File name: Pandora239s1_Kosetice_20240214_L2Fit_fout2c2d20220901p1-8.txt File generation date: 20240214T232007.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nadezda Zikova Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 239 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora239_OF_v3d20220426.txt Instrument calibration file used: Pandora239s1_CF_v2d20220901.txt Level 1 file used: Pandora239s1_Kosetice_20240214_L1_smca1c2d20220901p1-8.txt Full location name: National Atmospheric Observatory Kosetice Short location name: Kosetice Country of location: Czech Republic Location latitude [deg]: 49.5733 Location longitude [deg]: 15.0803 Location altitude [m]: 534 Local noon date: 20240214 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial instrument OoB session based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0356 305.1770 305.3183 305.4597 305.6010 305.7424 305.8837 306.0250 306.1663 306.3076 306.4488 306.5901 306.7314 306.8726 307.0138 307.1551 307.2963 307.4374 307.5786 307.7198 307.8610 308.0021 308.1432 308.2844 308.4255 308.5666 308.7077 308.8487 308.9898 309.1309 309.2719 309.4129 309.5540 309.6950 309.8360 309.9769 310.1179 310.2589 310.3998 310.5408 310.6817 310.8226 310.9635 311.1044 311.2453 311.3861 311.5270 311.6678 311.8087 311.9495 312.0903 312.2311 312.3719 312.5126 312.6534 312.7942 312.9349 313.0756 313.2163 313.3570 313.4977 313.6384 313.7791 313.9197 314.0604 314.2010 314.3416 314.4822 314.6228 314.7634 314.9040 315.0445 315.1851 315.3256 315.4661 315.6066 315.7471 315.8876 316.0281 316.1686 316.3090 316.4495 316.5899 316.7303 316.8707 317.0111 317.1515 317.2918 317.4322 317.5725 317.7129 317.8532 317.9935 318.1338 318.2741 318.4144 318.5546 318.6949 318.8351 318.9753 319.1155 319.2557 319.3959 319.5361 319.6763 319.8164 319.9566 320.0967 320.2368 320.3769 320.5170 320.6571 320.7971 320.9372 321.0772 321.2173 321.3573 321.4973 321.6373 321.7773 321.9172 322.0572 322.1971 322.3371 322.4770 322.6169 322.7568 322.8967 323.0366 323.1764 323.3163 323.4561 323.5959 323.7358 323.8756 324.0153 324.1551 324.2949 324.4346 324.5744 324.7141 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240214T071415.8Z 8810.301572 5 1 27.22 2 81.76 121.65 98.96 63.37 0.00 1 0.00 1 7 257 1.302e-01 1.266e-01 2.403e-03 2.343e-03 1.740166e-01 1.252157e-03 2.309838e-03 -6.000000e+00 7.338077e-02 223.75 -2.00 3.74 -2.00 311.77 0.00e+00 7.738885e-04 5.983016e-05 1.799510e-04 -6.000000e+00 3.058204e-03 265.48 -2.00 20.00 -2.00 311.65 0.00e+00 6.561 0.006 302.00 328.00 3 -3.6524e-02 3.1088e-03 6.0928e-02 -6.0000e+00 1.8177e-01 1.1743e+00 3.4200e-03 1.0032e-02 -6.0000e+00 1.9813e-01 -3.9017e-01 2.0016e-03 3.8686e-03 -6.0000e+00 1.1715e-01 5.6060e-02 8.4980e-04 1.0052e-03 -6.0000e+00 5.0184e-02 1.1533e-03 -1.9838e-03 6.2453e-05 3.6879e-05 -6.0000e+00 3.4911e-03 -2.0799e-02 -2.4043e-03 12 11 10 11 4 0 55.31 22.05 0.55 -0.02080 -0.03571 279 279 1 8 0 97.530 19.98 22.05 9.29 25.58 25.07 17.3 969.10 19820 21234 15574 846 -15040 -20135 -16160 -8655 -4051 -5716 -12128 -12316 -4245 3519 11644 13828 12303 11442 11205 11342 7927 3896 3736 6140 6368 5927 447 -10557 -20984 -22676 -20593 -17488 -13841 -18993 -29598 -30216 -20980 -7958 7748 17223 20958 21570 21316 18945 16091 13321 7879 1937 -3314 -3784 60 3296 5967 8299 7577 7502 6525 3214 -354 -1220 2792 8478 14319 15805 8206 -3364 -11975 -14250 -6118 4265 9204 10137 7855 1492 -8167 -20787 -30387 -34869 -29047 -18540 -10070 -3051 231 4110 10326 15881 18927 20550 18492 11352 1870 -8587 -17358 -19954 -13550 -5487 3002 9266 10085 4502 -2307 -10049 -11699 -4991 1681 5295 9023 11918 15673 19443 20231 17143 9727 779 -8419 -12501 -11106 -6173 1048 5646 6832 5678 2816 -2943 -8837 -13864 -17675 -15103 -10819 -7998 -5675 -6203 -5859 -2178 2386 5313 1445 9156 8460 5944 4005 2153 900000 16136 17258 12717 690 -12304 -16564 -13300 -7107 -3341 -4696 -9936 -10193 -3507 2921 9601 11444 10180 9511 10163 10252 7192 3531 3405 5554 5780 5377 405 -9551 -19132 -20549 -18725 -15866 -12554 -17250 -26815 -27538 -19120 -7294 7063 15822 19187 19774 19582 17407 14839 12239 7238 1785 -3062 -3480 55 3036 5494 7632 6995 6904 6009 2964 -328 -1131 2574 7839 13192 14581 7603 -3109 -11118 -13230 -6232 4343 9412 10389 8004 1526 -8325 -21214 -30748 -35418 -29670 -18909 -10328 -3131 237 4236 10696 16414 19648 21273 19147 11765 1928 -8838 -17774 -20687 -14057 -5734 3164 9925 10813 4830 -2452 -10641 -12311 -5267 1782 5620 9610 12781 16887 21171 22366 19031 10854 866 -9348 -13832 -12334 -6895 1175 6359 7643 6309 3117 -3256 -9812 -15301 -19455 -16728 -12183 -9175 -6567 -7291 -6968 -2614 2902 6498 1879 11258 10370 7229 4820 2560 900000 SS 20240214T082338.1Z 8810.349746 40 1 21.71 2 73.02 136.48 88.55 76.16 0.00 1 0.00 1 0 73 1.082e-01 8.692e-02 3.161e-03 2.695e-03 2.913999e-01 1.367258e-03 3.819868e-03 -6.000000e+00 6.022077e-02 223.75 -2.00 3.74 -2.00 313.48 0.00e+00 -1.218971e-03 8.555529e-05 4.557940e-04 -6.000000e+00 2.528196e-03 265.48 -2.00 20.00 -2.00 313.19 0.00e+00 3.374 0.001 302.00 328.00 3 3.0497e+00 3.4218e-03 3.4435e-02 -6.0000e+00 1.4909e-01 7.9849e-01 3.8202e-03 1.4779e-02 -6.0000e+00 1.6323e-01 -6.1937e-01 2.1998e-03 7.4552e-03 -6.0000e+00 9.6572e-02 1.9504e-01 9.1905e-04 2.8573e-03 -6.0000e+00 4.0399e-02 7.9972e-04 1.1086e-03 7.2905e-05 4.4824e-05 -6.0000e+00 2.8878e-03 -4.4562e-02 -1.8108e-03 12 9 9 12 5 1 98.44 22.10 0.48 -0.04456 -0.03623 92 115 1 8 0 233.410 19.93 22.10 11.92 25.58 25.17 17.4 974.53 21343 23266 18529 5229 -13211 -20718 -18298 -11649 -5720 -6052 -12339 -13364 -6306 3013 10205 14588 13087 13240 11762 10989 7343 2552 2143 4846 5909 6552 1404 -10718 -21281 -24364 -20535 -16840 -11844 -15341 -25499 -29349 -21910 -8819 6001 16142 19994 20415 19960 17295 13062 10810 5530 1279 -3121 -3710 -408 3318 6134 7482 7911 8082 7116 3698 -187 -2020 955 4860 9573 11757 6974 -1852 -8670 -11773 -4841 3186 6974 7565 5474 637 -6887 -15555 -23439 -27367 -22370 -14367 -8029 -3213 -1525 1008 5954 8719 11042 11982 10450 6222 651 -6791 -11372 -12990 -8680 -4003 1031 4582 5030 1293 -3031 -7976 -8425 -3194 1098 2970 5435 6764 8875 10552 11009 8702 4354 -832 -5201 -7403 -5801 -3228 1070 2902 3782 3608 2869 -692 -3446 -5769 -8507 -6941 -4602 -3599 -3172 -3119 -3788 -1489 327 1569 1718 3707 2957 1990 900 510 532 13028 14213 11346 3176 -8087 -12711 -11266 -7203 -3536 -3736 -7609 -8270 -3926 1864 6388 9121 8248 8294 7436 6931 4647 1611 1359 3079 3771 4568 981 -7532 -14888 -17038 -14345 -11848 -8339 -10922 -18006 -20949 -15708 -6334 4360 11967 14991 15414 15118 13100 9993 8205 4216 972 -2387 -2845 -317 2606 4852 6044 6424 6571 5829 3041 -153 -1651 774 4033 8114 10159 6064 -1590 -7428 -10217 -4225 2875 6466 7104 5114 588 -6214 -13531 -19977 -23411 -19501 -13015 -7590 -3161 -1548 1041 6259 9438 12133 13269 11587 6769 682 -6984 -11303 -13041 -8997 -4383 1194 5117 5765 1475 -3350 -9331 -9485 -3613 1285 3561 6052 7787 10572 13212 14364 11573 5752 -1070 -6420 -8919 -6980 -3987 1360 3804 4926 4609 3584 -851 -4134 -7411 -10790 -8982 -5708 -4711 -4335 -4359 -5448 -2195 503 2478 2766 5968 4748 3103 1365 747 771 SS 20240214T082935.5Z 8810.353883 42 1 27.58 2 72.36 137.83 87.62 77.23 0.00 1 0.00 1 0 49 1.063e-01 8.390e-02 1.116e-03 9.458e-04 2.952486e-01 4.790654e-04 3.888602e-03 -6.000000e+00 5.921097e-02 223.75 -2.00 3.74 -2.00 313.54 0.00e+00 -1.053297e-03 3.029466e-05 4.480936e-04 -6.000000e+00 2.485346e-03 265.48 -2.00 20.00 -2.00 313.24 0.00e+00 3.256 0.001 302.00 328.00 3 1.3339e+00 1.1996e-03 3.3601e-02 -6.0000e+00 1.4659e-01 7.7158e-01 1.3436e-03 1.5055e-02 -6.0000e+00 1.6044e-01 -6.2118e-01 7.7128e-04 7.5818e-03 -6.0000e+00 9.4924e-02 2.0162e-01 3.2013e-04 2.7826e-03 -6.0000e+00 3.9742e-02 4.9167e-03 1.2408e-03 2.5612e-05 4.3859e-05 -6.0000e+00 2.8362e-03 -4.5596e-02 -1.6006e-03 12 9 8 11 4 0 99.55 22.10 0.46 -0.04560 -0.03627 763 763 1 8 0 35.580 19.93 22.10 12.08 25.58 25.17 17.4 974.69 20636 23363 18876 5730 -12779 -20906 -18782 -12285 -6191 -6491 -12439 -14308 -7109 1639 10100 14294 13228 12642 12055 11063 8118 2797 2150 4953 6030 5958 1385 -9288 -20745 -24254 -20618 -16866 -12319 -14581 -25098 -28565 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