File name: Pandora239s1_Kosetice_20240607_L2Fit_fout2c2d20220901p1-8.txt File generation date: 20240607T230125.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nadezda Zikova Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 239 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora239_OF_v3d20220426.txt Instrument calibration file used: Pandora239s1_CF_v2d20220901.txt Level 1 file used: Pandora239s1_Kosetice_20240607_L1_smca1c2d20220901p1-8.txt Full location name: National Atmospheric Observatory Kosetice Short location name: Kosetice Country of location: Czech Republic Location latitude [deg]: 49.5733 Location longitude [deg]: 15.0803 Location altitude [m]: 534 Local noon date: 20240607 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial instrument OoB session based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0356 305.1770 305.3183 305.4597 305.6010 305.7424 305.8837 306.0250 306.1663 306.3076 306.4488 306.5901 306.7314 306.8726 307.0138 307.1551 307.2963 307.4374 307.5786 307.7198 307.8610 308.0021 308.1432 308.2844 308.4255 308.5666 308.7077 308.8487 308.9898 309.1309 309.2719 309.4129 309.5540 309.6950 309.8360 309.9769 310.1179 310.2589 310.3998 310.5408 310.6817 310.8226 310.9635 311.1044 311.2453 311.3861 311.5270 311.6678 311.8087 311.9495 312.0903 312.2311 312.3719 312.5126 312.6534 312.7942 312.9349 313.0756 313.2163 313.3570 313.4977 313.6384 313.7791 313.9197 314.0604 314.2010 314.3416 314.4822 314.6228 314.7634 314.9040 315.0445 315.1851 315.3256 315.4661 315.6066 315.7471 315.8876 316.0281 316.1686 316.3090 316.4495 316.5899 316.7303 316.8707 317.0111 317.1515 317.2918 317.4322 317.5725 317.7129 317.8532 317.9935 318.1338 318.2741 318.4144 318.5546 318.6949 318.8351 318.9753 319.1155 319.2557 319.3959 319.5361 319.6763 319.8164 319.9566 320.0967 320.2368 320.3769 320.5170 320.6571 320.7971 320.9372 321.0772 321.2173 321.3573 321.4973 321.6373 321.7773 321.9172 322.0572 322.1971 322.3371 322.4770 322.6169 322.7568 322.8967 323.0366 323.1764 323.3163 323.4561 323.5959 323.7358 323.8756 324.0153 324.1551 324.2949 324.4346 324.5744 324.7141 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240607T030237.1Z 8924.126818 35 1 26.98 2 89.72 53.74 90.20 44.69 0.00 1 0.00 1 0 185 1.328e-01 1.268e-01 1.433e-02 1.259e-02 9.645550e-02 6.573191e-03 7.732492e-04 -6.000000e+00 7.676842e-02 232.51 -2.00 3.74 -2.00 313.38 0.00e+00 8.500716e-03 4.230923e-04 3.862627e-04 -6.000000e+00 3.288387e-03 278.05 -2.00 20.00 -2.00 313.01 0.00e+00 20.131 0.172 302.00 328.00 3 -1.0207e+01 1.6779e-02 2.4468e-01 -6.0000e+00 1.9326e-01 2.1683e+00 1.8496e-02 2.8579e-02 -6.0000e+00 2.0942e-01 -1.7212e-01 1.0699e-02 2.5073e-03 -6.0000e+00 1.2388e-01 -2.7562e-03 4.5256e-03 5.4821e-03 -6.0000e+00 5.2228e-02 1.0767e-04 5.1498e-03 3.4126e-04 2.4340e-05 -6.0000e+00 3.5746e-03 -3.2825e-03 -3.9636e-03 12 9 8 11 4 0 68.24 22.42 6.66 -0.00328 0.03542 48 48 1 8 0 562.020 20.00 22.42 21.11 26.00 25.39 20.0 954.38 11143 15486 -2535 -9945 -23852 -23405 -13897 -12476 -17439 -20711 -13611 -8067 5824 12500 21214 14937 21704 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12896 7111 -2090 -8362 -8967 -4950 -2489 -35 2030 308 -1761 -489 -730 -2330 -5425 -227 8461 12392 13278 9027 -6153 -11952 -18836 -17168 997 7975 8246 6285 3160 -10970 -21523 -35472 -33977 -32957 -23518 -11300 -4403 -1093 4356 11426 19333 21422 21703 23784 13859 7062 -7379 -17771 -15277 -13586 -7074 3384 10882 11958 7453 1540 -7604 -12161 -5509 4012 9180 14038 15722 20089 26019 25316 23951 15218 889 -9611 -14897 -15622 -9134 -2266 8464 10016 6715 8805 -174 -13819 -20781 -22754 -20206 -15379 -10935 -10453 -7851 -4527 -4809 2539 6292 6851 10087 12151 9431 2804 1937 -2406 900000 SS 20240607T052355.6Z 8924.224949 106 1 9.52 2 68.85 79.25 71.79 68.65 0.00 1 0.00 1 0 33 1.028e-01 8.128e-02 5.751e-04 4.870e-04 2.672649e-01 2.602751e-04 3.773493e-03 -6.000000e+00 5.996211e-02 232.52 -2.00 3.74 -2.00 313.62 0.00e+00 -5.373557e-04 1.660975e-05 4.475951e-04 -6.000000e+00 2.543015e-03 278.06 -2.00 20.00 -2.00 313.18 0.00e+00 2.746 0.000 302.00 328.00 3 -5.7873e-01 6.6261e-04 2.9575e-02 -6.0000e+00 1.5101e-01 6.4545e-01 7.2850e-04 1.4550e-02 -6.0000e+00 1.6312e-01 -5.4902e-01 4.1933e-04 7.3183e-03 -6.0000e+00 9.6464e-02 1.8781e-01 1.7904e-04 2.6654e-03 -6.0000e+00 4.1023e-02 5.4056e-02 -4.6575e-03 1.3319e-05 4.5013e-05 -6.0000e+00 2.7609e-03 -2.6012e-02 -2.2616e-03 12 9 8 11 4 0 25.22 22.42 0.51 -0.02601 -0.06101 2424 2019 1 8 0 3.810 19.99 22.42 23.12 26.00 25.39 19.9 956.62 19341 21535 17351 4170 -13495 -21011 -18662 -11903 -6124 -6515 -12801 -14207 -7058 1203 9256 13097 12156 11715 11090 10633 7809 3073 2755 4980 6014 5770 1441 -9163 -19773 -23094 -20174 -16576 -12279 -14660 -25158 -27913 -20851 -8977 4966 15245 18888 19043 18746 16498 13532 10903 6339 1525 -2445 -3540 -91 2730 4943 7046 6847 6576 6179 3513 232 -1102 946 5208 9402 11171 6336 -2109 -8390 -10774 -5394 1961 5671 6596 4428 1030 -5390 -13974 -21412 -25175 -21140 -14071 -8219 -3706 -1985 278 4522 7607 9693 10775 9865 6437 921 -5166 -10915 -12273 -8994 -4338 504 4272 4376 1325 -2393 -6479 -7386 -3182 661 2327 4469 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20240607T052405.3Z 8924.225061 106 2 9.73 2 68.83 79.28 71.77 68.67 0.00 1 0.00 1 0 25 1.027e-01 8.133e-02 5.603e-04 4.752e-04 2.668445e-01 2.537871e-04 3.775681e-03 -6.000000e+00 5.994874e-02 232.52 -2.00 3.74 -2.00 313.60 0.00e+00 -5.669510e-04 1.620296e-05 4.465812e-04 -6.000000e+00 2.541049e-03 278.06 -2.00 20.00 -2.00 313.17 0.00e+00 2.743 0.000 302.00 328.00 3 -6.0935e-01 6.4599e-04 2.9564e-02 -6.0000e+00 1.5098e-01 6.4278e-01 7.1051e-04 1.4576e-02 -6.0000e+00 1.6305e-01 -5.4726e-01 4.0884e-04 7.3366e-03 -6.0000e+00 9.6419e-02 1.8756e-01 1.7424e-04 2.6879e-03 -6.0000e+00 4.1031e-02 5.5958e-02 -4.0113e-03 1.2985e-05 4.4702e-05 -6.0000e+00 2.7577e-03 -2.7937e-02 -2.1499e-03 12 9 8 11 4 0 44.81 22.42 0.50 -0.02794 -0.05808 2424 2019 1 8 0 3.810 19.99 22.42 23.12 26.00 25.39 19.9 956.62 18965 21392 17363 4130 -13444 -21125 -18856 -12058 -6205 -6556 -12910 -14259 -7121 981 9122 13108 12158 11586 11065 10580 7945 2951 2629 4900 5940 5784 1589 -8995 -19610 -23004 -20246 -16654 -12399 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