File name: Pandora283s1_LaPaz_20241031_L2Fit_fout2c2d20240531p1-8.txt File generation date: 20241101T044215.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Marcos Andrade Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 283 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora283_OF_v3d20231025.txt Instrument calibration file used: Pandora283s1_CF_v2d20240531.txt Level 1 file used: Pandora283s1_LaPaz_20241031_L1_smca1c2d20240531p1-8.txt Full location name: Laboratory for Atmospheric Physics, UMSA, La Paz Short location name: LaPaz Country of location: Bolivia Location latitude [deg]: -16.5389 Location longitude [deg]: -68.0661 Location altitude [m]: 3420 Local noon date: 20241031 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 203 345 Nominal wavelengths inside fitting window [nm]: 305.0233 305.1640 305.3046 305.4453 305.5860 305.7266 305.8672 306.0078 306.1485 306.2891 306.4296 306.5702 306.7108 306.8513 306.9919 307.1324 307.2729 307.4134 307.5539 307.6944 307.8349 307.9754 308.1158 308.2563 308.3967 308.5371 308.6775 308.8179 308.9583 309.0987 309.2390 309.3794 309.5197 309.6600 309.8004 309.9407 310.0810 310.2213 310.3615 310.5018 310.6420 310.7823 310.9225 311.0627 311.2029 311.3431 311.4833 311.6235 311.7636 311.9038 312.0439 312.1840 312.3242 312.4643 312.6044 312.7444 312.8845 313.0246 313.1646 313.3046 313.4447 313.5847 313.7247 313.8647 314.0046 314.1446 314.2846 314.4245 314.5644 314.7044 314.8443 314.9842 315.1241 315.2639 315.4038 315.5437 315.6835 315.8233 315.9631 316.1029 316.2427 316.3825 316.5223 316.6621 316.8018 316.9416 317.0813 317.2210 317.3607 317.5004 317.6401 317.7797 317.9194 318.0590 318.1987 318.3383 318.4779 318.6175 318.7571 318.8967 319.0362 319.1758 319.3153 319.4549 319.5944 319.7339 319.8734 320.0129 320.1524 320.2918 320.4313 320.5707 320.7101 320.8495 320.9890 321.1283 321.2677 321.4071 321.5465 321.6858 321.8251 321.9645 322.1038 322.2431 322.3824 322.5216 322.6609 322.8002 322.9394 323.0786 323.2178 323.3570 323.4962 323.6354 323.7746 323.9138 324.0529 324.1920 324.3312 324.4703 324.6094 324.7485 324.8876 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241031T104734.7Z 9070.449707 64 1 54.44 2 78.55 101.74 68.57 96.44 0.00 1 0.00 1 0 25 1.018e-01 7.523e-03 4.549e-03 4.482e-04 5.192369e-01 2.230534e-04 5.252315e-03 -6.000000e+00 5.683000e-02 226.59 -2.00 3.03 -2.00 318.88 0.00e+00 1.963020e-03 4.958799e-05 4.567491e-04 -6.000000e+00 2.431095e-03 274.08 -2.00 20.00 -2.00 318.33 0.00e+00 4.884 0.000 302.00 328.00 3 9.4528e-01 6.0848e-04 3.9747e-02 -6.0000e+00 1.4133e-01 -4.6090e-03 6.9773e-04 2.2896e-02 -6.0000e+00 1.5383e-01 -3.7008e-02 5.2944e-04 1.1646e-02 -6.0000e+00 9.1207e-02 1.3901e-02 2.8485e-04 3.9075e-03 -6.0000e+00 3.8891e-02 4.3047e-03 -3.0391e-04 1.1664e-05 3.6987e-05 -6.0000e+00 2.5946e-03 3.5561e-02 -1.8981e-04 11 8 0 10 0 0 -8.58 24.25 0.31 0.03556 0.03328 645 66 1 5 0 84.390 33.25 20.22 24.25 18.20 3.5 882.09 -37243 -31364 -24036 -30397 -43065 -41864 -39257 -34923 -27980 -25332 -28649 -25785 -19166 -14795 -6666 -4333 -4396 -4385 -2449 -1485 130 -3806 -2247 -2046 -1327 -1615 -2989 -5125 -4668 -4252 -2363 785 1296 157 -4408 -4859 -2879 -1224 476 416 243 442 789 1380 951 1437 1132 595 375 751 1514 1643 1969 1856 1473 1159 847 476 146 -111 778 1419 2402 2690 1215 392 -128 -566 421 1067 931 643 376 172 -105 -777 -1547 -2115 -1758 -1310 -1369 -1422 -1955 -2000 -1215 -633 -83 381 781 874 798 379 -261 -462 -282 -299 151 573 339 -150 -558 -1068 -1193 -785 -987 -1004 -800 -542 -75 465 684 721 529 289 -180 14 -103 239 308 288 135 447 626 667 496 201 101 462 413 328 101 -23 -365 -148 -125 -8 74 246 173 -106 -408 -447 -654 -998 -914 -692 -896 -1301 -1213 -1203 -1185 -1007 -951 -1140 -1093 -935 -869 -445 -331 -371 -403 -216 -137 12 -367 -221 -219 -153 -197 -374 -629 -552 -522 -328 124 234 30 -850 -917 -583 -267 126 122 80 154 267 475 331 508 405 218 141 294 645 726 944 900 755 618 467 263 78 -59 420 785 1483 1743 834 260 -81 -363 292 808 742 513 299 137 -77 -540 -1048 -1416 -1212 -1002 -1159 -1302 -1878 -1941 -1248 -664 -91 416 849 954 846 389 -252 -446 -286 -332 177 733 458 -205 -715 -1326 -1409 -931 -1226 -1278 -1027 -734 -105 673 1049 1127 847 442 -265 20 -147 357 474 453 214 686 953 1012 722 291 140 641 615 513 167 -39 -622 -266 -233 -15 141 478 338 -201 -756 -801 -1162 SS 20241031T105307.1Z 9070.453554 67 1 54.41 2 77.25 101.40 67.27 96.14 0.00 1 0.00 1 0 17 6.102e-02 7.317e-03 2.586e-03 3.576e-04 4.754510e-01 1.775431e-04 4.837025e-03 -6.000000e+00 3.406155e-02 226.59 -2.00 3.03 -2.00 318.44 0.00e+00 1.380448e-03 3.441184e-05 3.403097e-04 -6.000000e+00 1.457073e-03 274.08 -2.00 20.00 -2.00 317.87 0.00e+00 4.419 0.000 302.00 328.00 3 8.5510e-01 4.7846e-04 3.6085e-02 -6.0000e+00 8.4706e-02 -8.6346e-03 5.4378e-04 2.0881e-02 -6.0000e+00 9.2197e-02 -2.4727e-02 3.8090e-04 1.0501e-02 -6.0000e+00 5.4665e-02 8.2310e-03 2.0305e-04 3.2999e-03 -6.0000e+00 2.3310e-02 6.6626e-03 -2.5184e-04 9.3713e-06 3.1346e-05 -6.0000e+00 1.5551e-03 3.5375e-02 -1.9113e-04 11 8 0 10 0 0 6.46 24.25 0.30 0.03538 0.03348 818 84 1 5 0 66.500 33.25 20.19 24.25 18.94 3.5 888.24 -23974 -16474 -12987 -19577 -25215 -26778 -22288 -20396 -16427 -14784 -17974 -15404 -11880 -6713 -3034 -2366 -1715 -1356 -43 437 1083 -1428 -365 -514 -537 -234 -1620 -3261 -3466 -1868 -171 1457 1486 165 -3503 -3697 -2732 -987 75 464 65 221 418 726 939 1171 679 298 175 655 1022 1350 1489 1709 1146 1036 790 367 173 46 806 1513 2300 2390 1154 299 -441 -700 397 968 717 538 349 366 -15 -739 -1427 -2099 -1685 -1314 -1294 -1441 -1969 -2037 -1213 -612 -7 431 785 901 829 289 -243 -375 -191 -202 162 632 461 -130 -648 -1212 -1214 -789 -957 -1008 -899 -545 -29 500 682 724 485 273 -70 64 7 315 245 317 128 309 586 603 505 321 140 494 436 304 120 -50 -318 -162 -120 -17 61 242 146 -99 -386 -464 -699 -935 -681 -548 -842 -1032 -1079 -930 -966 -850 -804 -1027 -929 -836 -556 -268 -241 -189 -161 -5 57 145 -195 -51 -78 -88 -41 -287 -561 -573 -313 -29 286 331 39 -821 -845 -677 -265 23 167 24 88 174 307 399 504 295 131 78 284 481 660 788 969 647 607 477 222 102 27 477 920 1554 1697 819 214 -301 -478 292 744 584 460 297 311 -12 -549 -1021 -1475 -1276 -1050 -1144 -1379 -1977 -2071 -1256 -675 -7 496 900 997 886 297 -243 -372 -198 -221 194 798 616 -175 -847 -1481 -1409 -923 -1178 -1276 -1189 -734 -40 739 1036 1149 763 419 -103 91 11 452 364 485 199 479 874 894 738 451 192 682 642 471 191 -84 -532 -276 -214 -31 115 449 273 -185 -705 -822 -1196 SS 20241031T105822.9Z 9070.457210 70 1 54.41 2 76.01 101.09 66.04 95.85 0.00 1 0.00 1 0 17 3.962e-02 7.067e-03 1.616e-03 2.996e-04 4.392353e-01 1.485385e-04 4.496104e-03 -6.000000e+00 2.211384e-02 226.59 -2.00 3.03 -2.00 318.09 0.00e+00 1.275444e-03 2.594166e-05 2.470149e-04 -6.000000e+00 9.459663e-04 274.08 -2.00 20.00 -2.00 317.52 0.00e+00 4.052 0.000 302.00 328.00 3 7.8300e-01 3.9667e-04 3.3175e-02 -6.0000e+00 5.4994e-02 -1.0299e-02 4.4843e-04 1.9279e-02 -6.0000e+00 5.9857e-02 -1.6734e-02 2.9685e-04 9.6331e-03 -6.0000e+00 3.5490e-02 4.4934e-03 1.5603e-04 2.9804e-03 -6.0000e+00 1.5134e-02 9.4493e-03 -2.3056e-04 7.8955e-06 2.8459e-05 -6.0000e+00 1.0096e-03 3.5389e-02 -1.8694e-04 11 8 0 10 0 0 7.04 24.26 0.31 0.03539 0.03366 997 102 1 5 0 54.570 33.25 20.07 24.26 20.04 3.5 895.84 -13013 -9563 -8202 -12729 -17301 -18048 -13993 -12657 -10145 -10039 -11929 -11361 -7250 -4429 -868 -950 -308 -146 808 710 1271 368 861 776 604 321 -179 -1838 -1579 -1204 593 1939 1902 -12 -3087 -3469 -2722 -1199 -18 319 -197 -17 111 459 442 690 412 92 -274 293 917 1116 1436 1393 1094 1030 922 360 109 35 832 1441 2155 2222 1131 157 -477 -644 310 851 707 590 322 280 2 -668 -1319 -1922 -1617 -1249 -1308 -1375 -1919 -1959 -1191 -578 -99 395 766 849 786 276 -215 -323 -142 -216 212 677 476 -122 -551 -1105 -1241 -813 -912 -887 -873 -528 -41 519 657 657 488 274 -103 11 15 311 252 304 103 303 527 635 508 329 167 497 493 348 132 -5 -322 -181 -107 -32 49 237 157 -133 -380 -522 -676 -688 -555 -493 -761 -972 -986 -793 -816 -723 -761 -932 -946 -630 -458 -105 -132 -46 -23 125 115 211 61 147 143 121 68 -38 -379 -310 -241 131 447 496 -3 -841 -922 -784 -376 -6 126 -87 -8 51 212 206 324 194 44 -132 145 461 617 809 840 657 640 589 231 68 21 523 980 1546 1674 850 118 -339 -455 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