File name: Pandora239s1_Kosetice_20240627_L2Fit_fout2c2d20220901p1-8.txt File generation date: 20240627T231008.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Nadezda Zikova Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 239 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora239_OF_v3d20220426.txt Instrument calibration file used: Pandora239s1_CF_v2d20220901.txt Level 1 file used: Pandora239s1_Kosetice_20240627_L1_smca1c2d20220901p1-8.txt Full location name: National Atmospheric Observatory Kosetice Short location name: Kosetice Country of location: Czech Republic Location latitude [deg]: 49.5733 Location longitude [deg]: 15.0803 Location altitude [m]: 534 Local noon date: 20240627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Initial instrument OoB session based on session 1 First and last pixel inside fitting window: 197 339 Nominal wavelengths inside fitting window [nm]: 305.0356 305.1770 305.3183 305.4597 305.6010 305.7424 305.8837 306.0250 306.1663 306.3076 306.4488 306.5901 306.7314 306.8726 307.0138 307.1551 307.2963 307.4374 307.5786 307.7198 307.8610 308.0021 308.1432 308.2844 308.4255 308.5666 308.7077 308.8487 308.9898 309.1309 309.2719 309.4129 309.5540 309.6950 309.8360 309.9769 310.1179 310.2589 310.3998 310.5408 310.6817 310.8226 310.9635 311.1044 311.2453 311.3861 311.5270 311.6678 311.8087 311.9495 312.0903 312.2311 312.3719 312.5126 312.6534 312.7942 312.9349 313.0756 313.2163 313.3570 313.4977 313.6384 313.7791 313.9197 314.0604 314.2010 314.3416 314.4822 314.6228 314.7634 314.9040 315.0445 315.1851 315.3256 315.4661 315.6066 315.7471 315.8876 316.0281 316.1686 316.3090 316.4495 316.5899 316.7303 316.8707 317.0111 317.1515 317.2918 317.4322 317.5725 317.7129 317.8532 317.9935 318.1338 318.2741 318.4144 318.5546 318.6949 318.8351 318.9753 319.1155 319.2557 319.3959 319.5361 319.6763 319.8164 319.9566 320.0967 320.2368 320.3769 320.5170 320.6571 320.7971 320.9372 321.0772 321.2173 321.3573 321.4973 321.6373 321.7773 321.9172 322.0572 322.1971 322.3371 322.4770 322.6169 322.7568 322.8967 323.0366 323.1764 323.3163 323.4561 323.5959 323.7358 323.8756 324.0153 324.1551 324.2949 324.4346 324.5744 324.7141 324.8538 324.9935 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Temperature at electronics board 1 [°C], 999=no temperature signal Column 98: Temperature at electronics board 2 [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-243: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 244-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240627T052450.0Z 8944.225579 195 1 26.86 2 69.02 78.29 63.33 209.45 0.00 1 0.00 1 0 57 9.441e-02 6.194e-02 6.874e-03 4.730e-03 2.930583e-01 2.424368e-03 3.902707e-03 -6.000000e+00 5.455360e-02 233.22 -2.00 3.74 -2.00 315.37 0.00e+00 -5.553255e-04 2.105941e-04 6.419330e-04 -6.000000e+00 2.344281e-03 280.11 -2.00 20.00 -2.00 314.71 0.00e+00 2.766 0.000 302.00 328.00 3 3.7350e+00 6.2560e-03 3.0459e-02 -6.0000e+00 1.3747e-01 6.1152e-01 6.9892e-03 1.5880e-02 -6.0000e+00 1.4899e-01 -5.7184e-01 3.9557e-03 7.6919e-03 -6.0000e+00 8.8217e-02 2.1451e-01 1.6962e-03 2.6989e-03 -6.0000e+00 3.6684e-02 6.7473e-04 9.5000e-05 1.3338e-04 3.7809e-05 -6.0000e+00 2.5261e-03 -4.8372e-02 -1.5180e-03 12 9 8 11 4 0 99.97 22.56 0.47 -0.04837 -0.04766 647 647 1 8 0 41.510 20.00 22.56 26.71 26.11 25.39 20.5 951.26 15030 19955 16531 4956 -13454 -21846 -21129 -13425 -9959 -7858 -12933 -15610 -9220 1020 7718 13720 11196 11913 11947 11276 8108 3493 2123 2106 5932 5443 4498 -8501 -15822 -21747 -18690 -16064 -10308 -11176 -20479 -24211 -19526 -7502 4659 14300 17184 19301 16878 16419 11358 10627 6253 2470 -999 -2751 287 2221 6683 6583 6571 5040 6272 2873 939 -2630 765 4364 7395 10529 5618 -1667 -8324 -10106 -5429 2005 3959 5283 3066 654 -4840 -12468 -18773 -22056 -19683 -13703 -8381 -4453 -2856 -1527 2789 4334 7186 7579 8643 4387 451 -5227 -8687 -11110 -8044 -4761 -902 2893 3291 756 -2217 -5753 -6486 -3301 -289 1672 2794 4821 5799 7467 7773 6411 4236 386 -2022 -5167 -3576 -2660 1046 1888 2720 3097 2696 -181 -1710 -3287 -5517 -4436 -3464 -2501 -2181 -1474 -2557 -1857 -56 1157 1423 2035 2236 900 -45 -957 -944 6413 8422 7028 2101 -5740 -9246 -9015 -5671 -4337 -3386 -5533 -6720 -4012 440 3409 6593 5531 5835 5856 5542 4025 1730 1057 1078 2975 2757 2222 -4320 -7743 -10842 -9373 -8232 -5273 -5764 -10468 -12274 -10136 -3926 2538 8089 10059 11258 10142 9742 6892 6341 3739 1467 -593 -1647 175 1395 4173 4278 4340 3396 4189 1942 623 -1770 558 3263 5765 8373 4581 -1329 -6573 -7915 -4320 1668 3489 4730 2762 573 -4101 -10116 -14626 -16949 -15606 -11535 -7472 -4194 -2801 -1541 2885 4702 7915 8516 9557 4808 471 -5258 -8315 -10680 -8022 -5088 -1033 3530 4181 954 -2690 -6636 -7147 -3691 -341 2024 3501 6207 7795 10550 11524 9676 6251 549 -2705 -6764 -4645 -3595 1463 2771 3998 4449 3783 -248 -2261 -4203 -6884 -5607 -4669 -3563 -3254 -2240 -4005 -3016 -95 2022 2531 3675 4008 1574 -77 -1573 -1524 SS 20240627T055727.2Z 8944.248232 205 1 11.08 2 63.80 84.15 66.03 217.61 0.00 1 0.00 1 0 41 8.926e-02 6.596e-02 5.210e-04 4.199e-04 2.487368e-01 2.218085e-04 3.298003e-03 -6.000000e+00 5.228657e-02 233.22 -2.00 3.74 -2.00 314.11 0.00e+00 3.727277e-04 1.548666e-05 2.910638e-04 -6.000000e+00 2.227996e-03 280.11 -2.00 20.00 -2.00 313.57 0.00e+00 2.251 0.000 302.00 328.00 3 -1.2456e-01 5.6723e-04 2.5184e-02 -6.0000e+00 1.3182e-01 4.5904e-01 6.2305e-04 1.3554e-02 -6.0000e+00 1.4222e-01 -4.5690e-01 3.5866e-04 6.6066e-03 -6.0000e+00 8.4149e-02 1.8252e-01 1.5584e-04 1.9365e-03 -6.0000e+00 3.5837e-02 5.5587e-02 -5.7159e-03 1.1562e-05 3.0525e-05 -6.0000e+00 2.3975e-03 -2.9601e-02 -2.0890e-03 12 9 8 11 4 0 12.01 22.57 0.49 -0.02960 -0.07255 2367 2366 1 8 0 4.560 20.00 22.57 27.95 26.11 25.39 20.9 954.32 16050 19468 16673 5566 -11521 -20211 -19160 -12782 -6749 -6279 -12143 -14559 -8106 168 8340 12567 12203 11459 11253 11034 9006 4586 3478 5223 5904 5894 2646 -6220 -15852 -19501 -17312 -14056 -10214 -11444 -20841 -24566 -18878 -8701 3199 12449 15771 16090 15923 14342 12165 10122 6524 2260 -1277 -2801 -371 1952 3718 5263 4981 4654 4310 2338 -166 -1296 127 3549 7009 8768 5237 -1661 -7118 -9706 -6100 -81 3204 4237 2914 579 -4072 -10711 -17245 -20899 -18432 -12745 -8010 -4463 -2985 -1291 2010 4700 6517 7593 7461 5230 1364 -3359 -8173 -9953 -7752 -4167 -522 2695 3295 1443 -1267 -4449 -5571 -2892 94 1580 3176 4404 5703 7147 7739 6788 4628 1462 -2028 -4065 -3843 -2278 411 2566 3256 3359 2635 977 -895 -3006 -5116 -4721 -3531 -2570 -2025 -2213 -2433 -1645 -188 679 1283 1848 1657 917 59 -1004 900000 7816 9557 8232 2743 -5669 -10913 -10398 -6962 -3699 -3465 -6709 -8065 -4536 95 4772 7307 7141 6754 6677 6567 5385 2742 2084 3153 3598 3616 1628 -3802 -9592 -11747 -10536 -8655 -6391 -7263 -13157 -15396 -12007 -5682 2179 8848 11566 11996 12007 10861 9198 7657 4918 1699 -957 -2103 -283 1533 2979 4315 4159 3914 3654 1985 -140 -1086 107 3081 6311 7414 4481 -1518 -6331 -8576 -5502 -70 2922 3951 2723 529 -3588 -9868 -15252 -18154 -16350 -11988 -7284 -4298 -2996 -1328 2143 5209 7428 8796 8639 5905 1468 -3444 -8031 -9656 -7806 -4464 -598 3308 4213 1826 -1541 -5143 -6175 -3261 112 1948 4028 5775 7099 9325 10532 9354 6225 1880 -2694 -5200 -4924 -3012 522 3394 4344 4410 3396 1330 -1174 -3832 -6332 -5899 -4664 -3574 -2689 -3012 -3370 -2350 -281 1053 2020 2958 2654 1431 90 -1480 900000 SS 20240627T055738.4Z 8944.248361 205 2 11.00 2 63.77 84.18 66.05 217.66 0.00 1 0.00 1 0 41 8.926e-02 6.600e-02 5.143e-04 4.148e-04 2.483626e-01 2.188468e-04 3.293580e-03 -6.000000e+00 5.229919e-02 233.22 -2.00 3.74 -2.00 314.10 0.00e+00 3.887475e-04 1.528523e-05 2.896700e-04 -6.000000e+00 2.227799e-03 280.11 -2.00 20.00 -2.00 313.57 0.00e+00 2.249 0.000 302.00 328.00 3 -1.3911e-01 5.5967e-04 2.5158e-02 -6.0000e+00 1.3186e-01 4.5795e-01 6.1477e-04 1.3540e-02 -6.0000e+00 1.4224e-01 -4.5594e-01 3.5387e-04 6.5956e-03 -6.0000e+00 8.4165e-02 1.8208e-01 1.5373e-04 1.9281e-03 -6.0000e+00 3.5849e-02 5.6567e-02 -5.5028e-03 1.1415e-05 3.0544e-05 -6.0000e+00 2.3972e-03 -2.8938e-02 -2.0099e-03 12 9 8 11 4 0 1.10 22.57 0.49 -0.02894 -0.07029 2367 2366 1 8 0 4.560 20.00 22.57 27.95 26.11 25.39 20.9 954.32 15872 19348 16790 5515 -11485 -20135 -19125 -12954 -7006 -6212 -12068 -14669 -8168 273 8223 12654 12127 11523 11222 11143 9180 4704 3508 5164 5910 5946 2776 -6016 -15904 -19659 -17312 -14108 -10226 -11358 -20694 -24534 -18966 -8702 3248 12397 15663 16137 15916 14389 12142 10095 6538 2304 -1288 -2826 -436 1948 3652 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