File name: Pandora239s1_Kosetice_20240510_L2Fit_fwvt1c2d20220901p1-8.txt File generation date: 20240511T130011.2Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c2p1-8 Local principal investigator: Nadezda Zikova Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 239 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora239_OF_v3d20220426.txt Instrument calibration file used: Pandora239s1_CF_v2d20220901.txt Level 1 file used: Pandora239s1_Kosetice_20240510_L1_smca1c2d20220901p1-8.txt Full location name: National Atmospheric Observatory Kosetice Short location name: Kosetice Country of location: Czech Republic Location latitude [deg]: 49.5733 Location longitude [deg]: 15.0803 Location altitude [m]: 534 Local noon date: 20240510 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial instrument OoB session based on session 1 First and last pixel inside fitting window: 1614 1763 Nominal wavelengths inside fitting window [nm]: 492.0436 492.1650 492.2863 492.4077 492.5290 492.6503 492.7716 492.8929 493.0142 493.1354 493.2567 493.3779 493.4991 493.6203 493.7414 493.8626 493.9837 494.1049 494.2260 494.3470 494.4681 494.5892 494.7102 494.8312 494.9522 495.0732 495.1942 495.3151 495.4361 495.5570 495.6779 495.7988 495.9197 496.0405 496.1614 496.2822 496.4030 496.5238 496.6446 496.7653 496.8860 497.0068 497.1275 497.2482 497.3688 497.4895 497.6101 497.7308 497.8514 497.9719 498.0925 498.2131 498.3336 498.4541 498.5746 498.6951 498.8156 498.9361 499.0565 499.1769 499.2973 499.4177 499.5381 499.6584 499.7788 499.8991 500.0194 500.1397 500.2600 500.3802 500.5005 500.6207 500.7409 500.8611 500.9813 501.1014 501.2216 501.3417 501.4618 501.5819 501.7019 501.8220 501.9420 502.0621 502.1821 502.3021 502.4220 502.5420 502.6619 502.7818 502.9018 503.0216 503.1415 503.2614 503.3812 503.5010 503.6208 503.7406 503.8604 503.9801 504.0999 504.2196 504.3393 504.4590 504.5787 504.6983 504.8180 504.9376 505.0572 505.1768 505.2963 505.4159 505.5354 505.6550 505.7745 505.8939 506.0134 506.1329 506.2523 506.3717 506.4911 506.6105 506.7299 506.8492 506.9686 507.0879 507.2072 507.3265 507.4457 507.5650 507.6842 507.8035 507.9227 508.0418 508.1610 508.2802 508.3993 508.5184 508.6375 508.7566 508.8757 508.9947 509.1137 509.2328 509.3518 509.4707 509.5897 509.7087 509.8276 509.9465 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Temperature at electronics board 1 [°C], 999=no temperature signal Column 99: Temperature at electronics board 2 [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-401: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20240510T032951.7Z 8896.145737 30 1 52.00 2 89.72 62.35 95.84 35.91 0.00 1 0.00 1 0 29 6.331e-02 6.426e-02 2.128e-02 2.098e-02 1.286245e+04 1.322908e+03 6.840612e+02 -6.000000e+00 3.283510e+03 274.78 -2.00 20.00 -2.00 505.43 0.00e+00 2.458190e-03 5.613124e-04 1.323798e-04 -6.000000e+00 1.715641e-03 274.78 -2.00 20.00 -2.00 501.37 0.00e+00 -8.447316e-01 3.915104e-01 1.426302e-01 -6.000000e+00 1.238225e+00 230.27 -2.00 3.74 -2.00 502.78 0.00e+00 20.254 0.175 489.00 513.00 1 8.3254e+00 2.9700e-02 3.7824e-02 -6.0000e+00 9.4470e-02 1.5845e-02 7.6107e-03 3.5257e-03 -6.0000e+00 2.4773e-02 3.2014e-05 -1.1874e-03 1.7052e-03 1.1315e-04 -6.0000e+00 5.5440e-03 5.6115e-02 -1.5395e-04 12 9 8 11 4 0 18.17 22.11 15.77 0.05612 0.04788 13 2 3 2 0 4000.000 20.01 22.11 9.89 25.58 25.17 18.6 960.75 -7406 5465 -13234 -2205 694 1591 2824 14793 -1171 4729 -165 11285 -2483 1825 107 -7745 -493 -8170 6839 -3465 3565 1096 -1921 2257 2875 3692 4050 3029 1374 -8931 -2738 1640 10089 -2269 -2133 12692 -4718 -2866 6430 778 2272 2273 -910 9735 9468 -19407 3661 31 3966 -5057 1231 -9805 8033 1938 -7406 -1636 -525 -5976 2984 6027 10269 8983 -3868 6194 514 -1563 -5502 1584 -2748 8463 -2670 2059 3412 3654 2335 10515 1033 -1309 -5234 -13283 -5856 435 -2033 -7421 -3053 -7385 -3287 1905 -1087 2431 3735 4712 3276 6895 4223 -5121 -5391 -4381 3249 -2314 228 -6257 -1835 5512 7116 151 2124 -6639 -12366 -16341 9933 18554 6096 -8 9039 10 16031 856 9807 2892 -6424 -3538 -2797 -2619 -2638 13500 3078 2564 -9651 2750 273 -483 -5383 8065 -1950 5834 2044 883 8736 -8525 -3636 1157 -1919 -2841 5751 -6084 4721 -7854 6150 1720 -6560 4335 -13172 -2051 644 1497 2680 12595 -1076 4374 -146 9550 -2187 1644 91 -7153 -431 -7919 5873 -3337 3208 1014 -1835 2081 2660 3398 3708 2773 1238 -8615 -2463 1426 8248 -2192 -2132 10978 -4805 -2837 5745 732 2120 2150 -903 8821 8714 -23938 3566 31 3751 -5094 1129 -9846 6720 1753 -7624 -1648 -536 -6502 2968 5804 9532 8537 -4208 6093 531 -1624 -5864 1558 -2790 7575 -2669 1987 3291 3571 2333 9594 1016 -1298 -5347 -14661 -6056 428 -2064 -8051 -3230 -8234 -3509 1919 -1126 2441 3745 4769 3404 6826 4174 -5385 -5498 -4295 2888 -2152 209 -6312 -1865 5500 7213 165 2261 -7058 -13890 -19435 9974 17282 6478 -9 9405 10 16022 934 9706 3015 -7198 -3777 -2957 -2796 -2835 13364 3155 2635 -11210 2823 283 -494 -5755 7520 -2024 5757 2149 953 8851 -10415 -4265 1303 -2243 -3358 6215 -7307 4978 -9191 6213 1831 SQ 20240510T033625.6Z 8896.150296 36 1 52.01 2 88.77 63.60 95.23 37.17 0.00 1 0.00 1 0 22 1.188e-02 1.163e-02 2.041e-03 2.027e-03 1.121157e+04 1.292127e+02 7.479715e+02 -6.000000e+00 6.161088e+02 274.78 -2.00 20.00 -2.00 505.47 0.00e+00 2.875631e-03 5.482701e-05 1.607000e-04 -6.000000e+00 3.221186e-04 274.78 -2.00 20.00 -2.00 501.20 0.00e+00 1.323502e+00 3.863263e-02 9.535072e-02 -6.000000e+00 2.331331e-01 230.27 -2.00 3.74 -2.00 502.69 0.00e+00 18.229 0.127 489.00 513.00 1 5.5030e+00 2.9407e-03 3.1117e-02 -6.0000e+00 1.7777e-02 -5.3875e-02 7.4580e-04 2.7468e-03 -6.0000e+00 4.6799e-03 6.0130e-04 6.7433e-04 1.6704e-04 1.1465e-04 -6.0000e+00 1.0408e-03 1.6139e-02 -1.6260e-04 12 9 8 11 4 0 65.29 22.10 5.80 0.01614 0.02082 13 2 3 2 0 4000.000 20.01 22.10 9.95 25.58 25.17 18.6 961.33 -3661 -2451 -2085 -542 652 799 1995 2260 1172 1353 247 1008 -246 -1317 -1580 -1539 -648 -256 735 752 372 815 209 899 646 1874 981 756 -171 -1911 -1730 -1889 -785 381 908 1763 -160 -100 352 280 90 116 549 1339 1543 296 1167 942 467 -682 -766 -2604 -1681 -1653 -1162 117 526 871 901 1253 1111 1981 1081 1151 422 327 -245 -158 -835 -780 -1052 -1076 -303 -265 -401 207 -551 -1413 -1869 -1912 -2374 -1211 -1261 -918 -956 -484 -876 -391 -737 -739 -16 412 962 1347 1377 806 188 -826 -984 -1897 -2154 -2369 -1110 290 448 182 -419 -960 -1510 -1134 781 1822 701 1276 2440 2109 2743 1640 1659 736 282 191 445 687 248 939 957 432 292 209 -155 -393 -1056 -615 -1470 -59 -282 268 634 100 -65 183 181 439 1117 472 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1.961916e-05 1.132105e-04 -6.000000e+00 1.803448e-04 274.79 -2.00 20.00 -2.00 500.91 0.00e+00 1.451553e+00 1.408115e-02 7.491402e-02 -6.000000e+00 1.305315e-01 230.28 -2.00 3.74 -2.00 502.43 0.00e+00 15.335 0.076 489.00 513.00 1 4.0972e+00 1.0716e-03 2.3950e-02 -6.0000e+00 9.9532e-03 -4.0092e-02 2.7524e-04 2.1923e-03 -6.0000e+00 2.6204e-03 3.6242e-03 4.5667e-04 6.0549e-05 1.0197e-04 -6.0000e+00 5.8271e-04 1.0429e-02 -1.3423e-04 12 9 8 11 36 0 60.35 22.11 2.69 0.01043 0.01360 20 3 3 2 0 2599.900 20.02 22.11 10.27 25.58 25.17 18.7 962.66 -1767 -1387 -791 -58 481 672 1078 1220 942 615 365 263 -250 -698 -724 -761 -305 -152 256 291 344 390 248 487 522 820 726 386 -265 -1007 -1001 -1033 -537 37 561 718 310 31 -69 -211 -177 198 313 627 735 630 778 589 238 -265 -873 -1331 -1425 -1135 -789 -16 402 424 570 427 678 610 725 638 386 176 235 -94 -525 -777 -838 -592 -288 73 -158 -100 -400 -647 -940 -1037 -1033 -538 -704 -618 -301 -362 -416 -638 -463 -261 -30 335 814 779 809 650 372 -435 -920 -1283 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