File name: Pandora91s1_Kigali_20250831_L2Fit_fwvt1c2d20250101p1-8.txt File generation date: 20250831T220534.5Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Tador Tekeste Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 91 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora91_OF_v3d20241022.txt Instrument calibration file used: Pandora91s1_CF_v2d20250101.txt Level 1 file used: Pandora91s1_Kigali_20250831_L1_smca1c2d20250101p1-8.txt Full location name: US Embassy of Rwanda Short location name: Kigali Country of location: Rwanda Location latitude [deg]: -1.9363 Location longitude [deg]: 30.0779 Location altitude [m]: 1495 Local noon date: 20250831 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 1615 1765 Nominal wavelengths inside fitting window [nm]: 492.0440 492.1650 492.2859 492.4068 492.5277 492.6486 492.7695 492.8904 493.0112 493.1320 493.2528 493.3736 493.4944 493.6152 493.7359 493.8566 493.9773 494.0980 494.2187 494.3393 494.4600 494.5806 494.7012 494.8218 494.9424 495.0629 495.1835 495.3040 495.4245 495.5450 495.6654 495.7859 495.9063 496.0267 496.1471 496.2675 496.3879 496.5082 496.6286 496.7489 496.8692 496.9895 497.1097 497.2300 497.3502 497.4704 497.5906 497.7108 497.8310 497.9511 498.0713 498.1914 498.3115 498.4315 498.5516 498.6717 498.7917 498.9117 499.0317 499.1517 499.2716 499.3916 499.5115 499.6314 499.7513 499.8712 499.9910 500.1109 500.2307 500.3505 500.4703 500.5901 500.7098 500.8296 500.9493 501.0690 501.1887 501.3084 501.4280 501.5476 501.6673 501.7869 501.9065 502.0260 502.1456 502.2651 502.3846 502.5041 502.6236 502.7431 502.8625 502.9820 503.1014 503.2208 503.3401 503.4595 503.5789 503.6982 503.8175 503.9368 504.0561 504.1753 504.2946 504.4138 504.5330 504.6522 504.7714 504.8905 505.0097 505.1288 505.2479 505.3670 505.4861 505.6051 505.7241 505.8432 505.9622 506.0811 506.2001 506.3191 506.4380 506.5569 506.6758 506.7947 506.9136 507.0324 507.1512 507.2701 507.3888 507.5076 507.6264 507.7451 507.8639 507.9826 508.1013 508.2199 508.3386 508.4572 508.5759 508.6945 508.8131 508.9316 509.0502 509.1687 509.2872 509.4057 509.5242 509.6427 509.7611 509.8796 509.9980 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250831T095542.7Z 9374.413688 190 1 53.73 2 10.46 5.83 88.72 117.04 0.00 1 0.00 1 0 15 6.497e-03 6.407e-03 2.927e-03 2.917e-03 1.192876e+03 1.697534e+02 8.000289e+01 -6.000000e+00 3.600146e+02 285.28 -2.00 20.00 -2.00 505.28 0.00e+00 5.936673e-04 8.022892e-05 3.298092e-05 -6.000000e+00 1.822809e-04 285.28 -2.00 20.00 -2.00 500.38 0.00e+00 -6.741786e-02 5.700861e-02 1.107494e-02 -6.000000e+00 1.270901e-01 227.76 -2.00 3.05 -2.00 502.01 0.00e+00 1.017 0.000 489.00 513.00 1 9.2989e+00 4.3670e-03 1.7077e-03 -6.0000e+00 9.7561e-03 3.5493e-03 1.1291e-03 2.3688e-04 -6.0000e+00 2.5193e-03 1.5824e-04 7.0395e-04 2.7536e-04 1.3607e-05 -6.0000e+00 6.2989e-04 -3.3022e-03 -8.6195e-05 12 8 8 10 0 0 100.00 25.97 0.70 -0.00330 0.00158 18 2 1 4 0 2984.740 34.25 19.96 25.97 33.61 0.0 1004.92 -635 358 -884 -690 552 -163 684 625 179 13 -167 1044 1124 -1019 -529 -542 -293 423 -322 80 -167 307 -546 75 149 817 827 -257 14 163 235 367 -102 400 -153 -92 -253 -197 -383 -679 -382 -656 124 1194 1284 -138 99 208 748 -529 809 -18 -1129 -1246 714 113 531 357 -26 -581 -732 165 152 1170 456 -203 764 839 -1800 -786 -102 -600 276 -719 -229 108 -907 -778 -718 -540 -1015 -1006 -172 90 -1268 1022 686 -373 90 57 -321 251 -574 346 443 415 617 -88 -648 -572 -1325 -145 -947 748 -332 -854 361 -576 -471 1065 1202 240 -445 161 346 428 426 -101 27 497 1874 -262 315 -555 103 425 -563 57 1093 516 -16 179 1130 -538 1293 -150 -188 -76 -69 573 374 -76 518 -197 402 463 -1339 -669 -109 -1487 -363 -605 340 -876 -709 576 -175 743 686 197 14 -180 1098 1161 -1058 -542 -558 -304 446 -351 88 -175 320 -573 78 157 852 859 -267 15 169 239 372 -106 425 -159 -97 -265 -204 -392 -689 -386 -668 126 1220 1323 -145 103 215 753 -526 819 -18 -1116 -1237 712 110 529 361 -26 -592 -746 167 155 1181 461 -203 747 808 -1758 -750 -96 -566 260 -695 -222 105 -874 -735 -669 -499 -946 -947 -162 85 -1230 980 662 -364 87 56 -317 249 -583 351 447 413 601 -85 -607 -525 -1215 -133 -898 724 -334 -868 359 -569 -459 1024 1168 239 -454 166 357 444 443 -106 28 507 1853 -261 310 -551 102 420 -563 56 1070 507 -15 173 1063 -508 1191 -141 -180 -75 -69 574 357 -73 497 -192 390 446 -1290 -662 -104 -1434 -348 SQ 20250831T104922.5Z 9374.450955 214 1 9.22 2 16.11 310.33 77.18 117.50 0.00 1 0.00 1 0 15 2.888e-03 2.874e-03 4.790e-04 4.783e-04 1.120393e+03 2.727242e+01 7.324927e+01 -6.000000e+00 1.600367e+02 285.28 -2.00 20.00 -2.00 505.27 0.00e+00 3.865265e-04 1.313238e-05 2.398795e-05 -6.000000e+00 8.102010e-05 285.28 -2.00 20.00 -2.00 500.49 0.00e+00 -3.311871e-02 9.283400e-03 1.050283e-02 -6.000000e+00 5.647012e-02 227.77 -2.00 3.05 -2.00 502.08 0.00e+00 1.041 0.000 489.00 513.00 1 4.4615e+00 7.1231e-04 1.6164e-03 -6.0000e+00 4.3352e-03 -8.7310e-03 1.8375e-04 2.2963e-04 -6.0000e+00 1.1189e-03 1.9916e-02 2.6408e-04 4.5376e-05 1.1237e-05 -6.0000e+00 2.7997e-04 -8.9218e-03 -1.9133e-05 12 1 1 12 1 1 100.00 26.52 1.10 -0.00892 -0.00709 197 61 1 4 0 46.550 34.75 20.02 26.52 36.08 0.0 1013.36 -628 -550 -259 -45 198 358 480 465 430 337 287 91 -37 -177 -276 -269 -146 55 -12 57 108 225 118 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-120 -208 -67 -85 29 149 280 421 542 554 546 363 349 139 80 200 186 280 159 222 344 358 306 240 69 -85 -290 -248 -184 -92 -103 -4 110 130 110 229 234 250 140 -92 -300 -429 -488 -396 SQ 20250831T110006.7Z 9374.458410 218 1 5.93 2 18.24 304.93 74.87 117.75 0.00 1 0.00 1 0 15 3.067e-03 3.050e-03 1.025e-04 1.024e-04 1.107411e+03 5.832014e+00 7.589894e+01 -6.000000e+00 1.699806e+02 285.28 -2.00 20.00 -2.00 505.27 0.00e+00 3.799597e-04 2.811537e-06 2.312988e-05 -6.000000e+00 8.605185e-05 285.28 -2.00 20.00 -2.00 500.50 0.00e+00 -3.287185e-02 1.985146e-03 9.705443e-03 -6.000000e+00 5.996812e-02 227.77 -2.00 3.05 -2.00 502.09 0.00e+00 1.053 0.000 489.00 513.00 1 9.7113e-01 1.5235e-04 1.5914e-03 -6.0000e+00 4.6039e-03 -7.8514e-03 3.9291e-05 2.1986e-04 -6.0000e+00 1.1880e-03 6.5232e-01 4.3910e-04 9.7285e-06 1.1537e-05 -6.0000e+00 2.9737e-04 -8.8916e-03 -6.4666e-06 10 0 0 10 0 0 98.71 26.57 1.10 -0.00889 -0.00585 945 95 1 4 0 6.270 34.75 20.01 26.57 36.75 0.0 1017.42 -687 -506 -266 1 188 377 582 514 478 412 239 98 -159 -231 -338 -307 -127 17 125 150 153 204 202 235 301 354 350 131 -140 -403 -527 -492 -276 53 168 84 94 0 -107 -158 -78 -20 125 271 390 382 418 327 143 -93 -421 -693 -753 -690 -417 -240 -50 15 41 112 179 274 328 343 275 189 146 0 -167 -229 -282 -246 -172 -42 0 -91 -218 -345 -386 -404 -420 -412 -377 -276 -131 -182 -183 -124 -174 -146 3 141 247 274 306 303 94 -175 -278 -524 -681 -554 -311 -126 -33 -72 -136 -219 -266 -161 -70 32 186 299 386 513 526 535 472 358 242 147 170 226 249 241 310 317 300 301 232 67 -110 -298 -352 -235 -124 -106 9 95 123 150 243 295 301 165 -62 -287 -434 -517 -432 -671 -498 -262 1 193 388 602 538 501 428 247 100 -163 -232 -338 -308 -129 17 130 157 160 213 211 246 317 369 367 136 -144 -407 -528 -494 -277 54 173 87 98 0 -110 -161 -79 -21 128 278 404 397 432 335 146 -93 -419 -680 -729 -670 -409 -240 -51 16 41 113 183 277 333 349 278 191 145 0 -164 -225 -274 -239 -170 -41 0 -90 -214 -336 -372 -387 -405 -401 -365 -269 -129 -179 -181 -123 -172 -145 3 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