File name: Pandora91s1_Kigali_20250824_L2Fit_fwvt1c2d20250101p1-8.txt File generation date: 20250828T083750.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Tador Tekeste Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 91 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora91_OF_v3d20241022.txt Instrument calibration file used: Pandora91s1_CF_v2d20250101.txt Level 1 file used: Pandora91s1_Kigali_20250824_L1_smca1c2d20250101p1-8.txt Full location name: US Embassy of Rwanda Short location name: Kigali Country of location: Rwanda Location latitude [deg]: -1.9363 Location longitude [deg]: 30.0779 Location altitude [m]: 1495 Local noon date: 20250824 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1615 1765 Nominal wavelengths inside fitting window [nm]: 492.0440 492.1650 492.2859 492.4068 492.5277 492.6486 492.7695 492.8904 493.0112 493.1320 493.2528 493.3736 493.4944 493.6152 493.7359 493.8566 493.9773 494.0980 494.2187 494.3393 494.4600 494.5806 494.7012 494.8218 494.9424 495.0629 495.1835 495.3040 495.4245 495.5450 495.6654 495.7859 495.9063 496.0267 496.1471 496.2675 496.3879 496.5082 496.6286 496.7489 496.8692 496.9895 497.1097 497.2300 497.3502 497.4704 497.5906 497.7108 497.8310 497.9511 498.0713 498.1914 498.3115 498.4315 498.5516 498.6717 498.7917 498.9117 499.0317 499.1517 499.2716 499.3916 499.5115 499.6314 499.7513 499.8712 499.9910 500.1109 500.2307 500.3505 500.4703 500.5901 500.7098 500.8296 500.9493 501.0690 501.1887 501.3084 501.4280 501.5476 501.6673 501.7869 501.9065 502.0260 502.1456 502.2651 502.3846 502.5041 502.6236 502.7431 502.8625 502.9820 503.1014 503.2208 503.3401 503.4595 503.5789 503.6982 503.8175 503.9368 504.0561 504.1753 504.2946 504.4138 504.5330 504.6522 504.7714 504.8905 505.0097 505.1288 505.2479 505.3670 505.4861 505.6051 505.7241 505.8432 505.9622 506.0811 506.2001 506.3191 506.4380 506.5569 506.6758 506.7947 506.9136 507.0324 507.1512 507.2701 507.3888 507.5076 507.6264 507.7451 507.8639 507.9826 508.1013 508.2199 508.3386 508.4572 508.5759 508.6945 508.8131 508.9316 509.0502 509.1687 509.2872 509.4057 509.5242 509.6427 509.7611 509.8796 509.9980 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250824T085809.9Z 9367.373725 164 1 6.53 2 20.46 50.62 30.19 73.70 0.00 1 0.00 1 0 15 3.640e-03 3.618e-03 2.448e-03 2.445e-03 1.588964e+03 1.416987e+02 1.006915e+02 -6.000000e+00 2.016591e+02 285.24 -2.00 20.00 -2.00 505.27 0.00e+00 4.450718e-04 6.725885e-05 2.846507e-05 -6.000000e+00 1.021084e-04 285.24 -2.00 20.00 -2.00 500.50 0.00e+00 -7.140564e-02 4.743982e-02 1.505032e-02 -6.000000e+00 7.116232e-02 227.53 -2.00 3.05 -2.00 502.09 0.00e+00 1.067 0.000 489.00 513.00 1 7.1015e+00 3.6407e-03 1.8950e-03 -6.0000e+00 5.4631e-03 -1.1925e-02 9.3855e-04 3.2197e-04 -6.0000e+00 1.4101e-03 1.4183e-03 -2.1040e-04 2.3142e-04 1.4417e-05 -6.0000e+00 3.5288e-04 -6.9724e-03 -3.9910e-05 12 1 1 12 1 1 99.98 26.21 1.01 -0.00697 -0.00843 4 4 1 4 0 1304.520 34.50 19.99 26.21 35.22 0.0 1008.41 -796 -629 -174 -104 -51 499 964 205 313 735 -123 187 -227 -153 -175 -729 -535 160 96 299 130 329 15 495 -182 321 237 251 -119 -180 -316 -291 -97 -52 25 298 48 -174 51 -280 295 54 357 291 300 370 395 -90 -4 -100 -203 -831 -498 -666 -107 -552 22 150 491 234 -130 426 406 661 223 512 -88 -99 -397 -114 -61 -366 16 7 -321 -189 -303 -433 -453 -464 -280 -306 -406 59 -267 -68 -82 -694 -253 22 -235 25 -136 53 341 483 63 -142 -492 -485 -763 -440 -54 -88 269 -307 89 -239 -83 52 58 417 -55 74 318 652 507 346 555 647 -51 -71 667 319 6 582 -7 370 -108 -147 156 587 278 -476 -501 -13 -198 -236 21 351 195 291 20 402 -158 297 133 -92 -371 -926 -842 -767 -610 -173 -104 -53 507 995 215 330 763 -126 190 -234 -155 -176 -740 -549 162 99 315 138 339 16 510 -190 334 246 258 -123 -180 -319 -294 -97 -53 26 310 50 -179 52 -290 303 55 361 298 311 385 409 -93 -4 -102 -200 -803 -486 -654 -104 -555 22 152 496 237 -131 431 413 671 226 510 -87 -99 -394 -111 -59 -355 15 6 -322 -189 -300 -422 -435 -443 -268 -295 -396 58 -265 -67 -81 -684 -248 22 -233 25 -139 52 347 483 62 -137 -477 -460 -722 -419 -53 -87 271 -305 88 -239 -81 52 57 409 -55 75 323 664 519 356 567 651 -51 -69 662 310 6 569 -7 362 -106 -144 152 575 268 -457 -479 -12 -194 -230 21 349 196 293 20 398 -158 294 134 -90 -356 -886 -809 SQ 20250824T093901.5Z 9367.402100 183 1 4.72 2 14.09 23.85 20.65 66.49 0.00 1 0.00 1 0 15 7.229e-03 7.207e-03 7.134e-03 7.119e-03 1.582276e+03 4.139862e+02 1.243419e+02 -6.000000e+00 4.005167e+02 285.24 -2.00 20.00 -2.00 505.28 0.00e+00 5.350395e-04 1.955813e-04 3.635946e-05 -6.000000e+00 2.027960e-04 285.24 -2.00 20.00 -2.00 500.49 0.00e+00 -1.845317e-01 1.384989e-01 1.090364e-02 -6.000000e+00 1.413298e-01 227.53 -2.00 3.05 -2.00 502.08 0.00e+00 1.031 0.000 489.00 513.00 1 8.2946e+00 1.0628e-02 1.7624e-03 -6.0000e+00 1.0850e-02 -1.3931e-02 2.7365e-03 2.6597e-04 -6.0000e+00 2.8004e-03 4.3511e-04 1.1425e-04 6.7630e-04 1.9843e-05 -6.0000e+00 7.0083e-04 -9.5942e-03 -2.0757e-05 12 9 9 12 1 1 999.00 26.45 1.22 -0.00959 -0.00880 1 2 1 4 0 2357.360 34.75 20.00 26.45 37.52 0.0 1018.72 589 791 -40 226 -43 -174 244 978 90 -198 305 482 433 -56 -96 -339 -481 -539 -472 1388 -219 1097 920 240 177 1074 441 -20 -362 853 -1176 10 484 -172 -1240 -257 -172 -609 -1510 -295 -28 0 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228 -941 -602 -1855 757 343 1229 1034 766 -115 415 1689 -150 -200 26 712 -366 397 706 803 1299 -432 495 -268 -703 940 1241 1436 -667 23 1053 23 -27 493 -604 896 1059 -1334 424 -1339 -468 -1287 SQ 20250824T094958.5Z 9367.409705 189 1 19.74 2 13.22 13.06 18.19 63.27 0.00 1 0.00 1 0 15 3.796e-03 3.774e-03 2.014e-03 2.011e-03 1.493261e+03 1.166178e+02 1.071427e+02 -6.000000e+00 2.103248e+02 285.24 -2.00 20.00 -2.00 505.27 0.00e+00 3.765604e-04 5.520259e-05 2.634084e-05 -6.000000e+00 1.064952e-04 285.24 -2.00 20.00 -2.00 500.48 0.00e+00 -6.624039e-02 3.910260e-02 1.164777e-02 -6.000000e+00 7.421710e-02 227.53 -2.00 3.05 -2.00 502.07 0.00e+00 1.027 0.000 489.00 513.00 1 7.8194e+00 2.9998e-03 1.6862e-03 -6.0000e+00 5.6977e-03 -9.3749e-03 7.7352e-04 2.7265e-04 -6.0000e+00 1.4706e-03 6.9564e-04 1.0330e-04 1.9072e-04 1.5440e-05 -6.0000e+00 3.6803e-04 -1.1053e-02 -1.1964e-05 12 1 1 12 1 1 99.98 26.50 0.99 -0.01105 -0.01034 6 2 1 4 0 2818.750 34.75 20.00 26.50 36.64 0.0 1012.91 -944 -98 -288 115 326 305 692 409 273 660 216 46 -82 -570 -438 -252 -39 -10 222 13 98 31 -48 -206 -21 465 309 95 -205 -143 -527 -341 8 225 -302 -139 68 302 246 18 150 -98 272 638 520 309 168 703 495 -378 184 -161 -1121 -993 -343 -142 -157 -90 -188 -359 72 89 91 508 300 65 115 75 -425 -259 -249 -506 -211 -84 153 320 -293 -276 -387 -741 -531 0 -328 -176 -351 -34 352 -721 -218 273 318 274 -391 322 -3 422 510 -112 -518 -462 -761 -474 -432 -236 -296 -272 -230 -238 -117 243 161 326 -466 -40 947 633 280 618 561 120 95 303 326 190 657 -133 154 45 212 312 149 30 -366 19 171 193 -60 -12 -264 373 272 113 468 207 301 393 -171 -406 -720 -950 -522 -911 -94 -287 114 332 317 732 424 283 699 227 47 -84 -575 -439 -252 -39 -10 226 14 102 33 -50 -217 -22 489 324 99 -209 -146 -529 -342 8 226 -315 -147 71 313 251 18 151 -99 279 659 543 325 176 725 503 -378 185 -158 -1090 -968 -340 -140 -158 -92 -193 -368 74 92 94 522 307 65 114 73 -414 -257 -246 -501 -203 -81 150 313 -284 -263 -377 -722 -518 0 -314 -169 -342 -34 346 -717 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