_v1d20241022.txt Instrument calibration file used: Pandora91s1_CF_v2d20250101.txt Level 1 file used: Pandora91s1_Kigali_20250509_L1_smca1c2d20250101p1-8.txt Full location name: US Embassy of Rwanda Short location name: Kigali Country of location: Rwanda Location latitude [deg]: -1.9363 Location longitude [deg]: 30.0779 Location altitude [m]: 1495 Local noon date: 20250509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1615 1765 Nominal wavelengths inside fitting window [nm]: 492.0440 492.1650 492.2859 492.4068 492.5277 492.6486 492.7695 492.8904 493.0112 493.1320 493.2528 493.3736 493.4944 493.6152 493.7359 493.8566 493.9773 494.0980 494.2187 494.3393 494.4600 494.5806 494.7012 494.8218 494.9424 495.0629 495.1835 495.3040 495.4245 495.5450 495.6654 495.7859 495.9063 496.0267 496.1471 496.2675 496.3879 496.5082 496.6286 496.7489 496.8692 496.9895 497.1097 497.2300 497.3502 497.4704 497.5906 497.7108 497.8310 497.9511 498.0713 498.1914 498.3115 498.4315 498.5516 498.6717 498.7917 498.9117 499.0317 499.1517 499.2716 499.3916 499.5115 499.6314 499.7513 499.8712 499.9910 500.1109 500.2307 500.3505 500.4703 500.5901 500.7098 500.8296 500.9493 501.0690 501.1887 501.3084 501.4280 501.5476 501.6673 501.7869 501.9065 502.0260 502.1456 502.2651 502.3846 502.5041 502.6236 502.7431 502.8625 502.9820 503.1014 503.2208 503.3401 503.4595 503.5789 503.6982 503.8175 503.9368 504.0561 504.1753 504.2946 504.4138 504.5330 504.6522 504.7714 504.8905 505.0097 505.1288 505.2479 505.3670 505.4861 505.6051 505.7241 505.8432 505.9622 506.0811 506.2001 506.3191 506.4380 506.5569 506.6758 506.7947 506.9136 507.0324 507.1512 507.2701 507.3888 507.5076 507.6264 507.7451 507.8639 507.9826 508.1013 508.2199 508.3386 508.4572 508.5759 508.6945 508.8131 508.9316 509.0502 509.1687 509.2872 509.4057 509.5242 509.6427 509.7611 509.8796 509.9980 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20250509T053633.0Z 9260.233715 1271 1 20.60 2 66.78 70.08 151.27 254.84 0.00 1 0.00 1 0 15 3.631e-03 3.608e-03 1.601e-03 1.597e-03 4.542814e+03 1.011653e+02 3.156425e+02 -6.000000e+00 2.019502e+02 286.31 -2.00 20.00 -2.00 505.27 0.00e+00 4.804370e-04 4.412966e-05 3.445982e-05 -6.000000e+00 1.021543e-04 286.31 -2.00 20.00 -2.00 500.37 0.00e+00 2.060504e-01 3.134348e-02 3.125573e-02 -6.000000e+00 7.096587e-02 227.00 -2.00 3.05 -2.00 501.98 0.00e+00 2.517 0.000 489.00 513.00 1 7.2864e+00 2.4085e-03 4.0940e-03 -6.0000e+00 5.4498e-03 7.0440e-03 6.1679e-04 7.6107e-04 -6.0000e+00 1.4078e-03 9.6523e-04 -5.4136e-05 1.4851e-04 3.5236e-05 -6.0000e+00 3.5209e-04 3.6399e-03 -1.8149e-04 10 0 0 10 0 0 96.02 25.00 1.20 0.00364 0.00326 6 6 1 4 0 3431.900 33.50 20.00 25.00 28.13 0.0 987.22 -947 -380 19 38 282 648 483 531 323 316 325 116 -158 -457 -25 -518 -462 154 258 269 212 -23 130 430 1 229 556 328 -164 -286 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-171 -136 -37 -83 274 234 539 456 605 462 342 267 187 370 175 391 194 485 -41 391 486 286 253 -204 81 24 -85 -144 -140 -207 238 234 112 188 429 278 99 -97 -375 -587 -604 -389 SO 20250509T053737.4Z 9260.234460 1274 1 15.70 2 66.53 70.03 151.52 254.70 0.00 1 0.00 1 0 15 3.037e-03 3.018e-03 8.403e-04 8.384e-04 4.448912e+03 5.275608e+01 3.060139e+02 -6.000000e+00 1.689188e+02 286.31 -2.00 20.00 -2.00 505.25 0.00e+00 4.433110e-04 2.309212e-05 3.278652e-05 -6.000000e+00 8.544778e-05 286.31 -2.00 20.00 -2.00 500.37 0.00e+00 1.651359e-01 1.642665e-02 3.101739e-02 -6.000000e+00 5.936906e-02 227.00 -2.00 3.05 -2.00 501.97 0.00e+00 2.492 0.000 489.00 513.00 1 5.8307e+00 1.2605e-03 4.0463e-03 -6.0000e+00 4.5591e-03 1.1086e-02 3.2400e-04 7.4948e-04 -6.0000e+00 1.1779e-03 4.1663e-03 1.2373e-04 7.8197e-05 3.4708e-05 -6.0000e+00 2.9450e-04 1.8679e-03 -1.8282e-04 12 1 1 12 1 1 -114.67 25.01 1.06 0.00187 0.00273 13 18 1 4 0 1121.170 33.50 20.00 25.01 28.22 0.0 987.40 -655 -501 -249 -171 181 373 492 492 457 349 241 176 -123 -243 -203 -342 82 49 49 142 -56 158 284 209 295 308 387 166 -182 -479 -423 -534 -358 37 197 49 86 30 -73 -17 -70 -127 53 402 431 217 497 356 161 -113 -436 -633 -647 -787 -518 -234 -84 148 139 163 135 259 321 245 198 150 129 60 -224 -162 -146 -136 -31 -213 1 -189 -93 -325 -586 -337 -596 -306 -385 -249 -62 -218 -190 -93 35 -43 -77 281 250 113 166 334 170 -46 -300 -496 -626 -676 -147 -151 -2 -103 -241 -56 -188 -94 -142 -163 -30 130 234 473 504 514 507 473 175 299 260 169 338 104 315 342 271 345 98 223 41 -109 -362 -308 -138 -169 168 210 236 126 227 118 190 101 -182 -196 -445 -572 -396 -642 -494 -251 -174 185 390 524 519 482 365 255 183 -127 -246 -209 -345 83 51 51 150 -60 168 301 222 315 329 412 175 -188 -494 -425 -535 -363 37 208 51 90 31 -76 -18 -72 -131 55 421 446 226 514 373 167 -114 -439 -621 -639 -779 -511 -237 -85 153 143 168 138 266 332 248 203 152 129 59 -224 -159 -142 -133 -30 -212 1 -186 -93 -317 -565 -322 -571 -295 -374 -243 -61 -213 -187 -92 34 -42 -76 280 252 113 163 329 164 -44 -282 -468 -586 -641 -139 -146 -2 -102 -237 -55 -184 -92 -141 -159 -29 129 235 476 499 511 503 474 173 290 255 163 326 100 305 330 261 332 94 215 39 -103 -339 -291 -132 -163 163 207 229 123 222 117 188 99 -178 -190 -424 -540 -375 SO 20250509T054004.5Z 9260.236163 1277 1 12.56 2 65.95 69.92 152.08 254.37 0.00 1 0.00 1 0 15 2.910e-03 2.894e-03 4.182e-04 4.174e-04 4.285924e+03 2.616856e+01 2.958359e+02 -6.000000e+00 1.618477e+02 286.31 -2.00 20.00 -2.00 505.26 0.00e+00 4.854151e-04 1.151730e-05 3.436174e-05 -6.000000e+00 8.187197e-05 286.31 -2.00 20.00 -2.00 500.40 0.00e+00 1.668496e-01 8.160427e-03 2.986191e-02 -6.000000e+00 5.688965e-02 227.00 -2.00 3.05 -2.00 502.00 0.00e+00 2.437 0.000 489.00 513.00 1 4.3103e+00 6.2634e-04 3.9436e-03 -6.0000e+00 4.3686e-03 8.5436e-03 1.6074e-04 7.2207e-04 -6.0000e+00 1.1288e-03 1.9175e-02 3.3365e-04 3.8963e-05 3.4313e-05 -6.0000e+00 2.8218e-04 2.8110e-03 -1.9565e-04 12 1 1 12 1 1 74.47 25.03 1.02 0.00281 0.00513 48 78 1 4 0 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