File name: Pandora239s1_Kosetice_20240610_L2Fit_fout2c2d20220901p1-8.txt File generation date: 20240610T230403.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nadezda Zikova Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 239 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora239_OF_v3d20220426.txt Instrument calibration file used: Pandora239s1_CF_v2d20220901.txt Level 1 file used: Pandora239s1_Kosetice_20240610_L1_smca1c2d20220901p1-8.txt Full location name: National Atmospheric Observatory Kosetice Short location name: Kosetice Country of location: Czech Republic Location latitude [deg]: 49.5733 Location longitude [deg]: 15.0803 Location altitude [m]: 534 Local noon date: 20240610 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial instrument OoB session based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0356 305.1770 305.3183 305.4597 305.6010 305.7424 305.8837 306.0250 306.1663 306.3076 306.4488 306.5901 306.7314 306.8726 307.0138 307.1551 307.2963 307.4374 307.5786 307.7198 307.8610 308.0021 308.1432 308.2844 308.4255 308.5666 308.7077 308.8487 308.9898 309.1309 309.2719 309.4129 309.5540 309.6950 309.8360 309.9769 310.1179 310.2589 310.3998 310.5408 310.6817 310.8226 310.9635 311.1044 311.2453 311.3861 311.5270 311.6678 311.8087 311.9495 312.0903 312.2311 312.3719 312.5126 312.6534 312.7942 312.9349 313.0756 313.2163 313.3570 313.4977 313.6384 313.7791 313.9197 314.0604 314.2010 314.3416 314.4822 314.6228 314.7634 314.9040 315.0445 315.1851 315.3256 315.4661 315.6066 315.7471 315.8876 316.0281 316.1686 316.3090 316.4495 316.5899 316.7303 316.8707 317.0111 317.1515 317.2918 317.4322 317.5725 317.7129 317.8532 317.9935 318.1338 318.2741 318.4144 318.5546 318.6949 318.8351 318.9753 319.1155 319.2557 319.3959 319.5361 319.6763 319.8164 319.9566 320.0967 320.2368 320.3769 320.5170 320.6571 320.7971 320.9372 321.0772 321.2173 321.3573 321.4973 321.6373 321.7773 321.9172 322.0572 322.1971 322.3371 322.4770 322.6169 322.7568 322.8967 323.0366 323.1764 323.3163 323.4561 323.5959 323.7358 323.8756 324.0153 324.1551 324.2949 324.4346 324.5744 324.7141 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240610T112309.1Z 8927.474411 273 1 26.85 2 26.92 192.20 46.15 108.93 0.00 1 0.00 1 0 25 4.133e-02 2.935e-02 1.444e-03 1.150e-03 1.670398e-01 5.998021e-04 2.122584e-03 -6.000000e+00 2.383353e-02 232.76 -2.00 3.74 -2.00 314.18 0.00e+00 1.274442e-03 4.288749e-05 4.767888e-05 -6.000000e+00 1.019124e-03 278.44 -2.00 20.00 -2.00 313.71 0.00e+00 1.121 0.000 302.00 328.00 3 4.2065e+00 1.5416e-03 1.4104e-02 -6.0000e+00 6.0022e-02 1.6644e-01 1.6994e-03 9.2899e-03 -6.0000e+00 6.5101e-02 -1.4124e-01 9.7460e-04 4.3888e-03 -6.0000e+00 3.8524e-02 5.6481e-02 4.1470e-04 1.2950e-03 -6.0000e+00 1.6005e-02 2.3513e-03 -2.7761e-03 3.1744e-05 1.6010e-05 -6.0000e+00 1.1057e-03 -4.5848e-02 -1.5068e-03 12 9 8 11 4 0 88.39 22.45 0.44 -0.04585 -0.06671 96 96 1 8 0 279.570 20.00 22.45 23.20 26.00 25.39 19.9 944.50 5725 8316 7450 2059 -8226 -12565 -11949 -7444 -3364 -3023 -6929 -8506 -5121 -364 3973 5994 5396 5295 5598 6046 5508 3011 2752 2762 2852 3140 1510 -2718 -6366 -7735 -7113 -5343 -3626 -4390 -10251 -12247 -9547 -4394 975 4057 5108 5291 5345 5104 4846 4164 2854 1170 -492 -784 351 834 1827 2547 1911 1833 1626 536 -229 -610 574 2120 3371 4426 2448 -526 -3174 -5011 -2529 -105 846 1632 132 674 -1287 -4107 -6854 -9101 -8375 -5879 -3977 -2690 -2572 -1551 99 1053 2238 2708 3019 2313 1115 -908 -2963 -4021 -3254 -1853 -56 1444 1734 931 -107 -1745 -2548 -1437 -674 -129 695 1094 1899 2780 3409 3272 2518 1071 -482 -1469 -1427 -1081 -28 1109 1289 1465 1441 745 35 -953 -2027 -1823 -1447 -1092 -936 -679 -1124 -621 -243 452 -836 1155 1015 758 27 -506 -1228 2635 3998 3634 981 -3732 -5445 -5240 -3374 -1595 -1483 -3397 -4121 -2573 -193 2230 3225 2966 2929 3141 3434 3166 1727 1573 1625 1718 1921 931 -1624 -3935 -4621 -4319 -3320 -2337 -2909 -6621 -7672 -6245 -2824 700 3273 4040 4298 4424 4245 3988 3415 2505 998 -408 -638 292 727 1640 2165 1665 1606 1441 475 -200 -530 507 1959 3296 4502 2496 -500 -2818 -4716 -2217 -102 881 1758 144 707 -1283 -3771 -6311 -7978 -7461 -5675 -3836 -2802 -2833 -1624 109 1233 2725 3389 3783 2801 1256 -1024 -3080 -4012 -3358 -2059 -62 1739 2188 1154 -126 -1930 -2918 -1694 -795 -159 887 1451 2412 3681 4671 4482 3303 1413 -587 -1691 -1637 -1291 -36 1500 1657 2007 1930 957 43 -1114 -2455 -2203 -1699 -1347 -1199 -884 -1482 -841 -323 626 -1201 1667 1474 1073 37 -681 -1630 SS 20240610T113420.9Z 8927.482186 275 1 16.61 2 27.39 197.75 44.51 111.64 0.00 1 0.00 1 0 17 4.086e-02 2.880e-02 1.134e-03 9.055e-04 1.642622e-01 4.717834e-04 2.053012e-03 -6.000000e+00 2.361380e-02 232.76 -2.00 3.74 -2.00 314.13 0.00e+00 1.218622e-03 3.360384e-05 3.422460e-05 -6.000000e+00 1.007562e-03 278.44 -2.00 20.00 -2.00 313.67 0.00e+00 1.126 0.000 302.00 328.00 3 3.2531e+00 1.2125e-03 1.3999e-02 -6.0000e+00 5.9471e-02 1.5820e-01 1.3384e-03 9.0819e-03 -6.0000e+00 6.4459e-02 -1.3747e-01 7.6633e-04 4.2819e-03 -6.0000e+00 3.8149e-02 5.5931e-02 3.2501e-04 1.2852e-03 -6.0000e+00 1.5879e-02 6.1248e-03 -5.6440e-04 2.5009e-05 1.4964e-05 -6.0000e+00 1.0923e-03 -5.2146e-02 -1.2139e-03 12 9 9 12 5 1 99.96 22.45 0.43 -0.05215 -0.05639 171 279 1 8 0 96.550 20.00 22.45 23.37 26.00 25.39 20.3 948.84 5854 8548 7423 2298 -7564 -12405 -11934 -7380 -3566 -3064 -7069 -8336 -5134 -615 3873 5961 5530 5512 5514 5964 5671 3121 2750 2732 2741 2935 1366 -1994 -6432 -7804 -6940 -5536 -3591 -4658 -10145 -12004 -9785 -4487 451 4097 5218 5327 5540 4999 4727 3948 2740 1202 -333 -1000 207 967 1690 2082 1900 1708 1429 646 -204 -335 512 1852 3366 4204 2256 -519 -3076 -4456 -2817 -417 592 1519 1204 623 -1290 -3938 -6501 -8840 -7844 -5798 -3936 -2685 -2750 -1811 -131 892 1966 2858 3091 2400 986 -775 -2860 -3711 -3071 -1828 -301 1258 1583 926 -284 -1931 -2316 -1428 -670 -63 722 1032 1986 2675 3355 3138 2335 1033 -512 -1329 -1652 -1075 96 1219 1059 1395 1189 622 120 -882 -1913 -1719 -1518 -1002 -886 -811 -1153 -697 -148 310 640 984 865 525 -87 -700 -1192 2706 4128 3650 1103 -3443 -5410 -5268 -3365 -1708 -1518 -3506 -4066 -2595 -329 2187 3226 3053 3058 3112 3407 3274 1799 1582 1617 1663 1811 850 -1192 -4010 -4696 -4229 -3462 -2323 -3110 -6582 -7536 -6441 -2897 327 3318 4143 4348 4602 4185 3917 3264 2220 1030 -277 -820 173 845 1398 1785 1664 1505 1274 576 -179 -292 455 1724 3310 4308 2316 -496 -2741 -3839 -2487 -405 621 1646 1308 657 -1293 -3630 -5998 -7771 -6987 -5153 -3813 -2811 -3048 -1910 -145 1052 2414 3591 3891 2920 1117 -877 -2984 -3711 -3181 -2042 -336 1525 2010 1153 -336 -2148 -2660 -1564 -794 -78 927 1279 2535 3566 4624 4324 3080 1368 -626 -1533 -1908 -1292 123 1538 1373 1786 1605 803 147 -1036 -2327 -2088 -1796 -1242 -1140 -1061 -1527 -950 -197 431 910 1430 1263 748 -121 -948 -1590 SS 20240610T114209.6Z 8927.487612 279 1 27.29 2 27.82 201.52 43.38 113.59 0.00 1 0.00 1 0 17 4.226e-02 3.015e-02 7.281e-04 5.854e-04 1.651373e-01 3.060471e-04 2.074106e-03 -6.000000e+00 2.441212e-02 232.76 -2.00 3.74 -2.00 314.08 0.00e+00 1.164104e-03 2.153720e-05 4.042379e-05 -6.000000e+00 1.042089e-03 278.44 -2.00 20.00 -2.00 313.62 0.00e+00 1.130 0.000 302.00 328.00 3 2.8851e+00 7.8652e-04 1.4068e-02 -6.0000e+00 6.1481e-02 1.6144e-01 8.6831e-04 9.1273e-03 -6.0000e+00 6.6648e-02 -1.4320e-01 4.9673e-04 4.3119e-03 -6.0000e+00 3.9444e-02 5.8217e-02 2.0965e-04 1.2665e-03 -6.0000e+00 1.6409e-02 8.8118e-03 -1.0515e-03 1.6180e-05 1.5491e-05 -6.0000e+00 1.1299e-03 -4.8625e-02 -1.2128e-03 12 9 8 11 4 0 94.47 22.45 0.43 -0.04863 -0.05653 396 396 1 8 0 68.900 20.00 22.45 24.10 26.00 25.39 20.5 951.14 6076 8652 7859 2164 -7659 -12645 -12043 -7837 -3737 -2823 -6918 -8716 -5333 -540 3890 6276 5751 5373 5615 6169 5470 3259 3101 2958 3160 3003 1606 -2235 -6571 -8206 -7217 -5846 -3982 -5058 -10503 -12327 -9950 -4942 556 4225 5266 5513 5572 5241 4919 4236 2953 1237 -438 -1014 304 955 1776 2258 2015 1773 1571 658 -156 -533 607 1923 3555 4389 2405 -512 -3150 -4765 -2919 -387 939 1492 1192 587 -1262 -4080 -6784 -9156 -8209 -6118 -4251 -2798 -2589 -1845 -111 1161 2297 2976 3184 2393 1133 -1001 -3084 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