File name: Pandora239s1_Kosetice_20231210_L2Fit_fout2c2d20220901p1-8.txt File generation date: 20240113T142421.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nadezda Zikova Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 239 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora239_OF_v3d20220426.txt Instrument calibration file used: Pandora239s1_CF_v2d20220901.txt Level 1 file used: Pandora239s1_Kosetice_20231210_L1_smca1c2d20220901p1-8.txt Full location name: National Atmospheric Observatory Kosetice Short location name: Kosetice Country of location: Czech Republic Location latitude [deg]: 49.5733 Location longitude [deg]: 15.0803 Location altitude [m]: 534 Local noon date: 20231210 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial instrument OoB session based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0356 305.1770 305.3183 305.4597 305.6010 305.7424 305.8837 306.0250 306.1663 306.3076 306.4488 306.5901 306.7314 306.8726 307.0138 307.1551 307.2963 307.4374 307.5786 307.7198 307.8610 308.0021 308.1432 308.2844 308.4255 308.5666 308.7077 308.8487 308.9898 309.1309 309.2719 309.4129 309.5540 309.6950 309.8360 309.9769 310.1179 310.2589 310.3998 310.5408 310.6817 310.8226 310.9635 311.1044 311.2453 311.3861 311.5270 311.6678 311.8087 311.9495 312.0903 312.2311 312.3719 312.5126 312.6534 312.7942 312.9349 313.0756 313.2163 313.3570 313.4977 313.6384 313.7791 313.9197 314.0604 314.2010 314.3416 314.4822 314.6228 314.7634 314.9040 315.0445 315.1851 315.3256 315.4661 315.6066 315.7471 315.8876 316.0281 316.1686 316.3090 316.4495 316.5899 316.7303 316.8707 317.0111 317.1515 317.2918 317.4322 317.5725 317.7129 317.8532 317.9935 318.1338 318.2741 318.4144 318.5546 318.6949 318.8351 318.9753 319.1155 319.2557 319.3959 319.5361 319.6763 319.8164 319.9566 320.0967 320.2368 320.3769 320.5170 320.6571 320.7971 320.9372 321.0772 321.2173 321.3573 321.4973 321.6373 321.7773 321.9172 322.0572 322.1971 322.3371 322.4770 322.6169 322.7568 322.8967 323.0366 323.1764 323.3163 323.4561 323.5959 323.7358 323.8756 324.0153 324.1551 324.2949 324.4346 324.5744 324.7141 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231210T101551.7Z 8744.427681 198 1 12.34 2 72.93 171.22 72.50 204.65 0.00 1 0.00 1 0 49 1.052e-01 8.143e-02 2.351e-03 1.970e-03 3.073447e-01 9.832119e-04 4.019256e-03 -6.000000e+00 5.790821e-02 220.76 -2.00 3.74 -2.00 313.65 0.00e+00 -1.467350e-03 6.476532e-05 4.950079e-04 -6.000000e+00 2.482383e-03 267.89 -2.00 20.00 -2.00 313.34 0.00e+00 3.358 0.001 302.00 328.00 3 1.9724e+00 2.4454e-03 3.4591e-02 -6.0000e+00 1.4233e-01 7.7595e-01 2.7490e-03 1.5449e-02 -6.0000e+00 1.5608e-01 -6.4229e-01 1.5808e-03 7.8038e-03 -6.0000e+00 9.2669e-02 2.1406e-01 6.6488e-04 3.0806e-03 -6.0000e+00 3.9078e-02 2.3154e-03 3.0653e-04 5.3185e-05 4.4551e-05 -6.0000e+00 2.8053e-03 -3.8303e-02 -1.5518e-03 12 9 9 12 5 1 79.16 22.16 0.42 -0.03830 -0.03600 132 285 1 8 0 92.710 19.97 22.16 9.92 25.68 25.17 16.5 958.00 20640 22949 18183 5160 -13048 -21589 -19026 -13265 -6622 -6319 -12305 -14584 -6686 1483 9889 14379 14035 12662 11571 10804 7135 2925 1395 5071 6086 6528 1446 -9521 -21443 -24423 -21128 -16663 -12204 -13879 -24656 -27751 -21243 -9370 5169 15719 19818 20348 19935 16888 13823 10389 6264 1111 -2535 -3347 -23 3345 5873 8146 7493 7759 7196 4063 428 -1633 91 4553 8999 11402 6712 -1569 -8321 -10141 -5258 2739 6502 6893 5429 860 -5538 -14868 -21939 -25987 -21389 -13844 -8104 -3393 -2201 596 4200 7956 9520 10870 9759 5932 436 -5688 -11160 -12162 -8759 -4109 639 4217 4211 761 -2768 -7059 -7249 -3434 1035 2216 4465 5953 7818 9656 9380 7765 4336 -128 -4459 -6182 -5523 -2736 617 2980 3339 3710 2537 153 -2441 -4816 -6952 -5512 -3806 -2916 -2571 -3231 -3217 -1912 294 1150 2066 2912 2254 1397 1104 47 -70 11985 13357 10666 3013 -7629 -12649 -11107 -7837 -3895 -3715 -7224 -8646 -3950 882 5898 8610 8402 7649 7028 7193 4773 1937 935 3379 4087 4373 974 -6397 -14491 -16397 -14258 -11264 -8325 -9494 -16856 -18844 -14543 -6487 3634 11296 14451 14955 14705 12519 10217 7715 4628 827 -1888 -2503 -18 2576 4577 6439 6037 6259 5835 3302 345 -1312 73 3724 7560 9803 5854 -1349 -7131 -8676 -4595 2480 6075 6553 5113 799 -4981 -12984 -18606 -22104 -18559 -12566 -7745 -3390 -2289 628 4150 8023 9829 11279 10118 6029 470 -5946 -11388 -12433 -9325 -4209 695 4884 5058 910 -3185 -7754 -7595 -3647 1137 2516 5190 7156 9761 12688 12994 10942 6037 -173 -5776 -7760 -6971 -3532 827 4096 4586 4968 3340 196 -3050 -5865 -8297 -6708 -4927 -3999 -3693 -4792 -4878 -2748 440 1772 3217 4587 3540 2127 1618 67 -108 SS 20231210T102628.1Z 8744.435048 204 1 9.82 2 72.71 173.76 73.27 207.07 0.00 1 0.00 1 0 65 1.073e-01 8.608e-02 5.961e-04 5.120e-04 2.884696e-01 2.569334e-04 3.786167e-03 -6.000000e+00 5.911736e-02 220.76 -2.00 3.74 -2.00 313.39 0.00e+00 -1.084822e-03 1.624608e-05 4.482294e-04 -6.000000e+00 2.533474e-03 267.89 -2.00 20.00 -2.00 313.09 0.00e+00 3.317 0.001 302.00 328.00 3 -1.0069e+00 6.3863e-04 3.3796e-02 -6.0000e+00 1.4531e-01 7.7843e-01 7.1565e-04 1.4385e-02 -6.0000e+00 1.5930e-01 -6.0906e-01 4.1253e-04 7.3043e-03 -6.0000e+00 9.4579e-02 1.9341e-01 1.7291e-04 2.7923e-03 -6.0000e+00 3.9923e-02 4.8847e-02 1.3098e-03 1.3840e-05 4.4564e-05 -6.0000e+00 2.8620e-03 -4.5553e-02 -1.6161e-03 12 9 8 11 4 0 99.64 22.15 0.48 -0.04555 -0.03571 2647 2205 1 8 0 3.490 20.00 22.15 10.07 25.68 25.17 16.5 959.73 20954 23266 18810 5425 -12736 -20817 -18944 -12037 -6031 -6164 -12547 -14003 -6710 1713 10182 14214 13596 12716 11959 10992 7644 2672 2242 4906 6175 5918 1443 -9444 -20577 -24123 -20922 -16974 -12630 -14741 -25556 -28670 -21793 -9492 4817 15748 19780 20187 19576 17060 13761 10803 6073 1202 -2577 -3570 -78 3114 5623 7855 7839 7626 7161 4116 258 -1362 360 4950 9598 11894 7033 -1882 -8193 -10715 -5044 2798 6713 7646 5275 1128 -5909 -15241 -23167 -26816 -22330 -14499 -8249 -3318 -1436 997 5327 8627 10809 11753 10816 6780 782 -5681 -11841 -12968 -9261 -4293 722 4751 4725 1395 -2815 -7204 -7970 -3347 676 2567 4868 6506 8513 10360 10567 8439 4692 -210 -4884 -6934 -6035 -3230 376 3082 3688 3659 2436 -311 -2957 -5888 -8074 -6572 -4616 -3480 -3012 -3399 -3389 -1768 387 1470 2395 3353 2807 1747 1075 280 193 12790 14224 11550 3326 -7830 -12803 -11700 -7435 -3727 -3816 -7776 -8699 -4179 1071 6372 8953 8571 8048 7588 6973 4860 1696 1567 3436 4338 4173 1017 -6633 -14446 -16932 -14744 -12015 -9015 -10563 -18301 -20456 -15643 -6861 3540 11755 14957 15394 15016 13090 10566 8296 4664 926 -1984 -2761 -61 2473 4512 6384 6439 6293 5929 3413 213 -1118 296 4138 8208 10389 6217 -1645 -7094 -9314 -4445 2555 6308 7265 5011 1053 -5375 -13460 -20019 -23111 -19631 -13267 -7889 -3302 -1474 1042 5695 9456 10956 12020 11028 7463 834 -5881 -12018 -13180 -9755 -4762 769 5357 5512 1616 -3158 -7731 -9052 -3830 804 2844 5517 7601 10295 13149 14030 11421 6278 -273 -6107 -8430 -7363 -4031 487 4079 4870 4735 3100 -387 -3582 -6987 -9394 -7785 -5787 -4600 -4157 -4822 -4910 -2640 601 2349 3549 5020 4189 2765 1647 416 284 SS 20231210T102638.0Z 8744.435162 204 2 9.67 2 72.70 173.80 73.28 207.11 0.00 1 0.00 1 0 49 1.068e-01 8.434e-02 8.070e-04 6.779e-04 2.926189e-01 3.394344e-04 3.788470e-03 -6.000000e+00 5.885451e-02 220.76 -2.00 3.74 -2.00 313.62 0.00e+00 -1.246583e-03 2.238512e-05 4.789789e-04 -6.000000e+00 2.522243e-03 267.89 -2.00 20.00 -2.00 313.31 0.00e+00 3.316 0.001 302.00 328.00 3 -6.2874e-01 8.4381e-04 3.3826e-02 -6.0000e+00 1.4466e-01 7.7798e-01 9.4352e-04 1.4465e-02 -6.0000e+00 1.5860e-01 -6.1699e-01 5.4524e-04 7.3377e-03 -6.0000e+00 9.4159e-02 1.9802e-01 2.3082e-04 2.8933e-03 -6.0000e+00 3.9745e-02 3.3264e-02 1.0861e-03 1.8344e-05 4.5003e-05 -6.0000e+00 2.8493e-03 -4.5315e-02 -1.6156e-03 12 9 8 11 4 0 99.58 22.15 0.47 -0.04531 -0.03715 2647 2205 1 8 0 3.490 20.00 22.15 10.07 25.68 25.17 16.5 959.73 21201 23101 19264 5318 -12303 -21025 -18290 -12326 -5674 -6203 -11880 -13828 -6475 1742 10065 14647 13574 13103 11647 11269 7578 2941 1932 5054 5920 6339 1483 -9107 -20594 -24138 -21041 -17165 -12393 -14860 -25147 -29003 -21513 -10073 4984 15434 19995 20131 19632 17009 13588 10737 5758 1223 -2943 -3391 -609 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