File name: Pandora239s1_Kosetice_20240508_L2Fit_fout2c2d20220901p1-8.txt File generation date: 20240511T143646.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nadezda Zikova Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 239 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora239_OF_v3d20220426.txt Instrument calibration file used: Pandora239s1_CF_v2d20220901.txt Level 1 file used: Pandora239s1_Kosetice_20240508_L1_smca1c2d20220901p1-8.txt Full location name: National Atmospheric Observatory Kosetice Short location name: Kosetice Country of location: Czech Republic Location latitude [deg]: 49.5733 Location longitude [deg]: 15.0803 Location altitude [m]: 534 Local noon date: 20240508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial instrument OoB session based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0356 305.1770 305.3183 305.4597 305.6010 305.7424 305.8837 306.0250 306.1663 306.3076 306.4488 306.5901 306.7314 306.8726 307.0138 307.1551 307.2963 307.4374 307.5786 307.7198 307.8610 308.0021 308.1432 308.2844 308.4255 308.5666 308.7077 308.8487 308.9898 309.1309 309.2719 309.4129 309.5540 309.6950 309.8360 309.9769 310.1179 310.2589 310.3998 310.5408 310.6817 310.8226 310.9635 311.1044 311.2453 311.3861 311.5270 311.6678 311.8087 311.9495 312.0903 312.2311 312.3719 312.5126 312.6534 312.7942 312.9349 313.0756 313.2163 313.3570 313.4977 313.6384 313.7791 313.9197 314.0604 314.2010 314.3416 314.4822 314.6228 314.7634 314.9040 315.0445 315.1851 315.3256 315.4661 315.6066 315.7471 315.8876 316.0281 316.1686 316.3090 316.4495 316.5899 316.7303 316.8707 317.0111 317.1515 317.2918 317.4322 317.5725 317.7129 317.8532 317.9935 318.1338 318.2741 318.4144 318.5546 318.6949 318.8351 318.9753 319.1155 319.2557 319.3959 319.5361 319.6763 319.8164 319.9566 320.0967 320.2368 320.3769 320.5170 320.6571 320.7971 320.9372 321.0772 321.2173 321.3573 321.4973 321.6373 321.7773 321.9172 322.0572 322.1971 322.3371 322.4770 322.6169 322.7568 322.8967 323.0366 323.1764 323.3163 323.4561 323.5959 323.7358 323.8756 324.0153 324.1551 324.2949 324.4346 324.5744 324.7141 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240508T070305.0Z 8894.293808 136 1 9.64 2 56.54 103.17 55.63 99.28 0.00 1 0.00 1 0 25 6.868e-02 4.453e-02 2.475e-03 1.825e-03 2.453269e-01 9.310677e-04 3.089300e-03 -6.000000e+00 3.925658e-02 230.08 -2.00 3.74 -2.00 314.81 0.00e+00 1.264111e-03 7.383140e-05 1.703779e-04 -6.000000e+00 1.666649e-03 274.56 -2.00 20.00 -2.00 314.32 0.00e+00 1.808 0.000 302.00 328.00 3 3.2416e+00 2.3863e-03 2.1563e-02 -6.0000e+00 9.8339e-02 2.9408e-01 2.6545e-03 1.3164e-02 -6.0000e+00 1.0691e-01 -3.3310e-01 1.5146e-03 6.3242e-03 -6.0000e+00 6.3271e-02 1.5152e-01 6.4863e-04 1.7612e-03 -6.0000e+00 2.6367e-02 2.8648e-03 -1.8743e-04 5.0274e-05 2.1717e-05 -6.0000e+00 1.8352e-03 -4.8063e-02 -1.3231e-03 12 9 9 12 5 1 99.40 22.10 0.44 -0.04806 -0.04947 65 188 1 8 0 145.980 19.98 22.10 18.81 25.58 25.17 19.1 961.21 8012 12806 11392 2311 -12779 -20540 -20694 -14397 -9222 -7730 -12543 -15385 -9237 -810 6792 11014 10425 9221 10595 10029 9847 5653 4317 5102 5342 5373 2598 -4113 -10935 -13167 -11807 -8403 -5543 -6417 -14098 -17277 -13458 -5743 3096 9229 11015 11090 11280 10583 9101 8160 5412 2286 -609 -738 942 2263 2941 3668 3240 3187 3154 925 -508 -1127 40 2656 4695 5738 2686 -1378 -5267 -7351 -4346 -628 1013 1800 1362 -239 -3015 -7582 -11677 -14242 -12815 -9193 -5718 -3739 -3268 -2369 139 1608 3378 4155 3966 2840 654 -2398 -5140 -6392 -5305 -3157 -514 1476 1798 367 -1019 -3088 -3517 -1701 203 847 2188 2669 3753 4574 5218 4402 3268 1139 -1038 -2174 -2094 -1120 606 2219 2465 2748 2645 1363 202 -1054 -2339 -2212 -1621 -1148 -1065 -1293 -1451 -1061 -204 233 596 889 772 151 -388 -1262 -1783 3358 5438 4882 988 -5397 -8558 -8758 -6134 -4018 -3398 -5520 -6843 -4198 -377 3256 5448 5267 4753 5459 5242 5126 2955 2269 2734 2914 2968 1448 -2257 -5825 -6918 -6359 -4607 -3140 -3720 -8057 -9729 -7835 -3522 2048 6016 7583 7830 8081 7607 6529 5833 3848 1611 -426 -512 670 1681 2262 2920 2640 2613 2606 770 -417 -918 33 2281 4258 5441 2582 -1255 -4600 -6344 -3846 -604 956 1746 1317 -225 -2935 -6892 -9958 -11804 -10958 -8523 -5720 -3694 -3407 -2552 157 1908 4130 4788 4578 3430 741 -2548 -5129 -6261 -5453 -3505 -618 1775 2262 455 -1199 -3701 -4012 -1990 254 1020 2717 3454 5041 6480 7154 6100 4709 1552 -1321 -2640 -2551 -1417 811 3106 3494 3823 3588 1782 252 -1376 -2938 -2816 -2025 -1516 -1471 -1829 -2086 -1579 -296 352 916 1391 1207 229 -571 -1939 -2699 SS 20240508T072331.4Z 8894.308003 146 1 0.84 2 53.35 107.67 52.42 103.43 0.00 1 0.00 1 0 25 6.546e-02 4.387e-02 1.985e-03 1.517e-03 2.302836e-01 7.777596e-04 2.925082e-03 -6.000000e+00 3.732770e-02 230.08 -2.00 3.74 -2.00 314.55 0.00e+00 1.256463e-03 5.879950e-05 1.320881e-04 -6.000000e+00 1.587571e-03 274.56 -2.00 20.00 -2.00 314.08 0.00e+00 1.671 0.000 302.00 328.00 3 6.3164e-01 1.9887e-03 2.0087e-02 -6.0000e+00 9.3500e-02 2.7427e-01 2.2067e-03 1.2429e-02 -6.0000e+00 1.0175e-01 -3.0098e-01 1.2630e-03 5.9822e-03 -6.0000e+00 6.0209e-02 1.3569e-01 5.4140e-04 1.6602e-03 -6.0000e+00 2.5024e-02 4.5364e-02 -3.0004e-03 4.1777e-05 2.1600e-05 -6.0000e+00 1.7508e-03 -3.6580e-02 -1.5770e-03 12 9 9 12 5 1 69.18 22.10 0.48 -0.03658 -0.05913 79 2604 1 8 0 10.300 19.97 22.10 19.55 25.58 25.17 19.1 961.26 8118 12368 10844 2336 -11310 -19694 -19352 -13206 -8265 -6292 -12414 -14446 -7895 -1110 6159 10143 10096 9421 9801 9970 8651 5487 3829 4466 5139 4712 2812 -4017 -10708 -13052 -11118 -8939 -5871 -7225 -14449 -16928 -13060 -5657 2353 8511 9985 10569 10341 9569 8607 7462 5145 2430 -501 -1379 386 1841 2373 3556 3141 2733 2346 1068 -239 -1149 471 2543 4806 5815 3014 -1409 -5011 -7006 -4399 -714 939 1842 1121 -7 -2860 -6890 -10867 -13854 -11970 -8521 -5716 -3783 -3097 -1807 102 1870 3436 4214 4211 3073 998 -2166 -5163 -6362 -5079 -2418 -606 1841 1901 760 -1017 -2829 -3379 -1722 -32 821 1880 2644 3522 4387 5011 4475 3004 1274 -1060 -2065 -2085 -1142 725 1943 2355 2400 2293 1450 174 -1113 -2413 -2345 -1927 -1421 -1118 -978 -1436 -1183 -322 286 681 1083 713 209 -448 -1227 -1759 3561 5522 4891 1045 -4934 -8551 -8511 -5867 -3768 -2882 -5767 -6723 -3735 -546 3124 5312 5365 5077 5334 5471 4788 3022 2129 2536 2959 2762 1650 -2323 -6004 -7218 -6250 -5167 -3493 -4416 -8668 -9947 -7937 -3635 1644 5858 7278 7861 7838 7286 6510 5636 3847 1791 -367 -1005 288 1430 1910 2947 2663 2338 2030 923 -204 -975 404 2277 4528 5245 2745 -1329 -4510 -6211 -4008 -648 913 1838 1119 -7 -2633 -6426 -9486 -11769 -10407 -8030 -5357 -3818 -3288 -1974 117 2083 3955 4954 4953 3494 1152 -2345 -5250 -6324 -5273 -2692 -678 2223 2407 947 -1207 -3413 -3885 -2033 -38 999 2363 3450 4771 5805 6903 6209 4034 1733 -1348 -2498 -2530 -1438 964 2720 3339 3352 3125 1897 218 -1341 -3032 -2977 -2400 -1866 -1530 -1365 -2042 -1617 -464 427 1036 1674 1106 316 -655 -1742 -2457 SS 20240508T083756.0Z 8894.359675 179 1 16.72 2 42.62 126.86 41.36 121.11 0.00 1 0.00 1 0 25 4.623e-02 2.991e-02 1.657e-03 1.239e-03 2.048179e-01 6.355604e-04 2.545535e-03 -6.000000e+00 2.643604e-02 230.09 -2.00 3.74 -2.00 314.60 0.00e+00 1.310567e-03 4.905906e-05 5.312799e-05 -6.000000e+00 1.121829e-03 274.56 -2.00 20.00 -2.00 314.16 0.00e+00 1.357 0.000 302.00 328.00 3 3.5871e+00 1.6294e-03 1.6961e-02 -6.0000e+00 6.6225e-02 1.8871e-01 1.8098e-03 1.1070e-02 -6.0000e+00 7.1989e-02 -1.8050e-01 1.0322e-03 5.2946e-03 -6.0000e+00 4.2604e-02 8.2483e-02 4.4116e-04 1.5836e-03 -6.0000e+00 1.7761e-02 3.2476e-03 -2.5244e-04 3.4192e-05 1.7907e-05 -6.0000e+00 1.2350e-03 -4.8650e-02 -1.2347e-03 12 9 9 12 5 1 99.82 22.10 0.42 -0.04865 -0.05055 92 154 1 8 0 179.600 19.94 22.10 21.56 25.58 25.17 19.5 964.29 4850 8108 6809 1245 -10638 -15581 -15189 -9828 -5776 -5008 -8985 -11153 -6606 -817 4535 7121 6736 6360 6657 7259 6188 3777 3187 3657 3434 3373 1533 -2374 -7246 -8585 -7092 -5310 -3554 -4797 -10656 -12378 -9629 -3944 1638 5008 6296 5877 6050 5696 5528 4720 3077 1294 -448 -881 570 1331 2005 2446 2074 1744 1445 509 -415 -686 413 2294 3578 4273 2251 -956 -3498 -5028 -2820 -232 466 1224 812 147 -1652 -4604 -7167 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